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O. L. DE Lange 《Molecular physics》2013,111(4):607-611
We apply general arguments (based on spatial transformation properties, intrinsic symmetry and dimensional analysis) to the theory of the Buckingham effect (electric-field–gradient-induced birefringence in a gas). These yield, in a simple manner, the temperature-dependent and temperature-independent terms in the birefringence (each to within a numerical factor), and also the expression, derived by Buckingham and Longuet-Higgins, for the effective quadrupole centre of a molecule. We show in addition how the calculation of the two numerical factors can be simplified in our approach. 相似文献
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Qiu-Cheng Chen Zi-Ye Xiao Shachar Fite Dr. Amir Mizrahi Dr. Natalia Fridman Xuan Zhan Or Keisar Dr. Yair Cohen Prof. Dr. Zeev Gross 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(48):11383-11388
Although the affinity of metallocorroles to axial ligands is quite low, this is not the case when the chelated element is phosphorus. This work is hence focused on the mechanism of ligand exchange of six-coordinate phosphorus corroles as a tool for affecting their chemical and physical properties. These fundamental investigations allowed for the development of facile methodologies for the synthesis of a large series of complexes and the establishment of several new structure/activity profiles that may be used to understand and predict spectroscopic features and for tailor-made modification of photophysical and electrochemical properties. This is exemplified by the facile access to complexes with terminal groups that are of large potential for practical applications based on click chemistry, optical imaging, and surface science. 相似文献
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Nora Jannsen Dr. Stefano Diodati Nicola Dengo Francesca Tajoli Dr. Nicola Vicentini Dr. Giacomo Lucchini Prof. Adolfo Speghini Prof. Denis Badocco Prof. Paolo Pastore Prof. Silvia Gross 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(59):13624-13634
The aim of this work was i) to develop a hydrothermal, low-temperature synthesis protocol affording the upconverting hexagonal phase NaYF4 with suitable dopants while adhering to the “green chemistry” standards and ii) to explore the effect that different parameters have on the products. In optimizing the synthesis protocol, short reaction times and low temperatures (below 150 °C) were considered. Yb3+ and Er3+ ions were chosen as dopants for the NaYF4 material. Within the context of the second goal, parameters including nature of the precursors, treatment temperature, and treatment time were investigated to afford a pure hexagonal crystalline phase, both in the doped and undoped materials. To fully explore the synthesis results, the prepared materials were characterized from a structural (XRD), compositional (XPS, ICP-MS), and morphological (SEM) point of view. The upconverting properties of the compounds were confirmed by photoluminescence measurements. 相似文献
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Qiu-Cheng Chen Dr. Natalia Fridman Dr. Yael Diskin-Posner Prof. Dr. Zeev Gross 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(43):9481-9485
Palladium complexes of corrole and sapphyrin were prepared in high yield and fully characterized. The corrole provides a tetradentate/trianionic square planar coordination sphere for PdII, charge balanced by pyridinium. Both one and two PdII ions may be accommodated by the pentapyrrolic skeleton of the sapphyrin, and in each case the macrocycle acts as bidentate/monoanionic ligand and the inner-sphere square planar geometry is completed by allyl anions coordinated in an η3 fashion. NMR spectroscopy and X-ray crystallography data analyses uncovered the presence of interesting stereoisomers due to the flexibility of the ally ligands and also the pyrrole ring(s) that is/are not involved in metal binding. 相似文献
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Ricardo ABREU-BLAYA Juan BORY-REYES Fred BRACKX Hennie DE SCHEPPER Frank SOMMEN 《数学学报(英文版)》2012,(11)
A Hilbert transform for Hlder continuous circulant (2 × 2) matrix functions, on the d-summable (or fractal) boundary Γ of a Jordan domain Ω in R2n , has recently been introduced within the framework of Hermitean Clifford analysis. The main goal of the present paper is to estimate the Hlder norm of this Hermitean Hilbert transform. The expression for the upper bound of this norm is given in terms of the Hlder exponents, the diameter of Γ and a specific d-sum (d d) of the Whitney decomposition of Ω. The result is shown to include the case of a more standard Hilbert transform for domains with left Ahlfors-David regular boundary. 相似文献