全文获取类型
收费全文 | 3840篇 |
免费 | 467篇 |
国内免费 | 469篇 |
专业分类
化学 | 3219篇 |
晶体学 | 48篇 |
力学 | 164篇 |
综合类 | 20篇 |
数学 | 438篇 |
物理学 | 887篇 |
出版年
2024年 | 6篇 |
2023年 | 60篇 |
2022年 | 104篇 |
2021年 | 103篇 |
2020年 | 133篇 |
2019年 | 139篇 |
2018年 | 114篇 |
2017年 | 83篇 |
2016年 | 166篇 |
2015年 | 135篇 |
2014年 | 198篇 |
2013年 | 255篇 |
2012年 | 329篇 |
2011年 | 313篇 |
2010年 | 216篇 |
2009年 | 190篇 |
2008年 | 222篇 |
2007年 | 209篇 |
2006年 | 206篇 |
2005年 | 175篇 |
2004年 | 152篇 |
2003年 | 158篇 |
2002年 | 174篇 |
2001年 | 136篇 |
2000年 | 108篇 |
1999年 | 132篇 |
1998年 | 79篇 |
1997年 | 61篇 |
1996年 | 89篇 |
1995年 | 70篇 |
1994年 | 33篇 |
1993年 | 40篇 |
1992年 | 26篇 |
1991年 | 31篇 |
1990年 | 30篇 |
1989年 | 21篇 |
1988年 | 17篇 |
1987年 | 17篇 |
1986年 | 14篇 |
1985年 | 12篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1970年 | 1篇 |
1963年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有4776条查询结果,搜索用时 0 毫秒
21.
QiaoHongYAO FuYouLI LuSHAN ChunHuiHUANG DongDongYIN 《中国化学快报》2003,14(11):1185-1188
A new photoresponsive D-π-A dye, mPS, has been designed and synthesized.Compared to the parent dye PS, IPCE values in the region from 400 nm to 560 nm was greatly improved upon changing the attaching group from the p- position to the o- position of the π-conjugation bridge. A solar cell based on mPS generated a remarkably high overall yield η of 5.4% under irradiation of 80.0 mW cm^-2 white light from a Xe lamp, Compared with PS, the overall yield η increased by 64%. 相似文献
22.
X. Y. You 《Heat and Mass Transfer》2003,40(1-2):75-81
Active feedback control for the onset of Rayleigh-Bénard Convection in temperature-dependent-viscosity liquids is investigated.
In this paper, three major problems are addressed: (1) The results of Tang-Bau control are improved by considering the effects
of temperature-dependent viscosity; (2) A more efficient two-plate control strategy is presented. A phenomenon of coalescence
of the unstable modes is observed as the controller gain is large enough; (3) A simple way to estimate the critical Rayleigh
number under the effects of temperature-dependent viscosity is described. Numerical results show that the effects of temperature-dependent
viscosity on the critical Rayleigh number should be taken into account in some cases and the onset of Rayleigh-Bénard convection
can be effectively delayed or advanced by the active feedback control strategies studied here. 相似文献
23.
Guan Wu WANG* Li Juan JIAO Er Hong HAO Yong Ming LU You Jun YANG Department of Chemistry University of Science Technology of China Hefei 《中国化学快报》2004,15(5)
Water-soluble fullerenes not only have a number of important applications in biological chemistry1, but also form ordered aggregate structures that can be utilized in materials science2. There are reports that some water-soluble fullerene derivatives can form ordered structures in water, such as vesicle, nanorod and nanoparticle2-5. However, relatively few reports on the aggregation process have been reported. Knowledge of factors that affect the cluster formation in solution is of consider… 相似文献
24.
关于结合方案和PBIB设计的定义及所用的有关符号见文献[1].设F_q为特征为2的有限域,q=2~r.熟知F_q上的对称矩阵合同于以下三种形式的矩阵(见[1]p.24). 相似文献
25.
26.
In this study, a rapid and sensitive high performance liquid chromatography-inductively coupled plasma-mass spectrometry (HPLC-ICP-MS) determination of primary As species in fish tissues and urine is reported. The separation was achieved on an Altima C18 column with a mobile phase containing citric acid and hexanesulfonic acid (pH 4.5). As(V), monomethylarsonic acid (MMA), As(III), dimethylarsinic acid (DMA) and arsenobetaine (AsB) were separated in less than 4 min with retention times of 83, 99, 130, 166 and 208 s, respectively. This separation of five species in less than 4 min should be attractive to those interested in As speciation. The quantification limits were 44, 56, 94, 64, 66 ng l(-1) and the relative standard deviations (R.S.D.) for day-to-day injections of As at 2 mug l(-1) were 2.0, 3.1, 2.4, 3.8 and 4.0%. The procedure was tested using two reference materials (DORM-2 dogfish muscle tissue, NIST SRM 2670 Freeze-dried Urine, normal level) and then applied to real-world samples. The results obtained demonstrate the suitability of the procedure for screening and quantification at physiological levels of primary As species in biological samples. 相似文献
27.
28.
二氧化碳多相催化加氢的新进展 总被引:4,自引:0,他引:4
就近年来关于CO2活化、几个重要的CO2多相催化加氢反应及廉价氢的供给的研究进展进行综述。参考文献34篇。 相似文献
29.
Self-assembly of a new precursor [Cu(L)](ClO4)2 (1) (L = macrocyclic ligand) with octacyanometalates [M(CN)8]3- (M = Mo, W) produced two-dimensional cyano-bridged Cu(II)-M(V) bimetallic assemblies [Cu(L)]3n[M(CN)8]2n.6nH2O [M = Mo (2), W (3)] with novel honeycomblike structures, characterized by spectroscopic data, single-crystal X-ray diffraction studies, and magnetic measurements. The crystallographic determination reveals that compounds 2 and 3 are isostructural and crystallize in the triclinic system (P). The Cu atom in a distorted octahedral environment experiences a tetragonal elongation of apical nitrogen atoms exhibiting average Cu-Nax lengths of 2.566 Angstroms for 2 and 2.593 Angstroms for 3, which accounts for the Jahn-Teller effect of a Cu(II) ion. The Cu-NC angles are magnetically important, ranging from 135.7 to 159.2 degrees. Three types of L in the crystal lattice are observed, which are dependent on the relative positions of the pendant hydroxyl groups with respect to the CuN4 basal plane. The positions are correlated with hydrogen bonding of OH groups to neighboring atoms. The magnetic data indicate that ferromagnetic and antiferromagnetic interactions between Cu(II) and M(V) through the CN linkage coexist. 相似文献
30.