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131.
Seong Cho Dana Jones Wilburn E. Reddick Robert J. Ogg R.Grant Steen 《Magnetic resonance imaging》1997,15(10):1133-1143
The goal of this study was to determine the expected normal range of variation in spin-lattice relaxation time (T1) of brain tissue in vivo, as a function of age. A previously validated precise and accurate inversion recovery method was used to map T1 transversely, at the level of the basal ganglia, in a study population of 115 healthy subjects (ages 4 to 72; 57 male and 58 female). Least-squares regression analysis shows that T1 varied as a function of age in pulvinar nucleus (R2 = 56%), anterior thalamus (R2 = 51%), caudate (R2 = 50%), frontal white matter (R2 = 47%), optic radiation (R2 = 39%), putamen (R2 = 36%), genu (R2 = 22%), occipital white matter (R2 = 20%) (all p < 0.0001), and cortical gray matter (R2 = 53%) (p < 0.001). There were no significant differences in T1 between men and women. T1 declines throughout adolescence and early adulthood, to achieve a minimum value in the fourth to sixth decade of life, then T1 begins to increase. Quantitative magnetic resonance imaging provides evidence that brain tissue continues to change throughout the lifespan among healthy subjects with no neurologic deficits. Age-related changes follow a strikingly different schedule in different brain tissues; white matter tracts tend to reach a minimum T1 value, and to increase again, sooner than do gray matter tracts. Such normative data may prove useful for the early detection of brain pathology in patients. 相似文献
132.
Experimental studies have been conducted on a 0.9 m diameter, horizontal axis wind turbine (HAWT) placed in the open jet
of a closed return wind tunnel. The turbine was tested in a three blade and a two blade configuration. The power coefficient
of the turbine was measured and wake flow studies conducted for a range of yawed flows by tilting the rotor plane at various
angles up to 30° to the incident wind direction. The motion of the shed vorticity was followed using laser-sheet flow visualisation
with the overall wake deflection being measured. The results were compared with theoretical predictions and with studies conducted
elsewhere.
Received: 24 October 1996 / Accepted: 16 May 1997 相似文献
133.
Detection of NO in a spark-ignition research engine using degenerate four-wave mixing 总被引:2,自引:0,他引:2
We report the first application of degenerate four-wave mixing (DFWM) to combustion diagnostics in a methane-fuelled internal
combustion research engine. Combustion-generated NO in the spark-ignited engine was detected using scanning narrowband DFWM
in a modified forward folded BOXCARS geometry. The resulting spectra of the X2Π-A2Σ+(0,0) band at 226 nm display an excellent signal-to-noise ratio. Extension of the technique to different engine operating
conditions and to time-resolved multiplex DFWM is discussed.
Received: 3 May 2001 / Revised version: 1 October 2001 / Published online: 29 November 2001 相似文献
134.
T. J. Grant 《The Journal of the Operational Research Society》1986,37(1):41-57
This paper compares operational research (O.R.) with the currently fashionable topic of artificial intelligence (A.I.) at a detailed level. A.I. concepts, techniques and history are summarized, and O.R. and A.I. approaches compared. A case study-the development of a potential aid to scheduling repair jobs on RAF squadrons—is described. The paper shows where A.I. concepts and techniques were used in the prototype program, known as the Fault Identification & Expediting Repair (FIXER) system. Finally, some lessons for O.R. are drawn. 相似文献
135.
DeCoste JB Glover TG Mogilevsky G Peterson GW Wagner GW 《Langmuir : the ACS journal of surfaces and colloids》2011,27(15):9458-9464
A novel technique for determining the relative accessibility and reactivity of basic surface hydroxyl sites by reacting various zirconium(IV) hydroxide materials with 2,2,2-trifluoroethanol (TFE) and characterizing the resulting material using (19)F magic angle spinning (MAS) nuclear magnetic resonance (NMR) is presented here. Studied here are three zirconium hydroxide samples, two unperturbed commercial materials, and one commercial material that is crushed by a pellet press. Factors, such as the ratio of bridging/terminal hydroxyls, surface area, and pore size distribution, are examined and found to affect the ability of the zirconium(IV) hydroxide to react with TFE. X-ray diffraction, nitrogen isotherms, and (1)H MAS NMR were used to characterize the unperturbed materials, while thermogravitric analysis with gas chromatography and mass spectrometry along with the (19)F MAS NMR were used to characterize the materials that were reacted with TFE. Zirconium hydroxide materials with a high surface area and a low bridging/terminal hydroxyl ratio were found to react TFE in the greatest amounts. 相似文献
136.
Bates CM Strahan JR Santos LJ Mueller BK Bamgbade BO Lee JA Katzenstein JM Ellison CJ Willson CG 《Langmuir : the ACS journal of surfaces and colloids》2011,27(5):2000-2006
The orientation of cylinder-forming poly(styrene-block-methyl methacrylate) [P(S-b-MMA)] was investigated on two sets of polymeric surface treatments: 10 para-substituted polystyrene derivatives with <10 mol % poly(4-vinylbenzyl azide) and a series of poly(styrene-random-4-vinylbenzyl azide) [P(S-r-VBzAz)] copolymers with 5-100 mol % poly(4-vinylbenzyl azide). The copolymers were spin-coated to form thin films and then cross-linked by heating. The resulting films exhibited a range of surface tensions from 21 to 45 dyn/cm. Perpendicular orientation of P(S-b-MMA) cylinders was achieved with poly(p-bromostyrene) and all the [P(S-r-VBzAz)] copolymer surface treatments, most notably the homopolymer of poly(4-vinylbenzyl azide). Films made from these simple copolymers are as effective as random terpolymer alignment layers commonly made from both block monomers and a cross-linkable monomer. 相似文献
137.
A. F. Fucaloro C. Edmunds S. Grant W. Kim B. Lee J. Mao G. Pera K. Pinnock 《Journal of solution chemistry》2011,40(7):1349-1360
The partial molar volumes (V
2) and refractions (R
2) for poly[vinyl alcohol] (PVOH) in water were determined at 0.00, 5.00, 15.00, 20.00, and 25.00 °C. Each of the partial molar
quantities exhibits a small but significant dependence upon concentration which is analyzed using a previously reported model
of solvation. This study concludes that the water in the regions surrounding the solute molecules exhibits less hydrogen bonding
and as a consequence is denser than the bulk water. In addition, the study finds that the partial molar volume of PVOH at
infinite dilution is the simple sum of contributions from its monomer units (–CH2–CHOH–). 相似文献
138.
Grant Hill J Mitrushchenkov A Yousaf KE Peterson KA 《The Journal of chemical physics》2011,135(14):144309
Explicitly correlated CCSD(T)-F12b calculations have been carried out with systematic sequences of correlation consistent basis sets to determine accurate near-equilibrium potential energy surfaces for the X(2)Π and a(4)Σ(-) electronic states of the CCN radical. After including contributions due to core correlation, scalar relativity, and higher order electron correlation effects, the latter utilizing large-scale multireference configuration interaction calculations, the resulting surfaces were employed in variational calculations of the ro-vibronic spectra. These calculations also included the use of accurate spin-orbit and dipole moment matrix elements. The resulting ro-vibronic transition energies, including the Renner-Teller sub-bands involving the bending mode, agree with the available experimental data to within 3 cm(-1) in all cases. Full sets of spectroscopic constants are reported using the usual second-order perturbation theory expressions. Integrated absorption intensities are given for a number of selected vibronic band origins. A computational procedure similar to that used in the determination of the potential energy functions was also utilized to predict the formation enthalpy of CCN, ΔH(f)(0K) = 161.7 ± 0.5 kcal/mol. 相似文献
139.
The oxidative decomposition mechanism of the lithium battery electrolyte solvent propylene carbonate (PC) with and without PF(6)(-) and ClO(4)(-) anions has been investigated using the density functional theory at the B3LYP/6-311++G(d) level. Calculations were performed in the gas phase (dielectric constant ε = 1) and employing the polarized continuum model with a dielectric constant ε = 20.5 to implicitly account for solvent effects. It has been found that the presence of PF(6)(-) and ClO(4)(-) anions significantly reduces PC oxidation stability, stabilizes the PC-anion oxidation decomposition products, and changes the order of the oxidation decomposition paths. The primary oxidative decomposition products of PC-PF(6)(-) and PC-ClO(4)(-) were CO(2) and acetone radical. Formation of HF and PF(5) was observed upon the initial step of PC-PF(6)(-) oxidation while HClO(4) formed during initial oxidation of PC-ClO(4)(-). The products from the less likely reaction paths included propanal, a polymer with fluorine and fluoro-alkanols for PC-PF(6)(-) decomposition, while acetic acid, carboxylic acid anhydrides, and Cl(-) were found among the decomposition products of PC-ClO(4)(-). The decomposition pathways with the lowest barrier for the oxidized PC-PF(6)(-) and PC-ClO(4)(-) complexes did not result in the incorporation of the fluorine from PF(6)(-) or ClO(4)(-) into the most probable reaction products despite anions and HF being involved in the decomposition mechanism; however, the pathway with the second lowest barrier for the PC-PF(6)(-) oxidative ring-opening resulted in a formation of fluoro-organic compounds, suggesting that these toxic compounds could form at elevated temperatures under oxidizing conditions. 相似文献
140.
In this paper, we examine, by dissipative particle dynamics (DPD) simulation, the interactions between nanoparticles and block copolymer bilayer membranes. The bilayer has a hydrophobic core and hydrophilic head groups on both sides of the core. Nanoparticles without or with a grafted homopolymer are considered. For the conditions investigated, the single nanoparticles and small aggregates are located at the interfaces of the membrane, namely the interfaces between the hydrophilic domains of the membrane and the solvent as well as at the interface between the hydrophobic and hydrophilic domains of the membrane. The large aggregates are located in the hydrophilic domains. By increasing the length of the homopolymer grafted on the nanoparticles, the size of the aggregates in the membrane decreases. At relatively short DPD step times, the particles aggregate in the solvent. As the time increases, the single particles and aggregates penetrate into the membrane. 相似文献