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61.
62.
J. Döring L. Funke W. Wagner G. Winter 《Zeitschrift für Physik A Hadrons and Nuclei》1991,339(3):425-426
Excited states in the doubly-odd nucleus82Rb have been investigated via the reactions79Br(,n) and78Se(7Li,3n) using in-beam-ray spectroscopy. The level energy of the longlived 5– isomer has been determined to 68.3 keV which is below the energy of the 2– state found at 88.9 keV with a lifetime of=2.4(2) ns. A sequence of positive-parity states beginning with a 6+ level at 191.3 keV (=20(3) ns) and extending to a (10+) level has been interpreted to contain the two-particle configuration (g
9/2
9/2) and collective excitations. 相似文献
63.
The reaction of o-, m-, and p-F2CCFC6H4X with SF5Br produces an intermediate adduct, F5SCF2CFBrC6H4X, which, on treatment with AgBF4, affords the first useful, high yield preparation of o-, m-, and p-F5SCF2CF2C6H4X. 相似文献
64.
A range of new small bite-angle diphosphine complexes, [M(CO)4{X2PC(R1R2)PX2}] (M = Mo, W; X = Ph, Cy; R1 = H, Me, Et, Pr, allyl, R2 = Me, allyl), have been prepared via elaboration of the methylene backbones in [M(CO)4(X2PCH2PX2)] as a result of successive deprotonation and alkyl halide addition. When X = Ph it proved possible to replace both methylene protons but for X = Cy only one substitution proved possible. This is likely due to the electron-releasing nature of the cyclohexyl groups but may also be due to steric constraints. Attempts to prepare the bis(allyl) substituted complex [Mo(CO)4{Ph2PC(allyl)2PPh2}] were only moderately successful. The crystal structures of nine of these complexes are presented. 相似文献
65.
Small-angle static light scattering has been used to probe the evolution of aggregate size and structure in the shear-induced aggregation of latex particles. The size of aggregates obtained from the particle-sizing instrument (Coulter LS230) was compared with the size of those obtained with another approach utilizing the Guinier equation on the scattering data. Comparison of the two methods for studying the effects of mixing on the evolution of the aggregate size with time revealed similar trends. The aggregate structures were quantified in terms of their fractal dimensions on the grounds of the validity of Rayleigh-Gans-Debye scattering theory for the fractal aggregates. Analysis of the scattering patterns of aggregates verified that restructuring of the aggregates occurred as the aggregates were exposed to certain shear environments, resulting in a scale-dependent structure that could not be quantified by a fractal dimension. The effect of restructuring on aggregate size was particularly noticeable when the aggregates were exposed to average shear rates of 40 to 80 s(-1), whereas no significant restructuring occurred at lower shear rates. At 100 s(-1), the fragmentation of aggregates appeared to be more significant than aggregate compac-tion. Copyright 2001 Academic Press. 相似文献
66.
The alignment of foil-excited hydrogen was determined by measuring the polarization of Ly- radiation in the particle energy region 23E190 keV. A change of sign at 45 keV is observed. 相似文献
67.
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70.
The first diastereoselective synthesis of the 5-hydroxy-pyrrolidinone amino acid common to eight members of the microsclerodermin family is presented. Our strategy involves formal hydration of an unsaturated precursor via the use of a two-step hydroxybromination-debromination protocol; this procedure provides exclusively the requisite 4,5-cis-pyrrolidinone. Furthermore model studies are presented that indicated the potential viability of this hydration strategy in the context of a synthesis of microsclerodermin B. 相似文献