航天育种第4代白术的XRF和PXRD分析

用X射线荧光(XRF)和X射线衍射(PXRD)技术对第4代太空组和地面组白术中元素种类、含量及主要化学组分的微结构进行测定并作对比分析。结果表明,太空组比地面组白术少了Na和Ti两种元素,K和Mn的含量分别提高到1.16和1.15倍,其他元素含量有不同程度的下降,尤其是Si和P,分别下降了82.1%和71.2%;在地面组白术中鉴别出含有一水草酸钙和菊糖,而太空组白术中不含菊糖,一水草酸钙的含量比地面组明显减小。航天育种有利于选育出变异幅度大的特异质白术新品种。这两种技术配合使用适宜对变异幅度大的航天育种药用植物的元素和主要组分微结构的分析。     

LC Method for Analysis of Three Flavonols in Rat Plasma and Urine after Oral Administration of Polygonum aviculare Extract

A high-performance liquid chromatographic method has been developed for the simultaneous analysis of the flavonols myricitrin (1), avicularin (2), and juglanin (3) in rat plasma and urine after oral administration of the total flavonoids from Polygonum aviculare. Samples were prepared by solid-phase extraction then separated on a C₁₈ reversed-phase column by use of a mobile-phase gradient prepared from methanol and aqueous formic acid solution. The flow rate was 1 mL min^?1. Detection was performed at 254 nm. The calibration range was 11–1,100 μg mL^?1 for both 2 and 3 in plasma; in urine the calibration ranges for 1, 2, and 3 were 32–1,600, 11–1,100, and 22–1,100 μg mL^?1, respectively. Intra-day and inter-day RSD were less than 4.33 and 3.62% for 2 and 3, respectively, in plasma, and no more than 4.03 and 2.22% for all the analytes in urine. The analytical sensitivity and selectivity of the assay enabled successful application to pharmacokinetic studies of flavonols 1–3 in rats.     

毛细管气相色谱法研究硝基氨基甲苯异构体在SE-30、SE-54中的热力学性质

通过对色谱分离过程的热力学处理, 得到了用毛细管色谱法测定溶质在溶剂中的溶解热力学性质的关系式, 利用该式测定了硝基氨基甲苯的五种异构体在SE-30, SE-54固定液中的溶解焓和溶解熵, 并对结果进行了定性解释。     

Structure elucidation and complete NMR spectral assignments of a novel sesquiterpene glycoside from Ixeris sonchifolia

A novel sesquiterpene glycoside was isolated from the whole plant of Ixeris sonchifolia. The structure was established as 1(10)E-4Z-3alpha-hydroxy-germacra-1(10),4,11(13)-trien-6, 12-olide-14-O-beta-D-glucopyranoside (1) on the basis of spectroscopic techniques and chemical analysis.     

Photo-induced Coupling Reaction of 1, 1-Diphenyl-2, 2-dicyanoethylene with 10-Methyl-9, 10-dihydroacridine

In a previous communication1, we reported a novel photo-induced coupling of 9-fluorenylidenemalononitrile 1 with the coenzyme NADH model 10-methyl-9, 10-dihydroacridine (AcrH2) to give 9-dicyanomethyl-9-(10-methyl-9-acridinyl)fluorene and proposed a mechanism involving photo-induced electron transfer-proton transfer and radical coupling. This is a scarce mechanism for the reaction of NADH models2, which usually takes place by a formal hydride transfer pathway3. In view of the novelty of t…     

Surface functionalization and characterization of magnetic polystyrene microbeads

A new approach to the surface functionalization of magnetic polystyrene microbeads with chloroacetyl chloride in the presence of aluminum chloride was reported. Composite microbeads consisting of polymer-coated iron oxide nanoparticles were prepared by spraying suspension polymerization. Functional chloride groups were introduced onto the surface of magnetic polystyrene microbeads by surface chemical reaction without destroying the magnetite nanoparticles within the microbeads. First, a complex was synthesized by a reaction between aluminum chloride and chloroacetyl chloride. Then, the complex was added dropwise to the solution of magnetic polystyrene microbeads, and a surface acylation reaction between complex and polystyrene microbeads was carried out. Subsequently, the amino groups were coupled to the magnetic microbeads via an ammonolysis reaction between ethylenediamine and chloride groups on the acylated magnetic polystyrene microbeads. The chemical composition, surface functional groups, and magnetism of the magnetic polystyrene microbeads before and after surface functionalization were characterized by Fourier transform infrared spectroscopy and vibrating sample magnetometry. The results showed that the surface functionalization reaction had little impact on the magnetism of the microbeads. The content of surface amino groups on the magnetic polystyrene microbeads was found to be 0.2 mmol/g. An affinity dye, Cibacron Blue F3G-A (CB), was then immobilized to prepare a magnetic affinity adsorbent. It was confirmed from X-ray photoelectron spectroscopy spectra that the CB molecules were covalently coupled on the magnetic microbeads.     

Construction of C2-Spirocyclopropyl-Indolin-3-Ones through Base-Promoted [2+1] Annulation Reaction of Indolin-3-ones with Bromosulfonium Salts

A simple base-promoted [2+1] annulation of indolin-3-ones and bromosulfonium salts has been developed in this article. This strategy uses simple and easily prepared indolin-3-ones 1 as C1 synthons and bromosulfonium salts 2 as C2 synthons under mild reaction conditions, and 33 examples of C2-spirocyclopropyl-indolin-3-ones were obtained with up to 99 % yield and >20 : 1 dr.     

阴离子在构筑吡啶酰胺－铜(II)配位超分子体系中的作用

Three complexes Cu（ppca）2（H2O）2（NO3）2 （1）, Cu2（μ-OH）2（ppca）2（H2O）4）·（ClO4）2 （2） and Cu2（μ-CH3COO）4（ppca）2（3） have been synthesized by the reaction of copper（Ⅱ） salts with N-phenyl-4-pyridinecarboxamide （ppca） and characterized. For anions, in complex 1, NO3^- coordinated with copper（Ⅱ）, in complex 2 perchlorate anion did not take part in coordination, the copper（Ⅱ） cations were connected by μ-OH to form a dinuclear unit, and complex 3 had a dimeric copper（Ⅱ） carboxylate paddle-wheel core. Noncovalent interactions linked these complexes to form supramolecular networks. Different coordinating modes of anions controlled modes of intennolecular interactions, which resulted in different final structures.     

基于XGM的SOA波长变换器噪音特性分析及优化设计

利用动态载流子恢复时间可以精确模拟基于交叉增益调制的SOA全光波长变换器的饱和增益效应,本文将SOA分段ASE噪音功率和分段动态模型结合,得到沿长度分布的ASE噪音功率,并讨论了偏置电流、泵浦光和探测光的波长、功率、SOA长度对消光比和信噪比的影响理论计算结果表明,大的偏置电流有利于提高消光比和信噪比;对于一定的输入波长,相对较大的泵浦光和相对较小的探测光变换效果好;SOA的长度存在最佳值.     

Preparation of multi-walled carbon nanotubes functionalized magnetic particles by sol-gel technology and its application in extraction of estrogens

Magnetic silica particles coated with hydroxy-terminated multi-walled carbon nanotubes (MWCNTs-OH) were prepared by sol-gel technology, characterized and used for the convenient, rapid and efficient extraction of several estrogens (including diethylstilbestrol, estrone and estriol) in water followed by sweeping micellar electrokinetic chromatography analysis with UV detection. The results demonstrated that sol-gel technology was a feasible, simple and effective technique for the preparation of MWCNTs-OH functionalized magnetic silica particles. The factors affecting the extraction efficiency of estrogens (the pre-activation of magnetic particles, adsorption time, desorption time and the amount of elution solvent) were carefully investigated. The extraction efficiencies for diethylstilbestrol, estrone and estriol were 95.9%, 93.9%, and 52.4%, respectively, under the optimum conditions. The method detection limits for the three estrogens were less than 0.2 ng mL⁻¹. The developed method was applied for the analysis of tap water, mineral water, Pearl River water and honey.