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11.
The mechanism of silicon epitaxy on porous Si(111) layers is investigated by the Monte Carlo method. The Gilmer model of adatom
diffusion extended to the case of arbitrary surface morphology is used. Vacancies and pendants of atoms are allowed in the
generalized model, the activation energy of a diffusion hop depends on the state of the neighboring positions in the first
and second coordination spheres, and neighbors located outside the growing elementary layer are also taken into account. It
is shown that in this model epitaxy occurs by the formation of metastable nucleation centers at the edges of pores, followed
by growth of the nucleation centers along the perimeter and the formation of a thin, continuous pendant layer. Three-dimensional
images of surface layers at different stages of epitaxy were obtained. The dependence of the kinetics of the epitaxy process
on the amount of deposited silicon is determined for different substrate porosities.
Pis’ma Zh. éksp. Teor. Fiz. 67, No. 7, 512–517 (10 April 1998) 相似文献
12.
S. B. Sakuta B. G. Novatsky D. N. Stepanov D. V. Aleksandrov Yu. A. Glukhov E. Yu. Nikol'sky 《Physics of Atomic Nuclei》2002,65(10):1771-1777
The (6Li, 7Be) and (6Li, 7Li) reactions on 6Li and 7Li nuclei were investigated in the angular interval 0°–20° in the laboratory system at a 6Li energy of 93 MeV. In addition to low-lying states of the 5,6He and 5,6Li nuclei, broad structures were observed near the t(3He)+d and t(3He)+t thresholds at the excitation energies of 16.75 (3/2+) and ~20 MeV (for 5He), 16.66 (3/2+) and ~20 MeV (5Li), 14.0 and 25 MeV (6He), and ~20 MeV (6Li). The angular distributions measured in the 7Li(6Li, 7Be)6He reaction for transitions to the ground state (0+) and excited states at E x=1.8 MeV (2+) and 14.0 MeV of the 6He nucleus were analyzed by the finite-range distorted-wave method assuming the 1p-and 1s-proton pickup mechanism. The (6Li, 7Be) and (6Li, 7Li) reactions were shown to proceed predominantly through the one-step pickup mechanism, and the broad structures observed at high excitation energies are considered as quasimolecular states of the t(3He)+d and t(3He)+t types. 相似文献
13.
14.
V. N. Charushin G. M. Petrova G. G. Aleksandrov L. G. Egorova A. I. Chernishev E. O. Sidorov N. A. Klyuev O. N. Chupakhin 《Chemistry of Heterocyclic Compounds》1987,23(4):426-435
Dibenzo[d,k]-1,3,6,10-tetraazatetracyclo[7.3.1.02,7.06,13]trideca-4,11-dienes undergo addition reactions at the C(2) carbon atom with alcohols and thiols, accompanied by cleavage of the C-N bond of the imidazoline ring, to generate diquinoxalino[1,2-a2,3-d]pyrrole derivatives.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 513–522, April, 1987. 相似文献
15.
16.
I. V. Aleksandrov 《Theoretical and Experimental Chemistry》1965,1(2):134-141
Some causes of spin-lattice relaxation in the solid state are considered. It is found that anisotropic hyperfine interaction can make an appreciable contribution to the spin-lattice relaxation time, which becomes dependent on the orientation of the radical relative to the external field and on the number of HS components. There is no appreciable contribution from frequency modulation of the vibrations (of the radical as a whole or purely intramolecular) caused by the lattice vibrations. 相似文献
17.
A. I. Nekhaev B. I. Kolobkov M. T. Toshev Kh. B. Dustov G. G. Aleksandrov 《Russian Chemical Bulletin》1991,40(4):827-830
Reaction of excess styrene with Fe3(CO)12 and sulfur (60°C, 15 h, Ar, S/Fe3(CO)12 0.6 g-atom/mole) gave Fe2(CO)6S2, Fe3(CO)9S2, Fe2(CO)6(S2CO), Fe2(CO)6S2(PhCHCH2), PhCHCH2S4, and a novel binuclear complex Fe2(CO)6(S2CH2S), whose structure was analyzed by x-ray crystallography. The crystals are monoclinic, a=7.764(3), b=13.205(4), c=6.628(6) Å, =98.97(3)°. V=671.2(7) Å3, Z=2, space group P21/m. The bond lengths are Fe-Fe 2.520(2), Fe-S 2.236(2), S-S 2.078(4), C-S 1.825(12), Fe-CO 1.784(8), and CO 1.148(9) Å.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 930–934, April, 1991. 相似文献
18.
Chen H Aleksandrov A Chen Y Zha S Liu M Orlando TM 《The journal of physical chemistry. B》2005,109(22):11257-11262
Polycrystalline gadolinia-doped ceria (GDC) surfaces were studied using low-energy (5-400 eV) electron stimulated desorption (ESD). H(+), O(+), and H(3)O(+) were the primary cationic desorption products with H(+) as the dominant channel. H(+), H(3)O(+), and O(+) have a 22 eV threshold followed by a yield change around 40 eV. H(+) also has an additional yield change approximately 75 eV and O(+) has an additional change approximately 150 eV. The O(+) ESD yield change approximately 150 eV may indicate bond breaking of Gd-O and the involvement of oxygen vacancies. The H(+) and H(3)O(+) threshold data collectively indicate the presence of hydroxyl groups and chemisorbed water molecules on the GDC surfaces. ESD temperature dependence measurements show that the interaction of water with GDC surface defect sites, mainly oxygen vacancies, influences the desorption of H(+), O(+), and H(3)O(+). The temperature dependence of the O(+) ESD at 400 eV incident electron energy yields a 0.21 eV activation energy. This is close to the energy needed for oxygen vacancy production next to a pair of Ce(3+) on a CeO(2) surface. These results may indicate a correlation between the O(+) ESD yield and oxygen vacancy density on GDC surfaces and a potential correlation of O(+) ESD and GDC ionic conductivity. 相似文献
19.
T. L. Pilicheva V. L. Rusinov O. N. Chupakhin N. A. Klyuev G. G. Aleksandrov S. E. Esipov 《Chemistry of Heterocyclic Compounds》1986,22(11):1250-1255
Non-charge-activated 6-nitroazolo[1,5-a]pyrimidines have been reacted with indoles, and the effects of substituents in the azole moiety of the substrate molecule have been examined.For communication 5, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenni, No. 11, 1544–1549, November, 1986. 相似文献
20.
Interaction of a low-pressure gas flame and heterogeneous catalytic processes on the reactor surface
Conclusions (1) It was shown that the Semenov theory in various modes of chain termination quantitatively describes oxyhydrogen combustion
near the first ignition limit with allowance for the interaction between the flame and the catalytic processes on the reactor
wall.
(2) Numerical modeling of oxyhydrogen ignition in the diffusion-controlled chain-termination mode detected the dependence
of the rate “constant” for heterogeneous chain initiation on the model of the reaction in the gas.
(3) For the first time, the change in the specific rate of heterogeneous chain initiation during a single ignition was determined.
(4) method for controlling the low-pressure flame mode by affecting tubes far from the reactor was proposed and applied.
Original Russian Text ? E.N. Aleksandrov, S.N. Kozlov, N.M. Kuznetsov, 2006, published in Doklady Akademii Nauk, 2006, Vol.
407, No. 5, pp. 630–633.
Presented by Academician A.E. Shilov October 5, 2005 相似文献