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排序方式: 共有203条查询结果,搜索用时 15 毫秒
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利用傅里叶变换红外光谱(FTIR)法研究了不同类型氨基酸及其配合物与二棕榈酰磷脂酰胆碱脂质体浇铸膜的相互作用。结果表明,在有氨基酸存在下,二棕榈酰磷脂酰胆碱的红外谱图没有明显的变化;氨基酸稀土配合物与磷脂极性头基团有静电相互作用,作用的程度随稀土离子、氨基酸及稀土同氨基酸配比的不同而有所不同。 相似文献
3.
测定了二(2,4,4-三甲基戊基)膦酸(BTMPPA)及其稀土配合物Ln(BTMPP)3在4000~50cm^-1光谱区内的FT-IR光谱和部分配合物的激光拉曼光谱,对其谱带进行了经验归属。发现稀土氧键具有较高的离子键特性。由Ln-O伸缩振动频率值算出其近似力常数约8m dyn/nm。 相似文献
4.
Li Xuetian Shao Zhongbao Liu Kuiren Zhao Qing Liu Guangfu Xu Binshi 《Journal of Solid State Electrochemistry》2018,22(9):2837-2843
Journal of Solid State Electrochemistry - LiFePO4-x/3Fx/C (x = 0, 0.03, 0.06, 0.09) were obtained via wet mechanical agitation-assisted high-temperature ball milling method. XRD, SEM,... 相似文献
5.
Li Xuetian Shao Zhongbao Liu Kuiren Zhao Qing Liu Guangfu Xu Binshi 《Journal of Solid State Electrochemistry》2019,23(2):465-473
Journal of Solid State Electrochemistry - Li1-xNbxFePO4/C has been prepared by wet mechanical stirring–assisted high-temperature ball milling route. Wet mechanical stirring was considered to... 相似文献
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Kang Y Wu J Yin G Huang Z Liao X Yao Y Ouyang P Wang H Yang Q 《Langmuir : the ACS journal of surfaces and colloids》2008,24(14):7432-7441
In this study, paclitaxel loaded poly( L-lactic acid) (PTX-PLLA) microparticles were prepared using solution enhanced dispersion by supercritical CO2(SEDS) technique. This supercritical antisolvent technique offers the advantage of negligible organic solvent residua in the drug loaded microparticles. Scanning electron microscopy (SEM) showed that microparticles exhibited rather spherical shape and small particle size with narrow particle size distribution. X-ray diffraction (XRD) and differential scanning calorimeter (DSC) indicated that PTX was amorphously dispersed in the PLLA matrix. The drug loading and encapsulation efficiency of PTX-PLLA microparticles were 14.33% and 62.68%, respectively. In vitro cytotoxicity evaluation of PTX-PLLA microparticles against nonsmall-cell lung cancer A549 and ovarian cancer SKOV3 cell lines indicated that PTX-PLLA had superior antiproliferation activity against the A549 and SKOV3 cell lines, compared with free PTX formulations. The cellular internalization of fluorescent microparticles was evidenced by fluorescence microscope and further confirmed by transmission electron microscopy (TEM). This was attributed to the efficient intracellular accumulation of PTX via cell phagocytosis and sustained release of PTX from PLLA matrix. The anticancer activity of PTX-PLLA was associated with PTX-induced cell apoptosis such as nuclear aberrations, condensation of chromatin and swelling damage in mitochondria. The cell apoptosis index detected by flow cytometry was higher in PTX-PLLA group than in free PTX. The PTX-PLLA formulation, which was obtained through micronization of PTX and encapsulation of micronized PTX into PLLA simultaneously in the SEDS process, significantly potentiated the anticancer activity of PTX. 相似文献
8.
Phenyltriazolinones are one of the most important classes of herbicides targeting the protoporphyrinogen oxidase enzyme. A series of triazolinone derivatives containing a strobilurin pharmacophore were designed and synthesized with the aim of discovering new phenyltriazolinone analogues with high activity. The herbicidal activity of the synthesized compounds was assayed and some of the test compounds displayed moderate herbicidal activity at 150 g ai/ha. 相似文献
9.
玉米叶片残体腐解过程的傅里叶变换红外光谱研究 总被引:10,自引:2,他引:10
采用傅里叶变换红外光谱对玉米植株叶片残体腐解过程进行了研究。结果表明,随着玉米叶片残体腐解的进行,羟基,酮碳基,甲基,在和次甲基的含量逐渐降收据 的含量增加。 相似文献
10.
测量了1,4-羟基蒽醌及其氘化物的红外光谱,用NRCC程序进行了振动分析,由于同时考虑了分子内与分子间的氢键,统一处理面内与面外振动,计算结果优于文献报道,并纠正了一些错误归属。 相似文献