γ-苄基膦酸-磷酸锆的合成、表征及插层性能研究

于220℃水热晶化下制备了高结晶度的γ-ZrP,合成了3种γ-苄基膦酸-磷酸锆层状化合物Zr(PO₄).(H₂PO₄)_0.15(C₆H₅CH₂PO₃H)_0.85·0.4H₂O(1,d=1.86nm),Zr(PO₄)(H₂PO₄)_0.30(C₆H₅CH₂PO₃H)_0.70·0.6H₂O(2,d=1.78nm)和Zr(PO₄)(H₂PO₄)_0.50(C₆H₅CH₂PO₃H)_0.50·0.7H₂O(3,d=1.66nm).用X射线粉末衍射和³¹P固态核磁共振等手段表征其结构,并研究了其与α-苯乙胺的插层性能.     

超分子碱金属膦酸盐——哌嗪双膦酸钠的合成及晶体结构

二维或三维金属膦酸盐聚合物作为功能材料在催化、离子交换和纳米材料等研究领域受到广泛关注 .最初的研究主要集中在四价金属盐 ,后来陆续报道了对于其它价态金属盐的研究 [1～ 3] ,但关于单一碱金属的研究报道较少 . 2 0 0 0年 ,Aranda等[4 ] 报道了首例 Na2 [( HO3PCH2 ) 3NH ]· 1 .5 H2 O( Na PP- 1 )晶体结构 .与其它膦酸盐的明显差别是 ,碱金属双膦酸盐是治疗骨质疏松症的药物 [5] .本文从重要的医药原料哌嗪 [6 ]出发 ,制备并测定了一种具有超分子特征的 α-氨基双膦酸钠Na2 [( HO3PCH2 ) NC4 H8N( CH2 PO3H) ]( H2 O)…     

红外光谱法研究己内酯非等温结晶过程

红外光谱法研究己内酯非等温结晶过程;特征吸收谱带;结晶度;结晶速率     

Painlevé analysis, auto-Bäcklund transformation and new analytic solutions for a generalized variable-coefficient Korteweg-de Vries (KdV) equation

There has been considerable interest in the study on the variable-coefficient nonlinear evolution equations in recent years, since they can describe the real situations in many fields of physical and engineering sciences. In this paper, a generalized variable-coefficient KdV (GvcKdV) equation with the external-force and perturbed/dissipative terms is investigated, which can describe the various real situations, including large-amplitude internal waves, blood vessels, Bose-Einstein condensates, rods and positons. The Painlevé analysis leads to the explicit constraint on the variable coefficients for such a equation to pass the Painlevé test. An auto-B?cklund transformation is provided by use of the truncated Painlevé expansion and symbolic computation. Via the given auto-B?cklund transformation, three families of analytic solutions are obtained, including the solitonic and periodic solutions.     

On the general form of the Benjamin-Bona-Mahony equation in fluid mechanics

In the study of many problems of mechanical and physical sciences, various versions of the Benjamin-Bona-Mahony (BBM) equation or the regularized-long-wave equation have been proposed. In this paper, we obtain the solitary-wave solutions to the general form of the BBM equation, which fully cover the variety of the BBM solitary waves previously reported. This work has been supported by the China Talent Fund, by the Cheung Kong Scholars Programme of China, by the Cheung-Kong-Scholar Research Concerted Fund of Beijing University of Aeronautics and Astronautics, and by the Doctoral Education Fund in Basic Sciences of Beijing University of Aeronautics and Astronautics.     

多羟基甾醇25(R)-异螺甾环-5-烯-2β,3α,19-三醇的合成

以薯蓣皂素为原料, 经过磺酰酯化、N-溴代丁二酰亚胺(NBS)氧化加成、Pb(OAc)₄远程氧化关环、消去反应、间氯过氧苯甲酸(mCPBA)氧化、高氯酸开环及锌粉还原7步反应, 合成多羟基甾体25(R)-异螺甾环-5-烯-2β,3α,19-三醇. 并用IR, ¹H NMR, ¹³C NMR, MS及元素分析对各中间体及目标化合物进行了表征.     

溶聚丁苯链化学结构的NMR研究

溶聚丁苯链化学结构的NMR研究;溶聚丁苯; 链化学结构; 相容性     

成核剂cdbs和纳米碳酸钙对聚丙烯结晶行为和力学性能的影响

聚丙烯;成核剂对氯二苄叉山梨糖醇;纳米碳酸钙;结晶行为;雾度;力学性能     

Thermoluminescence in sea sediments during the cosmogenic isotopes enhancement 35000 y BP

Summary We have measured the thermoluminescence (TL) profile of the Mediterranean Sea core CT85.5 at the same depths where the cosmogenic-isotope¹⁰Be production peak at 35 ky BP was found. Strong TL peaks are evident at 37.5 ky and 35.6 ky BP. The Fourier analysis of the TL time series running from 32.5 ky to 42.6 ky at 100 y sampling interval shows 2500 y and 500 y periodicities. We suggest that the Sun was ?active? at the time of the¹⁰Be enhancement. Paper presented at the 6th Cosmic Physics National Conference, Palermo, 3–7 November 1992.     

N2流量对GaN的形貌及光学和电学性能的影响

采用化学气相沉积法(CVD)在Si(100)衬底上以Ni为催化剂, 金属Ga和NH₃为原料合成了GaN微纳米结构, 并研究了N₂流量对产物GaN的形貌及光学和电学性能的影响。利用场发射扫描电子显微镜(SEM)、透射电镜(TEM)、X射线衍射仪(XRD)、X-ray能谱仪(EDS)、光致发光谱(PL)和霍尔效应测试仪(HMS-3000)等测试手段对样品的形貌、结构、成分、光学和电学性能进行了分析。结果表明, 随着N₂流量的增加, 产物GaN的形貌发生了由微米棒到蠕虫状线再到光滑纳米线的转变;生成的GaN均为六方纤锌矿结构;样品均表现出383 nm的近带边紫外发射峰和470 nm左右的蓝光发射峰;所有样品均为n型;并对产物GaN的形貌转变机理进行了分析。