Time-division multiplexing of pump wavelengths to achieve ultrabroadband, flat, backward-pumped Raman gain

We describe a simple scheme, which we call the Raman smart pump, to allow for the achievement of flat gain over broad bands with backward-pumped Raman amplification. The proposed method, based on time-division multiplexing, also removes all interaction among the various pump wavelengths and allows for dynamic gain control through simple electronic means.     

Carbonates,thiocarbonates, and the corresponding monoalkyl derivatives: III. The 13C chemical shift tensors in potassium carbonate,bicarbonate and related monomethyl derivatives

The principal values of the 13C chemical shift tensors in potassium carbonate (K2CO3), trithiocarbonate (K2CS3), bicarbonate (KHCO3), methylcarbonate (KO2COCH3), S-methyl-monothiocarbonate (KO2CSCH3), O-methyl-monothiocarbonate (KOSCOCH3), S-methyl-dithiocarbonate (KOSCSCH3), and O-methyl-dithiocarbonate (KS2COCH3), were measured in solid-state nuclear magnetic resonance experiments. Chemical shift tensor calculations on the corresponding isolated anions were used to assign the chemical shift tensor orientations in the molecular frames of all anions. The correlation between experimental and calculated principal values improves significantly when the calculations are performed on isolated anions with proton-optimized X-ray geometries rather than on isolated anions with fully optimized geometries. Further considerable improvement in the correlation is achieved by utilizing the embedded ion method, which was recently developed to include electrostatic crystal potentials in chemical shift tensor calculations on ionic compounds. Similarities and differences in the chemical shift tensor orientations and principal values of the trigonal sp2 carbon atoms in the carbonate and thiocarbonate anions are compared with those known for condensed polyaromatic hydrocarbons.     

Resolution enhancement in 13C and 15N magic-angle turning experiments with TPPM decoupling

Many solid-state spectra have been shown to have problems related to the poor proton decoupling of carbon nuclei in methylene groups under conditions of slow magic-angle turning. Two-pulse phase-modulation (TPPM) decoupling during the 2D PHORMAT chemical shift separation experiment is shown to be more effective in comparison to that obtainable at much higher spin rates using conventional CW decoupling. TPPM decoupling can also alleviate similar inadequacies when observing the 15N nucleus, particularly with NH2 groups. This is demonstrated in the 15N resonances of fully labeled l-arginine hydrochloride, where a line narrowing of about a factor of two was observed at moderate rotation rates. This significant advantage was also obtained at turning frequencies as low as 500 Hz.     

Studies of Ziegler-type catalysts for the polymerization of ethylene and propylene II The polymerization of ethylene with VOCl3-Et3Al2Cl3 (chlorinated activator) catalysts

VOCl₃-Et₃Al₂C1₃(chlorinated activator) catalysts have been employed for the polymerization of ethylene at T between 15 and 85° in n-hexane. Using butylperchlorocrotonate as the activator, the following catalyst efficiencies (g polymerization, hr, atmosphere ethylene in the cap gas) were achieved: 10^6,1 MFI = 0-00; 10^5,8, e.g. MFI = 1 0 (with 9 per cent H₂ present in the cap gas) and 10^6–9 MFI = 0?4 (with 44 mmole/1 styrene in the hexane medium). Reactions between the aluminium alkyl and the activator molecules produced other chlorinated species of high average activator effectiveness. The catalyst system could be reactivated by further additions of Et₃Al₂Cl₃. The minimum value of the polymerization propagation rate constant is estimated to be 10¹²²?6x10,461 cm³/mole sec.     

The diterpenes of dacrydium colensoi—III

An oxidoditerpene, isolated from the heartwood of Dacrydium colensoi, has been shown to be 18-hydroxy-2-ketomanoyl oxide (V).     

Optically sectioned fluorescence lifetime imaging using a Nipkow disk microscope and a tunable ultrafast continuum excitation source

We demonstrate an optically sectioned fluorescence lifetime imaging microscope with a wide-field detector, using a convenient, continuously tunable (435-1150 nm) ultrafast source for fluorescence imaging applications that is derived from a visible supercontinuum generated in a microstructured fiber.