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11.
L. Graf 《Zeitschrift für Physik B Condensed Matter》1978,32(1):27-36
The resonant coupling between magnons and optical phonons of symmetryB
g
was observed in the Raman spectra at different magnetic fields in the antiferro-, ferri- and ferromagnetic phases of FeCl2·2H2O at 2K. The line positions of the coupled modes were calculated taking a field dependence of the coupling strength into account. Varying this strength and the frequencies of the uncoupled modes as parameters of this calculation a fit of the experimental data was obtained also at low fields where former interpretations were not satisfying. However, the field dependence of the coupling strength disagrees with a corresponding term of an appropriate microscopic coupling mechanism in which the local spins are disturbed by a modulation of the ctystal field via spin-orbit coupling. In accordance with the former results of the far infrared absorption measurements zero field splitting of the magnonlike mode was found to exist. In the AF-phase two magnonlike modes can be observed, but the Raman scattering cross section of one of these modes tends to zero at zero field corresponding to its vanishing phonon contributions responsible for the scattering cross sections of the coupled modes. The relationship between cross sections of the coupled modes and their phonon contributions was confirmed by analysing the field dependence of the mode intensities in the Raman spectra.A project of the Sonderforschungsbereich 65 Festkörperspektroskopie Darmstadt-Frankfurt, supported by the Deutsche Forschungsgemeinschaft 相似文献
12.
Hacker CA Anderson KA Richter LJ Richter CA 《Langmuir : the ACS journal of surfaces and colloids》2005,21(3):882-889
Aliphatic alcohols and aldehydes were reacted with the Si(111)-H surface to form Si-O-C interfacial bonds from dilute solution by using ultraviolet light. The resulting monolayers were characterized by using transmission infrared spectroscopy, spectroscopic ellipsometry, and contact angle measurements. The effect of different solvents on monolayer quality is presented. The best monolayers were formed from CH(2)Cl(2). The optimized monolayers were thoroughly characterized to determine the film structure and monolayer stability. The UV-promoted, alcohol-functionalized, and aldehyde-functionalized monolayers are of comparable quality to those previously prepared by other means. Although both molecules are tethered through a Si-O-C bond, the film reactivity is distinctly different with the aldehyde films being more chemically resistant. The differences in chemical reactivity, vibrational spectra, hydrophobicity, and ellipsometric thickness between the alcohol and aldehyde monolayers are attributed to a difference in molecular coverage and monolayer formation. 相似文献
13.
Peter Graf Ekkehard Kaempf Klaus Reichlmeier Karl Bernhard 《Helvetica chimica acta》1977,60(7):2151-2154
Metabolism of Acetylenic Monocarboxylic and Dicarboxylic Acids Feeding of acetylenic monoacids with chain length of 11 to 18 C-atoms to rats led to excretion of dicarboxylic acids with retained triple bonds. 10-Octadecynoic acid led to the formation of metabolites with even and odd number of C-atoms, suggesting in addition to established ω- and β-oxidation an α-oxidative pathway. 相似文献
14.
R. Imhof Frl. E. Gssinger W. Graf W. Schnüriger H. Wehrli 《Helvetica chimica acta》1971,54(8):2775-2785
The preparation of the title compounds 11 , 37 , and 39 is described. 37 will serve as starting material for a partial synthesis of the steroidal alkaloid batrachotoxinin A ( 1 ). 相似文献
15.
The decomposition of η6-(2-lithiochlorobenzene)tricarbonylchromium(0) (I) was found to follow first order kinetics with kdec 5.1 x 10-3 min-1 at 0°C, the half life of I being 136 min at 0°C. While this dependence strongly suggests intermediacy of η6-(benzyne)tricarbonylchromium, trapping experiments were successful in only low yield. 相似文献
16.
Starting from 3-oxo-17β-hydroxy-Δ1-5α-androstene (2b) the preparation of 1-oxo-2-methoxy-4α-methyl-17β-hydroxy-Δ2-5α-androstene (9), a compound with the ring A structure of quassine (1) is described. The key problem of the reaction sequence is shown to be the monomethylation at C(4). 相似文献
17.
Background
One of the signatures of Alzheimer's disease is the accumulation of aggregated amyloid protein, Aβ, in the brain. Aβ arises from cleavage of the Amyloid Precursor protein by β and γ secretases, which present attractive candidates for therapeutic targeting. Two β-secretase candidates, ASP-1 and ASP-2, were identified as aspartic proteases, both of which cleave the amyloid precursor at the β-site. These are produced as immature transmembrane proteins containing a pro-segment.Results
ASP-2 expressed in HEK293-cells cleaved the Swedish mutant amyloid precursor at different β-sites at different pHs in vitro. Recent reports show that furin cleaves the pro-peptide of ASP-2, whereas ASP-1 undergoes auto-catalysis. We show that purified recombinant ASP-2 cleaves its own pro-peptide at ph 5 but not pH 8.5 as seen by mass spectrometry, electrophoresis and N-terminal sequencing.Conclusion
We suggest that ASP-2 processing as well as activity are influenced by pH, and hence the cellular localisation of the protein may have profound effects on the production of Aβ. These factors should be taken into consideration in the design of potential inhibitors for these enzymes. 相似文献18.
Christina Prveva Pawel Ganev Venetta Ninova und Antoanetta Delijska 《Fresenius' Journal of Analytical Chemistry》1971,255(2):113-115
Zusammenfassung Ein zweites spektrochemisches Verfahren zur Bestimmung von Silber, Blei, Zinn, Wismut, Tellur, Arsen und Antimon in Eisen und Stahl wurde entwickelt. Auch hier wird die spektrographische Analyse nach Auflösen der Probe in Salpetersäure und Eindampfen der Lösung zur Trockne durchgeführt. Die leichtflüchtigen Elemente werden ohne Puffer durch Anwendung eines inhomogenen Magnetfeldes und einer zweckmäßigen Elektrodenform störungsfrei und mit guter Reproduzierbarkeit bestimmt. Dabei sind die unteren Bestünmungsgrenzen gleich oder niedriger als die anderer spektrochemischer Methoden, die bisher beschrieben wurden. Das Verfahren zeichnet sich durch Schnelligkeit und Einfachheit aus.
Teil I: diese Z. 254, 16 (1971). 相似文献
Spectrochemical determination of trace elements in iron and steelPart II. determination of Ag, Pb, Sn, Bi, Te, As and Sb by using an inhomogeneous magnetic field
A second spectrochemical method for the determination of silver, lead, tin, bismuth, tellurium, arsenic and antimony in iron and steel has been developed. Here also the spectrographic analysis is to be carried out after dissolution of the sample in nitric acid and evaporation of the solution to dryness. Without buffer, the easily volatile elements are determined free of interferences and with good reproducibility by using an inhomogeneous magnetic field and electrodes of an appropriate form. The lower limits of determination are the same or lower than those obtained by any other spectrochemical method described. The method is characterised by rapidity and simplicity of procedure.
Teil I: diese Z. 254, 16 (1971). 相似文献
19.
20.
Acylation of diene Fe(CO)3 complexes using the Perrier complexes RCOCl/AlCl3 in methylene chloride at 0°C gives dienone complexes in high yield. Substitution occurs only at unsubstituted terminal carbons of the diene unit. Quenching the reaction mixtures in cold aqueous ammonia gives cis dienone complexes only. Trans dienone complexes are prepared by subsequent isomerization in methanolic sodium methoxide. Formylation of diene Fe(CO)3 complexes proceeds in modest yield using dichloromethylmethyleter/AlCl3 in methylene chloride to give trans-dienal complexes. Reduction of the dienone and dienal complexes as well as those of dienols and dienoic esters with 4 : 1 AlCl3/LiAlH4 results in complete removal of the oxygen function to give trans-diene complexes in good yield. 相似文献