A phenomenological quark matter equation of state

Both the MIT bag model and potential models are able to reproduce static properties of hadrons (e.g. their mass spectrum) with reasonable accuracy. However, while the extrapolation of the MIT bag model from hadrons to dense matter is rather straightforward, it is not the same for potential models. To deal with this problem, in this paper, the methods of relativistic quantum many-body theory are applied to the study of quark matter interacting through an instantaneous potential at zero temperature. It is shown that under some conditions, the quark plasma undergoes a first order transition from a massive state at low density to a gas of particles of decreasing mass at high density—as one expects from perturbative QCD. In addition, immediately after the transition, the quarks are in a collective bound state, which might perhaps be interpreted as the fact that they just start to leave the inside of hadrons.     

Comparing particle emission scenarios in hydrodynamics: Continuous emission vs. freeze-out

The usual particle emission scenario used in hydrodynamics presupposes that particles instantaneously stop interacting (freeze-out) once they reach some three dimensional surface. Another formalism has been developed recently where particle emission occurs continuously during the whole expansion of thermalized matter. Here we compare both mechanisms in a simplified hydrodynamical framework and show that they lead to a drastically different interpretation of data.     

Generation of Chaotic Beats in a Modified Chua's Circuit Part I: Dynamic Behaviour

This paper and the companion one [Cafagna, D. and Grassi, G., Nonlinear Dynamics, this issue] present the new phenomenon of chaotic beats in non-autonomous Chua's circuit, driven by two sinusoidal inputs with slightly different frequencies. In particular, in this paper the behaviour of the proposed circuit is analyzed both in time-domain and state-space, confirming the chaotic nature of the phenomenon and the effectiveness of the design.     

113Cd NMR and fluorescence studies of multiple binding mechanisms of Cd(II) by the Suwannee River fulvic acid

The binding of Cd (II) by the fulvic acid from a Suwannee River (FA) was investigated at various pH values and reactants ratios by 113Cd NMR and fluorescence spectroscopy. The NMR results provided evidences that the FA-Cd interactions occur through a variety of binding modes and mechanisms. Different kinds of organically bound Cd-species were detected in the 1.8-10.8 pH range depending on the FA/Cd ratios. Labile complexes (amenable to Cd-aminoacidic and Cd-hydroxy interactions or outer-sphere complexes) were observed at low pH and FA/Cd levels while stronger interactions (of carboxylate-type or inner-sphere complexation) took place as the pH and/or the FA concentration were increased. At pH ca. 6 insoluble FA-Cd adducts were primarily produced but, at relatively large FA concentration, only soluble complexes, stable in the whole pH 1.8-10.8 range, were formed. A complementary analysis, by fluorescence spectroscopy, provided clear evidences of FA-Cd association/aggregation phenomena. While no noticeable effects occurred with soluble samples, the formation of insoluble adducts led to significant enhancements of the emission fluorescence spectra. Although other explanations could not be excluded, this result was accounted for by modifications of the optical properties of the ligand itself due to sedimentation of the heavier components. Fluorescence enhancement was also observed on samples before the effective precipitation and interpreted as spectroscopic evidence of the onset of aggregation phenomena.     

Fermionic wigs for BTZ black holes

We compute the wig for the BTZ black hole, namely the complete non-linear solution of supergravity equations with all fermionic zero modes. We use a “gauge completion” method starting from _AdS3${\mathit{AdS}}_3$ Killing spinors to generate the gravitinos fields associated to the BH and we compute the back-reaction on the metric. Due to the anticommutative properties of the fermionic hairs the resummation of these effects truncates at some order. We illustrate the technique proposed in a precedent paper in a very explicit and analytical form. We also compute the mass, the angular momentum and other charges with their corrections.     

Polymerization of 1-vinylcyclohexene in the presence of group 4 metallocenes – MAO catalysts

1-Vinylcyclohexene was polymerized in the presence of several homogeneous catalytic systems consisting of methylaluminoxane and group 4 metallocenes such as CpTiCl₃, [isopropyl(cyclopentadienyl)(1-fluorenyl)]ZrCl₂,rac-[ethylenebis(1-indenyl)] ZrCl₂, (CH₃)₂Si(Cp)₂ZrCl₂, CpZrCl₃. The structure of the polymers depends on the catalyst. In fact, with CpTiCl₃, [isopropyl(cyclopentadienyl)(1-fluorenyl)]ZrCl₂ and rac-[ethylenebis-(1-indenyl)]ZrCl₂ the polymers are chemo-, regio- and stereoregular with 1,4 cis, 1,4 trans and 1,2 isotactic structure, respectively.     

Ab initio and DFT Study on 2H-Isoxazol-5-one: Consequences of Strong Intermolecular Hydrogen-Bond Formation in Supramolecular Structures

Ab initio and density-functional-theory (DFT) calculations on 2H-isoxazol-5-one (A), its linear dimer (LD), cyclic dimer (CD), and cyclic trimer (CT), have been performed with several basis sets in the gas phase, including electron correlation by second-order Møller-Plesset perturbation theory. The calculated complexation energy for the intermolecular H-bonded trimer as well as the corresponding geometric changes are in good agreement with the notion of resonance-assisted intermolecular H-bond formation. Bond distances and angles of the optimized geometry of CT are in accordance with the X-ray-diffraction data found on a trimeric supramolecular complex of parent compound 4-(2-methoxybenzyl)-3-phenyl-4H-isoxazol-5-one. Ab initio and DFT geometry optimizations are also reproducing exactly the large asymmetry in bond angles around the CO group that is systematically present in all literature available X-ray data for analogous heterocyclic penta-atomic compounds.