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排序方式: 共有847条查询结果,搜索用时 250 毫秒
841.
Petr Gregor 《Discrete Mathematics》2009,309(6):1711-1713
Recently, Fink [J. Fink, Perfect matchings extend to Hamilton cycles in hypercubes, J. Combin. Theory Ser. B 97 (2007) 1074-1076] affirmatively answered Kreweras’ conjecture asserting that every perfect matching of the hypercube extends to a Hamiltonian cycle. We strengthen this result in the following way. Given a partition of the hypercube into subcubes of nonzero dimensions, we show for every perfect matching of the hypercube that it extends on these subcubes to a Hamiltonian cycle if and only if it interconnects them. 相似文献
842.
Chizhik AI Gregor I Schleifenbaum F Müller CB Röling C Meixner AJ Enderlein J 《Physical review letters》2012,108(16):163002
We investigate the impact of rotational diffusion on the electrodynamic coupling of fluorescent dye molecules (oscillating electric dipoles) to a tunable planar metallic nanocavity. Fast rotational diffusion of the molecules leads to a rapidly fluctuating mode density of the electromagnetic field along the molecules' dipole axis, which significantly changes their coupling to the field as compared to the opposite limit of fixed dipole orientation. We derive a theoretical treatment of the problem and present experimental results for rhodamine 6G molecules in cavities filled with low and high viscosity liquids. The derived theory and presented experimental method is a powerful tool for determining absolute quantum yield values of fluorescence. 相似文献
843.
Julian Kund Jan-Hendrik Kruse Andreas Gruber Dr. Ivan Trentin Marcel Langer Dr. Clarissa Read Dr. Gregor Neusser Dominik Blaimer Dr. Ulrich Rupp Prof. Dr. Carsten Streb Prof. Dr. Kerstin Leopold Prof. Dr. Felix H. Schacher Prof. Dr. Christine Kranz 《Angewandte Chemie (International ed. in English)》2023,62(22):e202217196
Heterogeneous light-driven catalysis is a cornerstone of sustainable energy conversion. Most catalytic studies focus on bulk analyses of the hydrogen and oxygen evolved, which impede the correlation of matrix heterogeneities, molecular features, and bulk reactivity. Here, we report studies of a heterogenized catalyst/photosensitizer system using a polyoxometalate water oxidation catalyst and a model, molecular photosensitizer that were co-immobilized within a nanoporous block copolymer membrane. Via operando scanning electrochemical microscopy (SECM), light-induced oxygen evolution was determined using sodium peroxodisulfate (Na2S2O8) as sacrificial electron acceptor. Ex situ element analyses provided spatially resolved information on the local concentration and distribution of the molecular components. Infrared attenuated total reflection (IR-ATR) studies of the modified membranes showed no degradation of the water oxidation catalyst under the reported light-driven conditions. 相似文献
844.
845.
Dr. Irena Senkovska Dr. Volodymyr Bon Dr. Leila Abylgazina Dr. Matthias Mendt Jan Berger Dr. Gregor Kieslich Prof. Petko Petkov Jhonatan Luiz Fiorio Dr. Jan-Ole Joswig Prof. Thomas Heine Larissa Schaper Christopher Bachetzky Prof. Rochus Schmid Prof. Roland A. Fischer Prof. Andreas Pöppl Prof. Eike Brunner Prof. Dr. Stefan Kaskel 《Angewandte Chemie (International ed. in English)》2023,62(33):e202218076
Flexible porous frameworks are at the forefront of materials research. A unique feature is their ability to open and close their pores in an adaptive manner induced by chemical and physical stimuli. Such enzyme-like selective recognition offers a wide range of functions ranging from gas storage and separation to sensing, actuation, mechanical energy storage and catalysis. However, the factors affecting switchability are poorly understood. In particular, the role of building blocks, as well as secondary factors (crystal size, defects, cooperativity) and the role of host–guest interactions, profit from systematic investigations of an idealized model by advanced analytical techniques and simulations. The review describes an integrated approach targeting the deliberate design of pillared layer metal–organic frameworks as idealized model materials for the analysis of critical factors affecting framework dynamics and summarizes the resulting progress in their understanding and application. 相似文献
846.
847.
Franziska Hausig-Punke Gregor Dekevic Fabian H. Sobotta Jana I. Solomun Friederike Richter Denise Salzig Anja Traeger Johannes C. Brendel 《Macromolecular bioscience》2023,23(5):2370016
Cationic pH-responsive polymers promise to overcome critical challenges in cellular delivery. Ideally, the polymers become selectively charged along the endosomal pathway disturbing only the local membrane and avoiding unintended interactions or cytotoxic side effects at physiological conditions. Polypiperazines represent a novel, hydrophilic class of pH-responsive polymers whose response can be tuned within the relevant pH range (5–7.4). The authors discovered that the polypiperazines are effectively binding plasmid DNA (pDNA) and demonstrate high efficiency in transfection. By design of experiments (DoE), a wide parameter space (pDNA and polymer concentration) is screened to identify the range of effective concentrations for transfection. An isopropyl modified polypiperazine is highly efficient over a wide range of concentrations outperforming linear polyethylenimine (l-PEI, 25 kDa) in regions of low N*/P ratios. A quantitative polymerase chain reaction (qPCR) surprisingly revealed that the pDNA within the piperazine-based polyplexes can be amplified in contrast to polyplexes based on l-PEI. The pDNA must therefore be more accessible and bound differently than for other known transfection polymers. Considering the various opportunities to further optimize their structure, polypiperazines represent a promising platform for designing effective soluble polymeric vectors, which are charge-neutral at physiological conditions. 相似文献