全文获取类型
收费全文 | 329914篇 |
免费 | 3044篇 |
国内免费 | 933篇 |
专业分类
化学 | 164769篇 |
晶体学 | 5374篇 |
力学 | 15531篇 |
综合类 | 7篇 |
数学 | 38464篇 |
物理学 | 109746篇 |
出版年
2021年 | 3132篇 |
2020年 | 3330篇 |
2019年 | 3760篇 |
2018年 | 5198篇 |
2017年 | 5439篇 |
2016年 | 7368篇 |
2015年 | 4139篇 |
2014年 | 7028篇 |
2013年 | 15904篇 |
2012年 | 12375篇 |
2011年 | 14824篇 |
2010年 | 11012篇 |
2009年 | 10913篇 |
2008年 | 13233篇 |
2007年 | 13191篇 |
2006年 | 12137篇 |
2005年 | 10520篇 |
2004年 | 9832篇 |
2003年 | 8685篇 |
2002年 | 8672篇 |
2001年 | 10393篇 |
2000年 | 7655篇 |
1999年 | 5967篇 |
1998年 | 4973篇 |
1997年 | 4811篇 |
1996年 | 4479篇 |
1995年 | 3864篇 |
1994年 | 3820篇 |
1993年 | 3701篇 |
1992年 | 4096篇 |
1991年 | 4306篇 |
1990年 | 4096篇 |
1989年 | 4008篇 |
1988年 | 3779篇 |
1987年 | 3917篇 |
1986年 | 3683篇 |
1985年 | 4629篇 |
1984年 | 4681篇 |
1983年 | 3885篇 |
1982年 | 3973篇 |
1981年 | 3697篇 |
1980年 | 3647篇 |
1979年 | 3913篇 |
1978年 | 3901篇 |
1977年 | 3906篇 |
1976年 | 3879篇 |
1975年 | 3675篇 |
1974年 | 3615篇 |
1973年 | 3650篇 |
1972年 | 2603篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
941.
An analysis of the effects of combined evaporation and quench periods on the formation of asymmetric membranes by the phase inversion technique is presented. The model for the evaporation period assumes binary diffusion and includes composition dependence in the mutual diffusion coefficient and free convection mass transfer in the gas phase. The quench period model includes the use of 4 composition-dependent diffusion coefficients and incorporates a modified from of the interface jump mass balance which enables efficient numerical analysis of composition gradients in the film at the beginning of the quench period. Results for the effects of evaporation-period variable, including: evaporation time, initial cast film thickness, casting surface dimension, and vapor-phase composition, clearly indicate that significant effects of the evaporation period on membrane structure formation and its reproducibility occur within 20 seconds. 相似文献
942.
Kinetics of oxidation of indigo carmine (IC) by sodium hypohalites, NaOX (X ? Cl or Br), in alkaline buffer of pH 9–11 has been studied spectrophotometrically at λ = 610 nm. The experimental rate law obtained is ?d[IC]/dt = k[OX?][IC][OH?]x where x <1. Variation of ionic strength or dielectric constant of the medium had no effect on the reaction rate while the addition of halide ions slightly retarded the rate. A most plausible mechanism proposed on the basis of experimental results involves the formation of isatin sulphonate which undergoes further oxidation to anthranilate. Activation parameters have been evaluated. 相似文献
943.
E. V. Zakharov S. N. Levchenko Yu. Ya. Kharlanov 《Computational Mathematics and Modeling》1997,8(3):282-287
The article considers the mathematical model of a lens antenna in the shape of a homogeneous dielectric torus excited by an
axial magnetic dipole. The boundary-value problem for an elliptical differential equation is posed and reduced by the fundamental
solution method to an integral equation of 2nd kind over the torus section. A numerical algorithm is proposed, and the numerical
results are compared with experimental findings.
Translated from Obratnye Zadachi Estestvoznaniya, Published by Moscow University, Moscow, 1997, pp. 109–115. 相似文献
944.
The impurity weakening of crystalline NaCl:Mg and NaCl:Mn associated with purification of the matrix in a melt is demonstrated.
This effect is manifested in a consistent change in the yield strength and mobility of dislocations. Its unusual temperature
dependence is determined: in a number of cases weakening becomes greater as the temperature is lowered within the interval
293–4.2 K. A deviation in the elastic region of the stress-strain curves is observed to increase as the temperature is lowered.
Plasticizing of crystalline NaCl is established: when the deformation temperature is lowered from 293 to 77 and 4.2 K the
rate of rise in the yield strength of Cd2+ and Sr2+ doped samples is lower than that of undoped samples. An explanation for this fact is proposed.
Fiz. Tverd. Tela (St. Petersburg) 39, 313–317 (February 1997)
Deceased. 相似文献
945.
R. P. Sundarraj P. S. Sundararaghavan Dale R. Fox 《The Journal of the Operational Research Society》1994,45(5):549-558
Several production and flexible manufacturing systems can naturally be modelled using queueing networks. In this paper, we consider the problem of acquiring servers for the nodes of an open queueing network, so as to optimize the steady-state mean virtual system parameters subject to a budget constraint. A partial enumeration scheme and a heuristic method have been proposed to solve this problem. Empirical results based on randomly generated test problems are used to identify a class of problems for which the heuristic performs well. 相似文献
946.
947.
J. S. Vrentas D. C. Venerus C. M. Vrentas 《Journal of Polymer Science.Polymer Physics》1991,29(5):537-545
An integral constitutive equation which includes strain-coupling effects is proposed. The constitutive equation is more general than the K-BKZ equation, and it is shown that this equation can explain various important aspects of double-step stress-relaxation data. 相似文献
948.
The stressed state of a rock mass in the vicinity of a preparatory working protected by a relief cavity is studied. A numerical study is made of the stress field and the relief zone, and the effect of length and slope of a slot on formation of the relief zone is clarified.Translated from Teoreticheskaya i Prikladnaya Mekhanika, No. 20, pp. 31–36, 1989. 相似文献
949.
Summary. In this paper we are interested in two phase flow problems in porous media. We use a Dual Mesh Method to discretize this
problem with finite volume schemes. In a simplified case (elliptic - hyperbolic system) we prove the convergence of approximate
solutions to the exact solutions. We use the Dual Mesh Method in physically complex problems (heterogeneous cases with non
constant total mobility). We validate numerically the Dual Mesh Method on practical examples by computing error estimates
for different test-cases.
Received March 21, 1997 / Revised version received October 13, 1997 相似文献
950.
IR and Raman spectra of (NH4)3ZnCl5 have been recorded. The observed spectra have been analysed on the basis of the vibrations of ZnCl
4
2−
and NH
4
+
ions. The appearance of multiple Raman bands indicates the presence of two different types of ammonium ions. The effect of
anisotropic crystalline field over the ZnCl4 and NH4 tetrahedra is also discussed. The assignment of internal modes has been verified by the potential energy distribution calculations. 相似文献