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101.
William Errington Usha Somasunderam Gerald R. Willey 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(2):190-191
The title compound, C5H16N22+·2Cl−, was isolated as a by-product from the reaction between trimethylethylenediamine and germanium tetrachloride in the presence of triethylamine. The asymmetric unit contains two cations, one in the gauche and the other in the trans conformation; these conformations are stabilized by hydrogen-bonding interactions between the N—H moieties and the chloride anions. 相似文献
102.
Bithiophene triarylborane dyad: An efficient material for the selective detection of CN− and F− ions
Sakthivel Perumal Sekar Karuppannan Sivaraman Gandhi Singaravadivel Subramanian Anbu Govindasamy Senthil Kumar Gopal 《应用有机金属化学》2020,34(1):e5257
A new fluorescent chemosensor based on bithiophene coupled dimesitylborane (BMB-1) was synthesized and characterized. BMB-1 was used for colorimetric and turn-on fluorescent sensing of cyanide (CN−) and fluoride (F−) ions, in the presence of other competitive anions in an aqueous (CH3CN–H2O) medium. BMB-1 showed a hypsochromic shift (blue shift) with addition of CN− and F− ions in absorption studies. The lower detection level of CN− and F− ions is 1.37 × 10−9 and 1.75 × 10−9 M, respectively. The BMB-1 binding mechanism is based on the nucleophilic addition of CN− and F− ions in the internal charge transfer transition of bithio moiety to the boranylmesitylene unit, and the color changes were observed under UV light. This result is further confirmed by Fourier transform infrared spectroscopy, mass spectrometry and density functional theory calculations. Also, the BMB-1 probe is found to be a good adsorbent for the removal of F− ions in real water samples using the adsorption technique. 相似文献
103.
Ruchi Badoni Deepak Kumar Semwal Prabhakar P.Badoni Sudhir Kumar Kothiyal Usha Rawat 《中国化学快报》2011,22(1):81-84
A novel bacteriohopanoid elucidated as 3β-hydroxy-35-(cyclohexyl-5’-propan-7’-one)-33-ethyl-34-methyl-bactereohopane(1) has been isolated from the bark of Celtis australis(Ulmaceae) together with three known compounds apigenin,quercetin and its glucoside.The structure of 1 was characterized by means of chemical and spectral methods including advanced 2D NMR studies. 相似文献
104.
105.
Pala Rajasekharreddy Pathipati Usha Rani Bojja Sreedhar 《Journal of nanoparticle research》2010,12(5):1711-1721
The development of rapid and ecofriendly processes for the synthesis of silver (Ag) and gold (Au) nanoparticles is of great
importance in the field of nanotechnology. In this study, the extracellular production of Ag and Au nanoparticles was carried
out from the leaves of the plants, Tridax procumbens L. (Coat buttons), Jatropa curcas L. (Barbados nut), Calotropis gigantea L. (Calotropis), Solanum melongena L. (Eggplant), Datura metel L. (Datura), Carica papaya L. (Papaya) and Citrus aurantium L. (Bitter orange) by the sunlight exposure method. Qualitative comparisons of the synthesized nanoparticles between the
plants were measured. Among these T. procumbens, J. curcas and C. gigantea plants synthesized <20 nm sized and spherical-shaped Ag particles, whereas C. papaya, D. metel and S. melongena produced <20 nm sized monodispersed Au particles. The amount of nanoparticles synthesized and its qualitative characterization
was done by UV–vis spectroscopy and transmission electron microscopy (TEM), respectively. X-ray diffraction (XRD) and X-ray
photoelectron spectroscopy (XPS) were used for structural confirmation. Further analysis carried out by fourier transform
infrared spectroscopy (FTIR), provided evidence for the presence of amino groups, which increased the stability of the synthesized
nanoparticles. 相似文献
106.
Krishna P. Bhabak Govindasamy Mugesh Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(4):1175-1185
In this paper, the effect of some commonly used antithyroid drugs and their analogues on peroxynitrite‐mediated nitration of proteins is described. The nitration of tyrosine residues in bovine serum albumin (BSA) and cytochrome c was studied by Western blot analysis. These studies reveal that the antithyroid drugs methimazole (MMI), 6‐n‐propyl‐2‐thiouracil (PTU), and 6‐methyl‐2‐thiouracil (MTU), which contain thione moieties, significantly reduce the tyrosine nitration of both BSA and cytochrome c. While MMI exhibits good peroxynitrite (PN) scavenging activity, the thiouracil compounds PTU and MTU are slightly less effective than MMI. The S‐ and Se‐ methylated compounds show a weak inhibitory effect in the nitration of tyrosine, indicating that the presence of a thione or selone moiety is important for an efficient inhibition. Similarly, the replacement of N? H moiety in MMI by N‐methyl or N‐m‐methoxybenzyl substituents dramatically reduces the antioxidant activity of the parent compound. Theoretical studies indicate that the substitution of N? H moiety by N? Me significantly increases the energy required for the oxidation of sulfur center by PN. However, such substitution in the selenium analogue of MMI increases the activity of parent compound. This is due to the facile oxidation of the selone moiety to the corresponding selenenic and seleninic acids. Unlike N,N′‐disubstituted thiones, the corresponding selones efficiently scavenge PN, as they predominantly exist in their zwitterionic forms in which the selenium atom carries a large negative charge. 相似文献
107.
108.
A new chromogenic calixarene with hydroxamic acid as chelating agent was synthesized by partial reduction of nitrocalixarene
which was subsequently coupled with coumarin chloride. The reagent showed selective and quantitative extraction of Ti(IV)
into chloroform at 6 M HCl and that of Zr(IV) at 0.5 M HCl. A facile liquid-liquid extraction method for the separation and
spectrophotometric determination of Ti(IV) and Zr(IV) has been proposed. The validity of the method was checked by separating
several synthetic mixtures. The method was successfully applied to the analysis of piezoelectric lead-zirconium-titanate (PZT) samples. The method shows remarkable simplicity and selectivity. The method can also be used for the determination of Ti(IV)
and Zr(IV) in various environmental samples.
The article is published in the original. 相似文献
109.
The effect of different donor nitrogen atoms on the strength and nature of intramolecular Se ??? N interactions is evaluated for organoselenium compounds having N,N‐dimethylaminomethyl (dime), oxazoline (oxa) and pyridyl (py) substituents. Quantum chemical calculations on three series of compounds [2‐(dime)C6H4SeX ( 1 a – g ), 2‐(oxa)C6H4SeX ( 2 a – g ), 2‐(py)C6H4SeX ( 3 a – g ); X=Cl, Br, OH, CN, SPh, SePh, CH3] at the B3LYP/6‐31G(d) level show that the stability of different conformers depends on the strength of intramolecular nonbonded Se ??? N interactions. Natural bond orbital (NBO), NBO deletion and atoms in molecules (AIM) analyses suggest that the nature of the Se ??? N interaction is predominantly covalent and involves nN→σ*Se? X orbital interaction. In the three series of compounds, the strength of the Se ??? N interaction decreases in the order 3 > 2 > 1 for a particular X, and it decreases in the order Cl>Br>OH>SPh≈CN≈SePh>CH3 for all the three series 1 – 3 . However, further analyses suggest that the differences in strength of Se ??? N interaction in 1 – 3 is predominantly determined by the distance between the Se and N atoms, which in turn is an outcome of specific structures of 1 , 2 and 3 , and the nature of the donor nitrogen atoms involved has very little effect on the strength of Se ??? N interaction. It is also observed that Se ??? N interaction becomes stronger in polar solvents such as CHCl3, as indicated by the shorter rSe ??? N and higher ESe ??? N values in CHCl3 compared to those observed in the gas phase. 相似文献
110.
Structural influence of mono and polyhydric alcohols on the stabilization of collagen 总被引:1,自引:0,他引:1
Usha R Maheshwari R Dhathathreyan A Ramasami T 《Colloids and surfaces. B, Biointerfaces》2006,48(2):101-105
In the present study, solvents effects on the structure of collagen have been examined by circular dichroism and their interfacial tension at glass/liquid and Teflon/liquid. Changes in the conformations of the protein have been analyzed after equilibration with aqueous solutions of monohydric and polyhydric alcohols like methanol, ethanol, n-propanol, propane-2-diol and glycerol. The results from viscosity and Circular dichroism (CD) spectra suggest a clear distinction in the structural changes for collagen with monohydric alcohols as against polyhydric ones. The surface tension and interfacial tension at glass (high surface energy, HFSE) and Teflon (Low surface energy, LSFE) reflect similar differences between the monohydric and polyhydric alcohols. Studies on the interfacial energy of the adsorbed protein at glass/solution interface compared to that of Teflon/solution interface show that the water structure near glass gets perturbed leading to an increase in the average free energy of the bulk water phase and a reduction in hydrophobic effect near the glass. The results suggest that the different solvents alter the hydrophobic effect on the hydrated protein to different extent and thus influence folding equilibrium of the protein without directly interacting with it. Polyhydric alcohols seem to favor the native collagen structure while monohydric alcohols enhance it. 相似文献