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991.
R Berger J Courtieu RR Gil C Griesinger M Köck P Lesot B Luy D Merlet A Navarro-Vázquez M Reggelin UM Reinscheid CM Thiele M Zweckstetter 《Angewandte Chemie (International ed. in English)》2012,51(33):8388-8391
Insensitive towards inversion: Can residual dipolar couplings (RDCs) and other anisotropic NMR observables be used to determine absolute configuration? A critical assessment of recent approaches is provided to determine the absolute configuration from RDCs. 相似文献
992.
Katharina Graf 《Nachrichten aus der Chemie》2012,60(6):666-668
993.
T. Nebel F. D. Amaro A. Antognini F. Biraben J. M. R. Cardoso D. S. Covita A. Dax L. M. P. Fernandes A. L. Gouvea T. Graf T. W. Hänsch M. Hildebrandt P. Indelicato L. Julien K. Kirch F. Kottmann Y. -W. Liu C. M. B. Monteiro F. Nez J. M. F. dos Santos K. Schuhmann D. Taqqu J. F. C. A. Veloso A. Voss R. Pohl 《Hyperfine Interactions》2012,212(1-3):195-201
We propose to measure several transition frequencies between the 2S and the 2P states (Lamb shift) in muonic helium ions (μ 4He?+? and μ 3He?+?) by means of laser spectroscopy, in order to determine the alpha-particle and helion root-mean-square (rms) charge radius. In addition, the fine and hyperfine structure components will be revealed, and the magnetic moment distribution radius will be determined. The contribution of the finite size effect to the Lamb shift (2S???2P energy difference) in μHe?+? is as high as 20 %. Therefore a measurement of the transition frequencies with a moderate (for laser spectroscopy) precision of 50 ppm (corresponding to 1/20 of the linewidth) will lead to a determination of the nuclear rms charge radii with a relative accuracy of 3 ×10???4 (equivalent to 0.0005 fm). The limiting factor for the extraction of the radii from the Lamb shift measurements is given by the uncertainty of the nuclear polarizability contribution. Combined with an ongoing experiment at MPQ aiming to measure the 1S???2S transition frequency in the helium ion, the Lamb shift measurement in μHe?+? will lead to a sensitive test of problematic and challenging bound-state QED terms. This measurement will also help to clarify the discrepancy found in our previous μ p experiment. Additionally, a precise knowledge of the absolute nuclear radii of the He isotopes and the hyperfine splitting of μ 3He?+? provide a relevant test of few-nucleon theories. 相似文献
994.
T. Nebel A. Antognini F. D. Amaro F. Biraben J. M. R. Cardoso D. S. Covita A. Dax S. Dhawan L. M. P. Fernandes A. Giesen T. Graf T. W. Hänsch P. Indelicato L. Julien C.-Y. Kao P. Knowles F. Kottmann E. Le Bigot Y.-W. Liu J. A. M. Lopes L. Ludhova C. M. B. Monteiro F. Mulhauser F. Nez P. Rabinowitz J. M. F. dos Santos L. A. Schaller K. Schuhmann C. Schwob D. Taqqu J. F. C. A. Veloso R. Pohl 《Hyperfine Interactions》2012,212(1-3):185-194
The root-mean-square (rms) charge radius r p of the proton has so far been known only with a surprisingly low precision of about 1% from both electron scattering and precision spectroscopy of hydrogen. We have recently determined r p by means of laser spectroscopy of the Lamb shift in the exotic “muonic hydrogen” atom. Here, the muon, which is the 200 times heavier cousin of the electron, orbits the proton with a 200 times smaller Bohr radius. This enhances the sensitivity to the proton’s finite size tremendously. Our new value r p?=?0.84184 (67) fm is ten times more precise than the generally accepted CODATA-value, but it differs by 5 standard deviations from it. A lively discussion about possible solutions to the “proton size puzzle” has started. Our measurement, together with precise measurements of the 1S–2S transition in regular hydrogen and deuterium, also yields improved values of the Rydberg constant, R ?∞??=?10,973,731.568160 (16) m???1. 相似文献
995.
The first synthesis of the spiroacetal-containing anti-Helicobacter pylori agents ent-CJ-12,954 and ent-CJ-13,014 is reported based on the union of a heterocycle-activated spiroacetal-containing sulfone fragment with a phthalide-containing aldehyde fragment; comparison of the 1H and 13C NMR data, optical rotations and HPLC retention times of the synthetic compounds (3S,2"S,5"S,7"S)-(1a) and (3S,2"S,5"R,7"S)-(2a) and the (3R)-diastereomers (3R,2"S,5"S,7"S)-(1b) and (3R,2"S,5"R,7"S)- (2b) with the naturally occurring compounds established that the synthetic isomers (1a) and (2a) were in fact enantiomeric to the natural products CJ-12,954 and CJ-13,014. 相似文献
996.
The distribution of Pb, Cd, Bi, and Cu in Black Sea brine system (solution--colloidal particles--biota) produced in Burgas and Pomorie salterns is studied. The established distribution of the title elements among the brine components is as follows: Pb--25% in the salt solution, 30%--in colloidal particles, 45%--in biota (Halobacterium salinarium and microalgae Dunaliela salina); Cu--30% in the salt solution, 22%--in colloidal particles, 48%--in biota. Cd and Bi are not detected in biota. They are uniformly distributed (50%: 50%) between the salt solution and colloidal particles. Two procedures for analysis are developed. The first one is designed for determination of the total content of the studied metals in brine. It involves elimination of the biota interference by addition of ethanol, extraction and pre-concentration of the metals with NaDDC into CCl4 followed by FAAS determination. The second procedure intends determination of the elements in the separate components of the brine. It involves separation of the colloidal particles through centrifugation, separation of the studied elements from the resulting solution as dithiocarbamate complexes on a Millipore filter, dissolution of the retained metal species and subsequent FAAS analysis. 相似文献
997.
998.
We present pressure tuning hole burning experiments with the enzyme ribonuclease A using the UV-absorbing amino acid tyrosine as a probe. We show that, at 2 K, the protein is intact, and that at least four different regions which we associate with different tyrosine sites can be distinguished through their specific response to pressure. For one site we could determine the compressibility to 0.15 GPa(-1). Upon denaturing the protein with guanidine hydrochloride, one of the tyrosine sites is preserved to a large extent. Reducing the sulfur bonds has a more drastic effect: the tyrosine sites lose most of their individual features and their compressibilities come close to that of tyrosine in solution. 相似文献
999.
Tang CY Downs AJ Greene TM Kettle L Rankin DW Robertson HE Turner AR 《Dalton transactions (Cambridge, England : 2003)》2006,(9):1204-1212
Dimethylamine-gallane is relatively slow to decompose in a closed system and vaporises at low temperature primarily as Me2(H)N.GaH3 molecules which can be trapped in a solid Ar matrix and characterised by their IR spectrum. Under the conditions needed to secure a useful gas electron diffraction (GED) pattern, however, the vapour was found to consist of dimeric dimethylamidogallane molecules, [Me2NGaH2]2, formed from the secondary amine adduct by elimination of H2, and the most reliable structure for which has been determined. Salient structural parameters (r(hl) structure) were found to be: r(Ga-N) 202.6(2), r(Ga-H) 155.6(8), r(N-C) 148.0(3), r(C-H) 111.2(6) pm; Ga-N-Ga 90.7(1), C-N-C 109.3(5), N-C-H 109.9(10) and H-Ga-H 119.4(42) degrees. 相似文献
1000.
A dinuclear Ni(II) complex involving tetrathiafulvalene (TTF) radicals as ligands has been prepared and characterized, [Ni2(mu-Cl)2(L*+)2(I3)4(I2)3.(H2O)2.(C4H8O)3 (1), L = 4,5-bis(2-pyridylmethylsulfanyl)-4',5'-ethylenedithiotetrathiafulvalene. There are two types of intramolecular magnetic exchange interactions, namely one ferromagnetic Ni(II)-Ni(II) and one antiferromagnetic Ni(II)-TTF*+. This study is new in the respect of revealing a magnetic exchange interaction between a TTF*+ radical and a paramagnetic transition metal ion. This is due to the fact of a direct binding of the transition metal ion to the skeleton of the TTF*+ radical. 相似文献