全文获取类型
收费全文 | 579篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 331篇 |
晶体学 | 7篇 |
力学 | 13篇 |
数学 | 77篇 |
物理学 | 160篇 |
出版年
2017年 | 4篇 |
2016年 | 8篇 |
2015年 | 4篇 |
2014年 | 8篇 |
2013年 | 30篇 |
2012年 | 19篇 |
2011年 | 17篇 |
2010年 | 19篇 |
2009年 | 35篇 |
2008年 | 22篇 |
2007年 | 9篇 |
2006年 | 22篇 |
2005年 | 19篇 |
2004年 | 23篇 |
2003年 | 13篇 |
2002年 | 7篇 |
2001年 | 15篇 |
2000年 | 16篇 |
1999年 | 10篇 |
1998年 | 6篇 |
1997年 | 8篇 |
1996年 | 4篇 |
1995年 | 14篇 |
1994年 | 7篇 |
1993年 | 13篇 |
1992年 | 13篇 |
1991年 | 13篇 |
1990年 | 9篇 |
1989年 | 10篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 7篇 |
1984年 | 10篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 15篇 |
1980年 | 10篇 |
1979年 | 6篇 |
1978年 | 8篇 |
1977年 | 8篇 |
1976年 | 8篇 |
1975年 | 12篇 |
1974年 | 6篇 |
1973年 | 7篇 |
1972年 | 7篇 |
1971年 | 5篇 |
1970年 | 4篇 |
1968年 | 3篇 |
1967年 | 5篇 |
1965年 | 3篇 |
排序方式: 共有588条查询结果,搜索用时 718 毫秒
101.
Mark P. Stockham Alice Griffiths Dr. Bo Dong Prof. Peter R. Slater 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(6):e202103442
Lithium garnets are promising solid-state electrolytes for next-generation lithium-ion batteries. These materials have high ionic conductivity, a wide electrochemical window and stability with Li metal. However, lithium garnets have a maximum limit of seven lithium atoms per formula unit (e.g., La3Zr2Li7O12), before the system transitions from a cubic to a tetragonal phase with poor ionic mobility. This arises from full occupation of the Li sites. Hence, the most conductive lithium garnets have Li between 6–6.55 Li per formula unit, which maintains the cubic symmetry and the disordered Li sub-lattice. The tetragonal phase, however, forms the highly conducting cubic phase at higher temperatures, thought to arise from increased cell volume and entropic stabilisation permitting Li disorder. However, little work has been undertaken in understanding the controlling factors of this phase transition, which could enable enhanced dopant strategies to maintain room temperature cubic garnet at higher Li contents. Here, a series of nine tetragonal garnets were synthesised and analysed by variable temperature XRD to understand the dependence of site substitution on the phase transition temperature. Interestingly the octahedral site cation radius was identified as the key parameter for the transition temperature with larger or smaller dopants altering the transition temperature noticeably. A site substitution was, however, found to make little difference irrespective of significant changes to cell volume. 相似文献
102.
Bob Boyd Gareth Brenton Eddie Clayton Jonathan Curtis R. M. Elliott G. A. Errock B. N. Green R. H. Bateman Simon J. Gaskell Iwan Griffiths Zdenek Herman Philip Jonathan Rich Kondrat Mila Laušević Chris Lock Deepak Mathur John F. J. Todd Károly Vékey 《Rapid communications in mass spectrometry : RCM》2016,30(11):1253-1264
103.
Griffiths G. Keegan E. Young E. Wotherspoon A. Palmer T. Lu K. Davis J. Alexander J. Jolly L. Nevers N. Delaunay F. Collins J. M. Dimayuga I. Bergeron A. Samuleev P. Dai Z. Holliday K. Robel M. Knight K. 《Journal of Radioanalytical and Nuclear Chemistry》2018,315(2):365-378
Journal of Radioanalytical and Nuclear Chemistry - Physical characterization is one of the most broad and important categories of techniques to apply in a nuclear forensic examination. Physical... 相似文献
104.
Ruthenium‐Containing Linear Helicates and Mesocates with Tuneable p53‐Selective Cytotoxicity in Colorectal Cancer Cells
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Simon J. Allison Dr. David Cooke Francesca S. Davidson Prof. Paul I. P. Elliott Dr. Robert A. Faulkner Hollie B. S. Griffiths Owen J. Harper Omar Hussain Prof. P. Jane Owen‐Lynch Prof. Roger M. Phillips Prof. Craig R. Rice Samantha L. Shepherd Dr. Richard T. Wheelhouse 《Angewandte Chemie (International ed. in English)》2018,57(31):9799-9804
The ligands L1 and L2 both form separable dinuclear double‐stranded helicate and mesocate complexes with RuII. In contrast to clinically approved platinates, the helicate isomer of [Ru2( L1 )2]4+ was preferentially cytotoxic to isogenic cells (HCT116 p53?/?), which lack the critical tumour suppressor gene. The mesocate isomer shows the reverse selectivity, with the achiral isomer being preferentially cytotoxic towards HCT116 p53+/+. Other structurally similar RuII‐containing dinuclear complexes showed very little cytotoxic activity. This study demonstrates that alterations in ligand or isomer can have profound effects on cytotoxicity towards cancer cells of different p53 status and suggests that selectivity can be “tuned” to either genotype. In the search for compounds that can target difficult‐to‐treat tumours that lack the p53 tumour suppressor gene, [Ru2( L1 )2]4+ is a promising compound for further development. 相似文献
105.
106.
Griffiths DV Al-Jeboori MJ Cheong YK Duncanson P Harris JE Salt MC Taylor HV 《Organic & biomolecular chemistry》2008,6(3):577-585
Dialkyl heteroaroylphosphonates based on thiophene, pyrrole or furan have been prepared and their reactions with trimethyl phosphite investigated. Deoxygenation of the carbonyl groups in these heteroaroylphosphonates occurs to give carbene intermediates, which then undergo further reaction. In the case of the furan-3-oylphosphonates and those systems containing a thiophene or pyrrole ring, the major reaction pathway involves intermolecular trapping of the carbene intermediates by the trimethyl phosphite, leading to the formation of ylidic phosphonates that can be readily converted into the corresponding 1,1-bisphosphonates. However, in some furan-2-oylphosphonates the carbenes generated undergo ring-opening to initially give acyclic alkynylphosphonates which may react further to give other novel phosphorus compounds. The effects of substituents on the extent to which intermolecular trapping of the initially formed carbene competes with intramolecular rearrangement has been investigated. The latter process appears to be suppressed by a substituent at the 5-position of the furan ring, the resulting ylidic phosphonates being a rare example of an efficient intermolecular trapping of a furan-2-yl carbene. 相似文献
107.
Kieran?Griffiths Albert?EscuerView authors OrcID profile George?E.?KostakisEmail author 《Structural chemistry》2016,27(6):1703-1714
This article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters formulated [Ni 3 II Na(L1)3(HL1)(MeOH)2] (1) and [Ni 6 II Na(L1)5(CO3)(MeO)(MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi-rigid Schiff base ligand (E)-2-(2-hydroxy-3-methoxybenzylideneamino)-phenol). Compound 1 possesses a rare Ni 3 II NaI cubane (3M4-1) topology, and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology. 相似文献
108.
Martin Griffiths Surajit Rajagopal 《International Journal of Mathematical Education in Science & Technology》2016,47(1):139-144
In this article, we describe the outcome of a mathematical collaboration between a university lecturer and an undergraduate student. The resulting investigation concerned a particular divisibility property of the Fibonacci numbers, and indeed it seems that a new result was found in this regard. An interesting point to be made here is that, although the mathematical content was relatively straightforward, this joint exploration did, in a very modest sense, mirror certain key aspects of the research process. 相似文献
109.
Martin Griffiths Jonny Griffiths 《International Journal of Mathematical Education in Science & Technology》2016,47(2):291-298
We study here a pair of sequences of polynomials that arise from a particular iterated mapping on the plane. We show how these sequences come about, and give some of their interesting mathematical properties. 相似文献
110.
Gonzalo Fiz Pontiveros Simon Griffiths Robert Morris David Saxton Jozef Skokan 《Combinatorica》2016,36(1):71-89
The Ramsey number r(K 3,Q n ) is the smallest integer N such that every red-blue colouring of the edges of the complete graph K N contains either a red n-dimensional hypercube, or a blue triangle. Almost thirty years ago, Burr and Erd?s conjectured that r(K 3,Q n )=2 n+1?1 for every n∈?, but the first non-trivial upper bound was obtained only recently, by Conlon, Fox, Lee and Sudakov, who proved that r(K 3,Q n )?7000·2 n . Here we show that r(K 3,Q n )=(1+o(1))2 n+1 as n→∞. 相似文献