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991.
Bogna Rudolf Janusz Zakrzewski Grzegorz Celichowski Michle Salmain Anne Vessires Grard Jaouen 《应用有机金属化学》2004,18(3):105-110
Molecular recognition between avidin covalently immobilized at the surface of acrylic resin beads and a transition metallocarbonyl tracer of the biotin ligand was detected using diffuse reflectance infrared Fourier transform spectroscopy. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
992.
Results are reported for the oxidation of complexes of the type [Cr(CN)5?x(H2O)xNO]x?3 by molecular oxygen in alkaline medium. In the case of the [Cr(CN)5NO]3? complex the reaction proceeded photochemically, whereas in othe cases the thermal oxidation was also observed. The influence of pH, CN? concentration and energy of radiation was investigated. 相似文献
993.
994.
Critical circle homeomorphisms have an invariant measure totally singular with respect to the Lebesgue measure. We prove that singularities of the invariant measure are of Hölder type. The Hausdorff dimension of the invariant measure is less than 1 but greater than 0.Partially supported by NSF grant #431-3604A 相似文献
995.
996.
Krystian Eitner Franz Bartl BogumiŁ Brzezinski Grzegorz Schroeder 《Supramolecular chemistry》2013,25(5):627-635
Abstract For macrocyclic bases such as: 1-aza-15-crown-5 (N15C5),1,4,10-trioxa-7,13-diazacyclopentadecan (21), 1,7,10,16-tetraoxa-4,13-diazacyclooctadecan (22) and 1, 4, 7, 13, 16-pentaoxa-10, 19-diazacycloheneicosane (23), the kinetics of deprotonation and protonation reactions in the presence of monovalent cations was studied using the temperature jump technique. For the sake of comparison, the measurements were also performed for 1,4-diazabicyclo[2,2,2]octane (DABCO) base, which does not form complexes with monovalent cations. The monovalent cations affect the temperature dependence of the kinetic parameters of deprotonation. They also affect the activation parameters, which is shown by a distribution of ΔH≠ and ΔS≠ values, but do not influence the value of ΔG≠. 相似文献
997.
Grzegorz Żołnierkiewicz Janusz Typek Niko Guskos Urszula Narkiewicz Daniel Sibera 《Central European Journal of Physics》2013,11(2):226-230
Magnetic properties of nanosize ZnO powders doped with MnO magnetic dopand have been studied. Sample designated as 0.10MnO/0.90ZnO was characterized by XRD that revealed the presence of ZnO and ZnMnO3 phases. An average size of magnetic ZnMnO3 nanocrystallites was 9 nm. Magnetic resonance study has been carried out in the 4-290 K temperature range. The spectrum at each temperature was analyzed in terms of three components. The temperature dependences of resonance field, linewidth and integrated intensity of these components have been determined. Magnetic centers responsible for producing the observed spectra have been proposed. 相似文献
998.
Grzegorz Derfel 《Liquid crystals》1991,10(5):647-658
The stability of the director field to deformations out of the plane of shear is examined by use of the Taylor expansion method based on catastrophe theory. For simple shear flow of nematics, the coming out of the shear plane is found for suitable surface alignment and not too high twist elastic constant. The role of these parameters is pointed out. Non-flow-aligning nematics are also considered, and results consistent with earlier reports are obtained. 相似文献
999.
Grzegorz Mlosto Jaroslaw Romaski Anthony Linden Heinz Heimgartner 《Helvetica chimica acta》1993,76(5):2147-2154
Thiocarbonyl Imides from the Reaction of 2,2,4,4-Tetramethyl-3-thioxocylobutanone and Aryl Azides Reaction of 2,2,4,4-tetramethyl-3-thioxocylobutanone ( 6 ) and 4-methoxyphenyl, phenyl, and 4-nitrophenyl azide ( 7a–c , respectively), at 80°, leads to the 11-aryl-5,10-dithia-11-azadispiro[3.1.3.2]undecane-2,8-diones 8a–c (Scheme 3), respectively, in 67–83% yield. The structure of 8b has been established by X-ray crystallography. The formation of the products may be explained via an intermediate thiocarbonyl imide of type D (Scheme 4), generated by the 1,3-dipolar cycloaddition of the aryl azide with the C? S bond of 6 and elimination of N2. 相似文献
1000.