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101.
102.
Ab initio calculations are carried out to determine γΠ (true), the first-order contribution to the spin-rotation constant, γΠ, for the X2Π ground states of OH, HF+, and HCl+ and their deuterated analogs. These calculations demonstrate that the contribution of this term to the experimentally determined value of γΠ is small, as has been previously conjectured. Furthermore, it is found in the cases under study that the Van Vleck approximation to γΠ (true) significantly overestimates its importance, and a more realistic approximation is presented. 相似文献
103.
The S-wave annihilation contribution to the pp? inelastic cross section at low energies is calculated in a quark-antiquark rearrangement model which includes the effect of NΔ̄ + N?Δ and ΔΔ̄ intermediate states. This mechanism, which leads automatically to a separable interaction, is able to account for about 15% of the observed cross section. The extension of the model to P-waves is also outlined. 相似文献
104.
Decleva P Fronzoni G Stener M de Simone M Coreno M Green JC Hazari N Plekan O 《Physical review letters》2005,95(26):263401
Photoemission from the two outermost ionizations [highest occupied molecular orbitals (HOMO and HOMO-1)] of Mg(eta(5)-C(5)H(5))(2) has been studied with synchrotron radiation in the gas phase. Strong oscillations in the HOMO-1/HOMO ratio, qualitatively similar to those well-known for fullerenes, are found. Excellent agreement with the experimental ratio is provided by accurate cross section calculations both at the density-functional theory and time-dependent density-functional theory level, indicating that a many electron response has a minor role for this effect. A comparison with the calculated values for other metal sandwich compounds indicate that the presence of oscillations is a widespread phenomenon, and a potential source of interesting information on the structural and electronic properties of the target molecule. 相似文献
105.
Reznikov et al. [Phys. Rev. Lett. 75, 3340 (1995)]] have presented definitive observations of nonequilibrium noise in a quantum point contact. Especially puzzling is the "anomalous" peak structure of the excess noise measured at constant current; to date it remains unexplained. We show that their experiment directly reveals the deep link between conservation principles in the electron gas and its low-dimensional, mesoscopic behavior. The keys to that connection are gauge invariance and the compressibility sum rule. These are central not only to the experiment of Reznikov et al., but to the very nature of all mesoscopic transport. 相似文献
106.
We have measured the circular polarization of light emitted from both atomic H and molecular H2 after bombarding H2 with longitudinally polarized electrons. For both atomic and molecular fluorescence near threshold we observe a circular polarization as great as 10% of the electron polarization. This represents the first direct observation of spin transfer in electron-molecule collisions. 相似文献
107.
Background
Growth hormone (GH) plays an incompletely understood role in the development of the central nervous system (CNS). In this study, we use transgenic mice expressing a growth hormone antagonist (GHA) to explore the role of GH in regulating postnatal brain, spinal cord and body growth into adulthood. The GHA transgene encodes a protein that inhibits the binding of GH to its receptor, specifically antagonizing the trophic effects of endogenous GH. 相似文献108.
Superficially, the free disposal hull production possibility set (pps) can be regarded as a binary version of the Banker, Charnes and Cooper pps, in which only one component of the vector, λ, is non-zero and of necessity equal to 1. We therefore propose, by analogy with a pps due originally to Koopmans, a new pps which retains the binary characteristic of the components of λ but permits more than one component to be non-zero. Thus, a given DMU's performance is assessed not only against the individual DMUs included in the sample but also against composite DMUs obtained by simple aggregation. This approach is demonstrated and investigated on a published data set. 相似文献
109.
R.M. Green 《Journal of Algebraic Combinatorics》2004,19(2):173-196
Heaps of pieces were introduced by Viennot and have applications to algebraic combinatorics, theoretical computer science and statistical physics. In this paper, we show how certain combinatorial properties of heaps studied by Fan and by Stembridge are closely related to the properties of a certain linear map
E
associated to a heap E. We examine the relationship between
E
and
F
when F is a subheap of E. This approach allows neat statements and proofs of results on certain associative algebras (generalized Temperley–Lieb algebras) that are otherwise tricky to prove. The key to the proof is to interpret the structure constants of the aforementioned algebras in terms of the maps . 相似文献
110.
Understanding the expression of known and unknown gene products represents one of the key challenges in the post-genomic world. Here, we have developed a new class of reagents to examine protein expression in vivo that does not require transfection, radiolabeling, or the prior choice of a candidate gene. To do this, we constructed a series of puromycin conjugates bearing various fluorescent and biotin moieties. These compounds are readily incorporated into expressed protein products in cell lysates in vitro and efficiently cross cell membranes to function in protein synthesis in vivo as indicated by flow cytometry, selective enrichment studies, and Western analysis. Overall, this work demonstrates that fluorescent-puromycin conjugates offer a general means to examine protein expression in vivo. 相似文献