一些高Tc超导体的弹性性质

 本文用超声相比较方法测定了高T_c超导体La_1.85Sr_0.15CuO₄，La₂CuO₄和YBa₂Cu₃O₇的纵波和横波声速，进而导出了它们的纵向模量、切变模量、杨氏模量、泊松比、德拜温度及定体比热。在La_1.85Sr_0.15CuO₄样品上，还进行了压力实验，发现所有弹性模量都是随压强增加而增加。定体比热c_V和泊松比σ在高压下则略有下降。德拜温度是随压强增加而增加的。     

Symmetric Hilbert spaces arising from species of structures

Symmetric Hilbert spaces such as the bosonic and the fermionic Fock spaces over some lsquo;one particle space’ are formed by certain symmetrization procedures performed on the full Fock space. We investigate alternative ways of symmetrization by building on Joyal's notion of a combinatorial species. Any such species F gives rise to an endofunctor of the category of Hilbert spaces with contractions mapping a Hilbert space to a symmetric Hilbert space with the same symmetry as the species F. A general framework for annihilation and creation operators on these spaces is developed, and compared to the generalised Brownian motions of R. Speicher and M. Bożejko. As a corollary we find that the commutation relation with admits a realization on a symmetric Hilbert space whenever f has a power series with infinite radius of convergence and positive coefficients. Received: 7 April 2000; in final form: 28 November 2000 / Published online: 19 October 2001     

Interval parameter perturbation method for evaluating the bounds on natural frequencies of structures with interval parameters

For structural parameters with uncertainties, interval mathematics can, in the case where the probabilistic distribution density of uncertain variables is unavailable, deal with the influence of uncertainties in structural parameters on the response of structures. In order to evaluate the region containing natural frequencies of structures with interval parameters, the interval parameter perturbation method is presented in this paper. The advantage of the present method is its computational efficiency in evaluating the region containing natural frequencies. A numerical example is used to illustrate the efficiency of the method proposed. The project is supported by National Youth Natural Science Foundation of China and National Outstanding Youth Science Foundation of China.     

配合物的生成热和配体的质子化热之间的直线焓关系——Ⅶ.Ni(Ⅱ)-2,2′-联吡啶-N-(间位取代苯基)氨基乙酸三元体系

有关Ni(Ⅱ)-N-(间位取代苯基)氨基乙酸二元体系的直线焓和直线熵关系,前文已有报道,本文报告Ni(Ⅱ)-2,2′-联吡啶-N-(间位取代苯基)氨基乙酸(Ni(Ⅱ)-biPy-m-RPhG:R=CH_3,H,CH_3O,Cl)三元体系的生成热研究,发现在此三元体系中亦存在良好的直线焓和直线熵关系。     

四川乌龙茶香气化学成分的剖析

四川乌龙茶在低温减压蒸馏所得香气浓缩物经气相色谱-质谱联用测定,以气相色谱保留值验证,鉴定出19个化合物,它们是:丙酮,乙酸乙酯,顺-3-己烯醇-[1],乙酸顺-3-己烯酯,苯甲醇,反-芳樟醇氧化物(呋喃型),顺-芳樟醇氧化物(呋喃型),芳樟醇,苯乙醇,反-芳樟醇氧化物(吡喃型),丁酸顺-3-己烯酯,香叶烯,己酸顺-3-己烯酯,茉莉酮,橙花叔醇,金台欢醇,茉莉酮酸甲酯,正十六烷和2,6,10,14-四甲基十五烷。     

The Electrochemical Investigation of MEH-PPV in Ionic Liquid

Ionic liquids are a new kind of room-temperature molten organic salts. It can be used as solvents in the organic/polymeric syntheses, and some of them are called "green" solvents because of its recyclability1. Ionic liquids possess the superior properties, such as thermal stability up to 200(C, involatility and re-designability(for both cation and anion). The ionic liquid employed in this work is [bmim] [PF6]- ( butylmethylimidazolium hexafluorophosphate ) which is immiscible with water and h…     

双邻苯二酚锑二甲基羟乙铵的晶体结构

含锑配合物是治疗血吸虫病、肿瘤等的常用药物,我们曾对双邻苯二酚锑二乙基羟乙胺进行了晶体结构测定,本文简要报导双邻苯二酚锑二甲基羟乙胺的结构.锑化合物的制法与其二乙基羟乙铵衍生物类似.产物为淡黄色晶体,它在水溶液中长时间放置会变成紫黑色,因此,制得的晶体须立即用丙酮溶解进行重结晶.晶体的密度为1.667g/cm~3.按C_(16)H_(20)O_5NSb的元素分析结果(％)如下:Sb 28.3(28.5),C 43.9(44.9),N 3.3(3.3),H 4.7(4.7).括号内为理论值.