全文获取类型
收费全文 | 39244篇 |
免费 | 7191篇 |
国内免费 | 6088篇 |
专业分类
化学 | 29009篇 |
晶体学 | 596篇 |
力学 | 2499篇 |
综合类 | 435篇 |
数学 | 4320篇 |
物理学 | 15664篇 |
出版年
2024年 | 121篇 |
2023年 | 721篇 |
2022年 | 1406篇 |
2021年 | 1524篇 |
2020年 | 1593篇 |
2019年 | 1640篇 |
2018年 | 1405篇 |
2017年 | 1454篇 |
2016年 | 1915篇 |
2015年 | 2098篇 |
2014年 | 2573篇 |
2013年 | 3202篇 |
2012年 | 3701篇 |
2011年 | 3782篇 |
2010年 | 2780篇 |
2009年 | 2829篇 |
2008年 | 3052篇 |
2007年 | 2555篇 |
2006年 | 2362篇 |
2005年 | 1928篇 |
2004年 | 1453篇 |
2003年 | 1211篇 |
2002年 | 1233篇 |
2001年 | 1002篇 |
2000年 | 823篇 |
1999年 | 690篇 |
1998年 | 513篇 |
1997年 | 449篇 |
1996年 | 408篇 |
1995年 | 325篇 |
1994年 | 329篇 |
1993年 | 252篇 |
1992年 | 212篇 |
1991年 | 158篇 |
1990年 | 159篇 |
1989年 | 100篇 |
1988年 | 89篇 |
1987年 | 66篇 |
1986年 | 80篇 |
1985年 | 55篇 |
1984年 | 38篇 |
1983年 | 36篇 |
1982年 | 16篇 |
1981年 | 17篇 |
1980年 | 10篇 |
1979年 | 20篇 |
1978年 | 8篇 |
1977年 | 11篇 |
1957年 | 9篇 |
1925年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
61.
Palladium-catalyzed cross-coupling reactions of aryl perfluorooctanesulfonates with amines are introduced. Application of the fluorous tag in multistep synthesis of triaryl-substituted pyrimidine is also described. 相似文献
62.
63.
64.
不锈钢丝网上薄膜TiO2光催化剂的Raman光谱研究 总被引:1,自引:0,他引:1
用Raman光谱方法来研究用Sol Gel法负载于金属丝网的薄膜TiO2 光催化剂的物相结构、厚度以及粒径大小。研究结果显示 ,薄膜达到一定厚度能够阻止基底Fe元素向薄膜表层的扩散 ;在 4 0 0℃下灼烧制得的薄膜TiO2 光催化剂具有锐钛矿晶型 ,而高于 4 0 0℃时 ,将出现金红石相TiO2 ;锐钛矿晶型TiO2 的Raman特征峰产生偏移 ,表明薄膜粒径的变化 ,通过计算表明 ,薄膜TiO2 的粒径为 10nm左右 ,TEM的分析结果也与之一致。 相似文献
65.
The crystallization behavior of miscible syndiotactic polystyrene (sPS) and atactic polystyrene (aPS) blends with different sPS/aPS weight ratios was investigated in supercritical CO2 by using Fourier‐transform infrared spectroscopy, differential scanning calorimetry, and wide‐angle X‐ray diffraction. Supercritical CO2 and aPS exhibited different effects on the conformational change of sPS and competed with each other. Increasing the content of amorphous aPS in the blends made its effect on the conformational change of sPS gradually surpass that of supercritical CO2. Supercritical CO2 favored the formation of the helical conformation of sPS in lower temperature range and the all trans planar conformation in higher temperature range, instead of forming the latter one only in higher temperature range in ambient atmosphere. However, increasing aPS content in the blends pushed the range for forming the helical conformation to lower temperature and made the all trans planar conformation dominant in aPS/sPS 25/75 blend after treating in supercritical CO2 above 60 °C. The all trans planar zigzag conformation was more favorable than the helical conformation after mixing aPS in sPS in supercritical CO2. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1755–1764, 2007 相似文献
66.
Kuan‐Wei Lee Hong‐Cheu Lin 《Journal of polymer science. Part A, Polymer chemistry》2007,45(20):4564-4572
A series of new liquid crystalline homopolymers, copolymers, and block copolymers were polymerized from styrene‐macroinitiator ( SMi ) and methacrylates with pendent 4,4′‐bis(biphenyl)fluorene ( M1 ) and biphenyl‐4‐ylfluorene ( M2 ) groups through atom transfer radical polymerization (ATRP). The number‐average molecular weights (Mn) of polymers P1 ‐ P4 were 10,007, 14,852, 6,275, and 10,463 g mol?1 with polydispersity indices values of 1.21, 1.15, 1.31, and 1.22, respectively. All polymers exhibit the nematic phase. The thermal, mesogenic, and photoluminescent properties of all polymers were investigated. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4564–4572, 2007 相似文献
67.
The interfacial dynamics‐based cavitation model, developed in Part‐1, is further employed for unsteady flow computations. The pressure‐based operator‐splitting algorithm (PISO) is extended to handle the time‐dependent cavitating flows with particular focus on the coupling of the cavitation and turbulence models, and the large density ratio associated with cavitation. Furthermore, the compressibility effect is important for unsteady cavitating flows because in a water–vapour mixture, depending on the composition, the speed of sound inside the cavity can vary by an order of magnitude. The implications of the issue of the speed of the sound are assessed with alternative modelling approaches. Depending on the geometric confinement of the nozzle, compressibility model and cavitation numbers, either auto‐oscillation or quasi‐steady behaviour is observed. The adverse pressure gradient in the closure region is stronger at the maximum cavity size. One can also observe that the mass transfer process contributes to the cavitation dynamics. Compared to the steady flow computations, the velocity and vapour volume fraction distributions within the cavity are noticeably improved with time‐dependent computations. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
68.
A one‐dimensional zinc(II) coordination polymer has been constructed from zinc(II), 4,4′‐biphenyldicarboxylate and pyridine in which each zinc(II) atom is coordinated by two pyridine ligands and two monodentate 4,4′‐biphenyldicarboxylate ligands that define a distorted tetrahedral geometry. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
69.
Hong-jun Liu Wei Zhao Guo-fu Chen Yi-shan Wang Lian-jun Yu Chi Ruan Xue-feng Li 《Optics & Laser Technology》2004,36(4):3482-314
Experimental investigations of a type-I noncollinear phase-matched optical parametric amplification based on lithium triborate, which was pumped by a 5-ns second-harmonic pulses from a Q-switched Nd:YAG, seeded by a cw Ti:sapphire laser at 800 nm, was presented. The experiments generated 2-ns signal output pulses at 800 nm, the maximum signal output pulse energy reached 19 μJ, the corresponding parametric gain was 44 dB. Furthermore, the experiments demonstrate that the 65 nm-FWHM parametric fluorescence gain spectrum could also be observed. A quantitative account of the ultrabroadband parametric fluorescence gain spectrum was given with our theory. The experimental measurements are in agreement with theoretical calculations. 相似文献
70.
Pal Jen Wei 《Journal of Non》2008,354(33):3911-3918
Through the arrangement of the applied load, experimental nanoindentation results of polymethylmethacrylate (PMMA) and polyurethane (PU) employed to establish a mechanical model. The proposed model consists of irreversible delayed plastic (viscoplastic) deformation, irreversible viscous deformation, and reversible delayed elastic (viscoelastic) deformations. The phase lag exhibited between the responding depth and the oscillating load is found to be linear proportional to frequency in the range of 1-50 Hz. The residual cavity profile of the PMMA scanned by an atomic force microscope gives a validity of accommodation assumption applied in the present model. The effects of overshooting, which occurred in the dwelling process, are also discussed. 相似文献