全文获取类型
收费全文 | 114篇 |
免费 | 6篇 |
国内免费 | 6篇 |
专业分类
化学 | 105篇 |
晶体学 | 2篇 |
力学 | 4篇 |
综合类 | 1篇 |
数学 | 8篇 |
物理学 | 6篇 |
出版年
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 1篇 |
2017年 | 2篇 |
2016年 | 4篇 |
2015年 | 3篇 |
2014年 | 5篇 |
2013年 | 9篇 |
2012年 | 11篇 |
2011年 | 8篇 |
2010年 | 10篇 |
2009年 | 3篇 |
2008年 | 10篇 |
2007年 | 8篇 |
2006年 | 7篇 |
2005年 | 2篇 |
2004年 | 6篇 |
2003年 | 5篇 |
2002年 | 7篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1989年 | 1篇 |
1934年 | 2篇 |
1926年 | 1篇 |
排序方式: 共有126条查询结果,搜索用时 15 毫秒
101.
Sami Hietala Mikael Paronen Svante Holmberg Jan Nsman Jyrki Juhanoja Milja Karjalainen Ritva Serimaa Minna Toivola Tero Lehtinen Katri Parovuori Gran Sundholm Hanna Ericson Britta Mattsson Lena Torell Franciska Sundholm 《Journal of polymer science. Part A, Polymer chemistry》1999,37(12):1741-1753
A series of proton exchange membranes have been prepared by the preirradiation grafting method. Styrene was grafted onto a matrix of poly(vinylidene fluoride) (PVDF) after electron beam irradiation. Part of the samples was crosslinked with divinylbenzene (DVB) or bis(vinylphenyl)ethane (BVPE). Subsequent sulfonation gave membranes grafted with poly(styrene sulfonic acid) and marked PVDF‐g‐PSSA. It was found that the intrinsic crystallinity of the matrix decreased in both the grafting and the sulfonation reaction in all the membranes. The graft penetration and the ion conductivity are influenced strongly by the crosslinker. The ion conductivity is considerably lower in crosslinked membranes than in noncrosslinked ones. Generally, the mechanical strength decreases with crosslinking. The membranes show a regular phase separated structure in which the sulfonated grafts are incorporated in the amorphous parts of the matrix polymer. The phase separated domains are small, of the order of magnitude of 100–250 nm. These were resolved on transmission electron micrographs and on atomic force images but could not be resolved with microprobe Raman spectroscopy. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 1741–1753, 1999 相似文献
102.
Lan Xie Huan Xu Zhong‐Ming Li Minna Hakkarainen 《Macromolecular rapid communications》2016,37(9):745-751
The realization of hierarchical shish‐kebab structures for stereocomplex poly(lactic acid) (PLA) is achieved by the application of a shear flow (100 s–1 for 1 s) mimicking what can be expected during polymer processing. Compared to the normal shearing scenarios, this transient and strong shear flow enables the creation of dense shish precursors in time‐ and energy‐saving manner. The distribution of crystal form associated with the hierarchical structure is revealed by 2D Fourier transform infrared spectroscopy imaging, creating a unique visualization for both spatial resolution and polymorphism identification. Interestingly, in the shear stereocomplex chains are preferentially extended and crystallized as stable central cores with weak temperature dependence, whereas the development of lateral kebabs is defined by the distinct relation to the crystallization temperature. Below the melting point of homocrystals, both homo and stereocomplex crystallization are engaged in lamellar packing. Above that, exclusive stereocomplex crystals are organized into ordered lamellae. Combining the direct observations at multiscale, the ordered alignment of stereocomplex chains is recognized as the molecular origin of fibrillar extended chain bundles that constitute the central row‐nuclei. The proposed hypothesis affords elucidation of shish‐kebab formation and unique polymorphism in sheared stereocomplex PLA, which generates opportunities for engendering hierarchically structured PLA with improved performance.
103.
Minna Kortelainen Aku Suhonen Dr. Andrea Hamza Dr. Imre Pápai Dr. Elisa Nauha Dr. Sanna Yliniemelä‐Sipari Prof. Dr. Maija Nissinen Prof. Dr. Petri M. Pihko 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(26):9493-9504
A series of small, unsymmetrical pyridine‐2,6‐dicarboxylamide oligoamide foldamers with varying lengths and substituents at the end groups were synthetized to study their conformational properties and folding patterns. The @‐type folding pattern resembled the oxyanion‐hole motifs of enzymes, but several alternative folding patterns could also be characterized. Computational studies revealed several alternative conformers of nearly equal stability. These folding patterns differed from each other in their intramolecular hydrogen‐bonding patterns and aryl–aryl interactions. In the solid state, the foldamers adopted either the globular @‐type fold or the more extended S‐type conformers, which were very similar to those foldamers obtained computationally. In some cases, the same foldamer molecule could even crystallize into two different folding patterns, thus confirming that the different folding patterns are very close in energy in spite of their completely different shapes. Finally, the best match for the observed NOE interactions in the liquid state was a conformation that matched the computationally characterized helix‐type fold. 相似文献
104.
Satu Strandman Minna Luostarinen Satu Niemel Kari Rissanen Heikki Tenhu 《Journal of polymer science. Part A, Polymer chemistry》2004,42(17):4189-4201
Two novel multifunctional initiators for atom transfer radical polymerization (ATRP) were synthesized by derivatization of tetraethylresorcinarene. The derivatization induced a change in the conformation of the resorcinarene ring, which was confirmed by NMR spectroscopy. The initiators were used in ATRP of tert‐butyl acrylate and methyl methacrylate, producing star polymers with controlled molar masses and low polydispersities. Instead of the expected star polymers with eight arms, polymers with four arms were obtained. Conformational studies on the initiators by rotating‐frame nuclear Overhauser and exchange spectroscopy NMR and molecular modeling suggested that of eight initiator functional groups on tetraethylresorcinarene, four are too close to each other to be able to initiate the chain growth. Starlike poly(tert‐butyl acrylate) macroinitiators were used further in the block copolymerization of methyl methacrylate. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4189–4201, 2004 相似文献
105.
Kallio M Jussila M Raimi P Hyötyläinen T 《Analytical and bioanalytical chemistry》2008,391(6):2357-2363
A previously constructed semi-rotating cryogenic modulator was modified for comprehensive two-dimensional gas chromatography
(GC×GC). The retention time repeatability was improved by replacing the modulator control program unit with a new system.
Peak widths obtained with the modified modulator were comparable with those obtained with the previous modulator and other
modulator types. The modulator was easy to construct and it can be installed in any commercial GC system. The constructed
GC×GC–FID system and data obtained by gas chromatography–mass spectrometry (GC–MS) were used for identification of unknowns
in forest aerosol samples.
Figure A semi-rotating cryogenic modulator in which modulation is based on two-step cryogenic trapping with continuously flowing
carbon dioxide has been developed for comprehensive two-dimensional gas chromatography 相似文献
106.
Valkonen A Kolehmainen E Lahtinen M Sievänen E Noponen V Tolonen M Kauppinen R 《Molecules (Basel, Switzerland)》2007,12(9):2161-2178
The synthetic method for preparing N-(3-hydroxypropyl) 3 alpha,12 alpha-dihydroxy-5 beta-cholan-24-amide can lead to formation of at least three different crystal forms - an anhydrous compound and two monohydrates. The structural and thermal properties of these forms have been characterized by 13C-CP/MAS-NMR and IR spectroscopy, thermo- gravimetry, differential scanning calorimetry and by powder and single crystal x-ray crystallography. In addition, theoretical 13C-NMR chemical shift calculations were also performed for the anhydrous compound and for the first monohydrate, starting from single crystal structures and the structures of these species have now been verified. The first monohydrate, C27H47NO4 x H2O, crystallizes in orthorhombic space group P2(1)2(1)2(1) with cell parameters: a = 7.1148(2), b = 18.1775(5), c = 20.1813(6), Z = 4. 相似文献
107.
Abstract The aim of this study was to compare three different test methods for assaying the biodegradability of starch-based materials. The materials tested included some commercial starch-based materials and thermoplastic starch film prepared by extrusion from native potato starch and glycerol. Enzymatic hydrolysis was performed using excess Bacillus licheniformis α-amylase and Aspergillus niger glucoamylase at 37°C. The degree of degradation was assayed by measuring the dissolved carbohydrates and the weight loss of the samples. The head-space test was based on carbon dioxide evolution using sewage sludge as an inoculum. The composting experiments were carried out in an insulated commercial composter bin. The degradation was evaluated visually at weekly intervals, and the weight loss of the samples was measured after composting. Good correlation was found among the three different test methods. 相似文献
108.
Kari Ahonen Babita Behera Elina Siev?nen Arto Valkonen Manu Lahtinen Minna Tolonen Reijo Kauppinen Erkki Kolehmainen 《Structural chemistry》2010,21(1):185-190
The synthetic procedure of lithocholyl-N-(2-aminoethyl)amide yielded a mixture of several forms detected by solid state 13C CP/MAS NMR although the solution state NMR unambiguously ascertained that the compound was pure. By recrystallization from
various solvents one pure polymorph alongside with four solvates were isolated. The structures of the pure polymorph and the
solvates were characterized by 13C and 15N CP/MAS NMR and powder X-ray diffraction (PXRD) methods. Variable contact time and dipolar dephasing experiments were employed
to obtain optimized CP parameters and to distinguish various CH
n
(n = 0–3) resonances. CSA analyses of spinning side bands at different spinning rates showed small variations in the shielding
tensor values of the carbonyl group between the pure polymorph (recrystallized from acetonitrile, tetrahydrofuran and 1,4-dioxane)
and p-xylene solvate. 相似文献
109.
Annika Lindström Minna Hakkarainen 《Journal of Polymer Science.Polymer Physics》2007,45(13):1552-1563
Four poly(butylene adipate) (PBA) polyesters, the structure ranging from linear to highly branched, were synthesized and solution casted with poly(vinyl chloride) (PVC) in 20 or 40 wt % concentrations to evaluate the influence of polyester chain architecture on miscibility, surface segregation, and mechanical properties. The miscibility of PVC and polyesters is based on specific interactions between the carbonyl group in the polyester and PVC. These interactions cause a shift in the carbonyl absorption band in the FTIR spectra. The shifting of the carbonyl absorption band was more significant for all the 40 wt % blends compared with the blends containing 20 wt % of the same polyester. In the 20 wt % blends surface segregation and enrichment of polyester at the blend surface increased as a function of branching. However, all the films containing 40 wt % of polyester had similar surface composition. This is explained by better miscibility and stronger intermolecular interactions in the 40 wt % blends, which counteract the effect of branching on the surface segregation. High degree of branching resulted in poor miscibility with PVC and poor mechanical properties. A linear or slightly branched polyester structure, however, resulted in good miscibility and desirable blend properties. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1552–1563, 2007 相似文献
110.
Minna Kallio Maarit KivilompoloSami Varjo Matti JussilaTuulia Hyötyläinen 《Journal of chromatography. A》2009,1216(14):2923-2927
User-friendly and easy-to-use laboratory-written programs for visualisation and interpretation of comprehensive two-dimensional chromatographic data were developed. The programs that are not tied to any particular commercial instrument, and data obtained either by comprehensive two-dimensional liquid (LC × LC) or gas (GC × GC) chromatography can be analysed. Operations of the programs allow visualisation of 2D and 3D plots, comparison of two 2D plots at a time, as well as determination of retention times and peak heights and volumes. 相似文献