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791.
Martina Sandholzer Alexandra Lex Gregor Trimmel Robert Saf Franz Stelzer Christian Slugovc 《Journal of polymer science. Part A, Polymer chemistry》2007,45(7):1336-1348
A convenient synthetic route towards polymerizable fluorescein, dicholorofluorescein, and eosin dyes is presented. Polymerizability was provided by linking 2‐norbornene carboxylic acid, 11‐bromo‐undecyl ester to the dye's carboxylate functionality. Although the monomers bearing dichlorofluorescein and eosin were obtained in high yield, the related fluorescein bearing monomer could only be obtained in low yield. In the latter case, concurring etherification and esterification led to a product mixture of the desired carboxy modified monomer and a double substituted by‐product. The dye‐monomers were used successfully for the preparation of statistical copolymers with endo,exo‐2,3‐norbornene dicarboxylic acid dimethylester by ROMP. Absorption and luminescence characteristics and, in particular, the acid/base sensitive behavior of the parent dyes were preserved in the monomers and copolymers. The absorption and emission maxima in THF solution and in the solid state were red shifted in comparison to the aqueous samples of the parent dyes. Dye‐copolymers exhibited good film forming properties. Solid state luminescence studies of the copolymers revealed an increasing sensitivity towards NEt3 vapor in the order fluorescein < dichlorofluorescein < eosin bearing copolymer. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1336–1348, 2007 相似文献
792.
793.
794.
P. Gregor 《Analytical and bioanalytical chemistry》1899,38(6):371-372
795.
796.
Gregor Dolinar Shuanping Du Jinchuan Hou Peter Legia 《Linear algebra and its applications》2008,429(1):100-109
Let be the space of all bounded linear operators on a Banach space X and let LatA be the lattice of invariant subspaces of the operator . We characterize some maps with one of the following preserving properties: Lat(Φ(A)+Φ(B))=Lat(A+B), or Lat(Φ(A)Φ(B))=Lat(AB), or Lat(Φ(A)Φ(B)+Φ(B)Φ(A))=Lat(AB+BA), or Lat(Φ(A)Φ(B)Φ(A))=Lat(ABA), or Lat([Φ(A),Φ(B)])=Lat([A,B]). 相似文献
797.
Georg Gregor 《Fresenius' Journal of Analytical Chemistry》1894,33(1):30-45
Ohne Zusammenfassung 相似文献
798.
799.
Total electron yields for perpendicular impact of C+ ions on W have been measured for projectile energies from 0.2 keV to 7 keV. The data are compared with the data of C+ bombardment of gold and graphite in order to demonstrate general trends in kinetic electron yields at low projectile velocities. The total electron yields in the studied combinations of projectiles and substrates show a similar exponential dependence Γ ∝ (v/A) exp(−A/v), where A is a constant and v is the projectile velocity. 相似文献
800.
M.A. Gregor F. Seffrin F. Fuest D. Geyer A. Dreizler 《Proceedings of the Combustion Institute》2009,32(2):1739-1746
Instantaneous measurements of temperature, equivalence ratio, and major species were performed along a one-dimensional probe volume using simultaneous Raman/Rayleigh scattering in an unconfined turbulent lean-premixed swirling methane/air flame. Temperature was determined from Rayleigh scattering and the major species, CO2, O2, N2, CH4, H2O, and H2 from Raman scattering. Effective Rayleigh cross-sections were corrected using the local chemical composition obtained from Raman scattering. These experiments were conducted to investigate the compositional structure of a lean-premixed swirling flame in detail and to complement previous measurements of the underlying flow field. The flame was classified within a revised regime diagram at the cross-over between corrugated flames and thin reaction zones. Instantaneous temperature profiles varied significantly showing shapes ranging from laminar-like flamelets to mixing between reacted fluid elements and secondary air. Different thermo-kinetic states could be assigned to the inner and outer recirculation zones and to the inner and outer mixing layers. Linked to published velocity data of this flame, the present multi-scalar data are useful for validation of numerical simulations. 相似文献