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排序方式: 共有174条查询结果,搜索用时 265 毫秒
141.
142.
143.
W. H. Woodcock G. Coffetti R. H. Greaves und C. Offerhaus 《Fresenius' Journal of Analytical Chemistry》1919,58(4):165-167
Ohne Zusammenfassung 相似文献
144.
Alasdair K. Cooper Megan E. Greaves William Donohoe Paul M. Burton Thomas O. Ronson Alan R. Kennedy David J. Nelson 《Chemical science》2021,12(42):14074
A nickel/dppf catalyst system was found to successfully achieve the Suzuki–Miyaura cross-coupling reactions of 3- and 4-chloropyridine and of 6-chloroquinoline but not of 2-chloropyridine or of other α-halo-N-heterocycles. Further investigations revealed that chloropyridines undergo rapid oxidative addition to [Ni(COD)(dppf)] but that α-halo-N-heterocycles lead to the formation of stable dimeric nickel species that are catalytically inactive in Suzuki–Miyaura cross-coupling reactions. However, the corresponding Kumada–Tamao–Corriu reactions all proceed readily, which is attributed to more rapid transmetalation of Grignard reagents.Nickel complexes with a dppf ligand can form inactive dinickel(ii) complexes during Suzuki–Miyaura cross-coupling reactions. However, these complexes can react with Grignard reagents in Kumada–Tamao–Corriu cross-coupling reactions. 相似文献
145.
R. Padilla Alvarez E. Chinea Cano J. R. Estévez Alvarez E. D. Greaves 《Journal of Radioanalytical and Nuclear Chemistry》1999,240(2):517-522
“Cut-off” reflectors, which allow obtaining a reflected beam with almost no high energy radiation, as well as different monochromator
devices that reflect a beam of monoenergetic and polarized radiation are the most widely employed artifacts to perform the
excitation radiation improvement in analytical “non-expensive” TR spectrometers. The aim of this work consisted in testing
several monochromator devices: a multilayer structured mirror for soft X-rays (0.7–12.5 nm), as well as different bent and
flat crystals of wavelength dispersive spectrometers. The achieved instrumental detection limits for the selected monochromator
device are compared with the values obtained using a Suprasil Cut-off reflector and a C-W multilayer (d∼5 nm). Several human corporal fluid samples were analyzed to compare the spectral characteristics when using the Cut-Off
Reflector and the RAP flat crystal, respectively. 相似文献
146.
A mathematical model is proposed for the process of vacuum superplasticforming. The model exploits the fact that in most industrialapplications the sheet aspect ratio (thickness/sheet width)is small. After an initial consideration of some of the moregeneral properties and the literature of superplastic materials,the elastic/plastic deformation of an internally-inflated thin-walledcylinder is examined. Plates of arbitrary geometry are thenconsidered. A quasisteady model in which the sheet moves througha sequence of steady states is developed. Some simplified closed-formsolutions are examined, but for general cases a system of nonlinearpartial differential equations must be solved numerically. Anefficient and accurate semi-explicit numerical scheme is proposedand a simplified stability analysis is presented; the methodis then used to compute properties of superplastic vacuum mouldedsheets in a number of practically motivated cases. 相似文献
147.
L. Saj-Bohus J. Plfalvi F. Urbani D. Castro E. D. Greaves J. A. Liendo 《Radiation measurements》1999,31(1-6):283-286
Environmental gamma exposure and radon concentration levels measured in Venezuelan regions are presented. A new generation image analyser was used for particle track counting in CR-39 detectors. Mineral water wells from where water is supplied for massive consumption have an alpha activity around 0.450 Bq L−1 and few of them have concentrations above 50 Bq L−1. Coastal potable water activity is on the average around 5.3 ± 12% Bq L−1. Indoor radon national average is 36 ± 5% Bq m−3; in two of the 36 monitored sites, the measured average is above 400 ± 5% Bq m−3. In air gamma dose values are between 100 and 144 nGy h−1. In soil, 137Cs concentration is around 0.5 and 10 Bq kg−1 at the depth of down to 20 cm. Building materials were included in this study. 7Be and 137Cs were measured in low concentration in tropical plants on Tepuy-s (sacred mountains in the Amazonas State). Geological active faults were identified by radon concentration measurements using LR-115. 相似文献
148.
G. Greaves 《Numerische Mathematik》1982,39(2):231-238
149.
The true potential energy curves forX
1
Σ
+, a3
π
r,A
1
π,e
3
Σ
−,E
1
Σ
+,c
3
π
i states of astrophysically important molecule SiO, whose spectra were observed in the sunspots, have been constructed using
the method of Lakshman and Rao. Dissociation energy and ionization potential have been estimated as 65,350 cm−1 and 92,854 cm−1 respectively and found to be in good agreement with the values cited in literature.
The true potential energy curves forX
1
Σ
+,D
1
π andE
1
Σ
+ states of SiS molecule have been constructed by the same method and its dissociation energy in the ground state has been
estimated using Hulburt-Hirschfelder potential function as 54,765 cm−1 in good agreement with 53,250.9 cm−1 given by Herzberg. 相似文献
150.