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71.
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74.
Summary With the resonant photomeission technique we investigated the valence bands of FePS3 and NiPS3. The experimental results, support the ionic picture of the compounds and our previous identification of the valence band
structures. The structures rapidly varying in intensity when the excitation energy is scanned across the Fe and NiM
2,3 absorption edge are associated to the transition metal 3d states; the nonresonating features are ascribed to the (P2P6)4− cluster states. With the yield technique we measured the high-resolution absorption spectra of the phosphorus and sulphur
inner-core levels in Mn, Fe and Ni thiophosphates. TheL
2,3(P) andL
2,3(S) spectra are similar to each other in all the compounds and are interpreted in terms of the projected density of states
of the conduction bands derived from the (P2S6)4− cluster states.
To speed up publication, the authors of this paper have agreed to not receive the proofs for correction. 相似文献
75.
Summary An ion-beam-assisted deposition (IBAD) technique, based on reactive evaporation using hydrogen/ methane gas mixture, has been
used for the preparation ofa-Si1−x
C
x
: H films. Measurements are reported on the composition, optical gap, infra-red vibrational absorption bands and on the electrical
dark-conductivity temperature dependence to verify the reliability of this deposition method. On increasing the compositional
parameterx up to 0.35, the IR results show an increasing hydrogenation and the presence of Si-CH3 units in addition to the ones with the carbon fully coordinated with the silicon, while the optical-gap and the dark-conductivity
activation energies reached the values of 2.44 eV and 0.77 eV, respectively.
The authors of this paper have agreed to not receive the proofs for correction 相似文献
76.
R. D’Agata G. Grasso S. Parlato S. Simone G. Spoto 《Applied Physics A: Materials Science & Processing》2007,89(1):91-95
The study of ancient works of art is a very challenging task, mainly due to the impossibility of applying experimental approaches
that could damage anyhow the object from which analytical information has to be obtained. Spatially resolved analytical methods
have significantly enhanced our capacity to study ancient material since they cause minimal and at times no damage to the
studied object. Unfortunately, only a few analytical techniques operating within the requested spatial resolution are applicable
for the investigation of the organic components of artistic and archaeological objects.
In this work, iron-gall ink was prepared according to ancient recipes and its composition was evaluated by AP/MALDI-MS. The
latter is demonstrated to be a very valuable tool for the study of the organic components of ancient works of art as it combines
the advantages of the vacuum MALDI-MS analytical approach to the possibility of analysing samples in air. In situ analyses
were also carried out by analysing strokes of ink directly from paper and parchment.
PACS 82.80.Ms; 61.66.Hq; 87.14.-g 相似文献
77.
Giuseppe Buemi Felice Zuccarello Antonio Raudino Domenico Grasso 《Journal of Molecular Structure》1980
The strain energy of the most probable conformers of 1,3,6-cyclononatriene and 1,3,6-cyclodecatriene, which are asymmetrical compounds, has been calculated as a function of various geometrical parameters by means of the semiempirical Hendrickson's treatment, partially modified. The most stable conformation of 1,3,6-cyclononatriene is a member of the all-cis family, while a transcis-trans structure is the most stable among the 1,3,6-cyclodecatriene conformations. In this latter compound however, the energy minima of the all-cis, trans-cis-cis, and cis-cis-trans conformers also appear to be close to each other. Some possible interconversions are also discussed. 相似文献
78.
Calorimetric data on the mesogenic homologous series H9C4OC6H4NCHC6H4OCnH2n + 1 are presented. Trends in the nematic-isotropic liquid transition temperatures, enthalpies and entropies are briefly discussed. A remarkable polymorphism is evidenced in several compounds. The importance of the thermal history of the samples in relation to their thermal behavior is shown. 相似文献
79.
Over one hundred quenched melts containing lithium, other alkali, and/or alkali earth or other divalent metal sulfates were examined by differential thermal analysis and powder X-ray diffraction. Glasses formed in many of these quenches, but pure glass generally was obtained only in ternary compositions and even then only in limited concentration ranges. Ionic conductivities ranged up to 10?3 (Ω cm)?1. Systematic variations, of the Li concentration and of ionic sizes, for example, were investigated. No factors were found which could be clearly correlated with either the occurrence of glass or the magnitude of the ionic conductivity. 相似文献
80.
A. Balzarotti R. Girlanda V. Grasso E. Doni F. Antonangeli M. Piacentini A. Baldereschi 《Solid State Communications》1977,24(4):327-329
The X-ray photoelectron spectrum of InSe is reported and interpreted on the basis of a tight-binding calculation which neglects interlayer interactions. The proposed band structure is also in reasonable agreement with the experimental energy bands recently obtained from angle-resolved photoemission. 相似文献