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81.
Plastic Antibodies for Cosmetics: Molecularly Imprinted Polymers Scavenge Precursors of Malodors 下载免费PDF全文
Sofia Nestora Franck Merlier Dr. Selim Beyazit Elise Prost Dr. Luminita Duma Bérangère Baril Dr. Andrew Greaves Prof. Karsten Haupt Dr. Bernadette Tse Sum Bui 《Angewandte Chemie (International ed. in English)》2016,55(21):6252-6256
Molecularly imprinted polymers (MIPs) are synthetic antibody mimics capable of specific molecular recognition. Advantageously, they are more stable, easy to tailor for a given application and less expensive than antibodies. These plastic antibodies are raising increasing interest and one relatively unexplored domain in which they could outplay these advantages particularly well is cosmetics. Here, we present the use of a MIP as an active ingredient of a cosmetic product, for suppressing body odors. In a dermo‐cosmetic formulation, the MIP captures selectively the precursors of malodorous compounds, amidst a multitude of other molecules present in human sweat. These results pave the way to the fabrication of a novel generation of MIPs with improved selectivities in highly complex aqueous environments, and should be applicable to biotechnological and biomedical areas as well. 相似文献
82.
Robson Matos Mohamed F. Meidine John F. Nixon Bernadette F. Trigo Passos Edgar Niecke Detlef Barion 《Journal of organometallic chemistry》1990,390(3)
Different types of ligating behaviour of the R
R′ ring system are reported; the sp2 hybridised phosphorus is the donor atom in Pt(0), W(0) and Rh(I) complexes, whereas ligation of the sp3 hybridised phosphorus atom is preferred by Pd(II), and both phosphorus atoms are ligated in dinuclear Pt(II) systems. 相似文献
83.
84.
Raphaël Frdrick Bernadette Norberg Franois Durant Frederic Ooms Johan Wouters 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(9):o623-o626
The structures of three compounds, namely 7‐methoxy‐2‐[3‐(trifluoromethyl)phenyl]‐9H‐indeno[1,2‐c]pyridazin‐9‐one, C19H11F3N2O2, (Id), 6‐methoxy‐2‐[3‐(trifluoromethyl)phenyl]‐9H‐indeno[1,2‐c]pyridazin‐9‐one, C19H11F3N2O2, (IId), and 2‐methyl‐6‐(4,4,4‐trifluorobutoxy)‐9H‐indeno[1,2‐c]pyridazin‐9‐one, C16H13F3N2O2, (IIf), which are potent reversible type‐B monoamine oxidase (MAO‐B) inhibitors, are presented and discussed. Compounds (Id) and (IId) crystallize in a nearly planar conformation. The crystal structures are stabilized by weak C—H⋯O hydrogen bonds. The packing is dominated by π–π stacking interactions between the heterocyclic central moieties of centrosymmetrically related molecules. In compound (IIf), the trifluoroethyl termination is almost perpendicular to the plane of the ring. 相似文献
85.
The paper provides full algorithmic details on switching to the continuation of all possible codim 1 cycle bifurcations from generic codim 2 equilibrium bifurcation points in n-dimensional ODEs. We discuss the implementation and the performance of the algorithm in several examples, including an extended Lorenz-84 model and a laser system. 相似文献
86.
One-pot synthesis of pentacyclic diamines from quinolines by a new Zn/AcOH-promoted cascade reaction
Gauffre JC Grignon-Dubois M Rezzonico B Léger JM 《The Journal of organic chemistry》2002,67(14):4696-4701
A simple and efficient method for the one-pot synthesis of pentacyclic diamines from quinolines is described. It involves a new Zn/AcOH-promoted cascade reaction, in which two C[bond]C bonds and four to five stereogenic centers are established under mild conditions. The regiochemistry of the dimerization and cyclization step is governed by substituent effects, allowing access to a head-to-head (2, 3) or head-to-tail skeleton (4, 5). 相似文献
87.
Chae PS Gotfryd K Pacyna J Miercke LJ Rasmussen SG Robbins RA Rana RR Loland CJ Kobilka B Stroud R Byrne B Gether U Gellman SH 《Journal of the American Chemical Society》2010,132(47):16750-16752
We describe a new type of synthetic amphiphile that is intended to support biochemical characterization of intrinsic membrane proteins. Members of this new family displayed favorable behavior with four of five membrane proteins tested, and these amphiphiles formed relatively small micelles. 相似文献
88.
89.
We give a variational formula for the solution of a Mixed Boundary Value Problem when the geometrical domain is perturbed (Hadamard's Variational Formula) ; we show that this formula contains singularities ; the result is used to construct a new approach to the optimal control problem for a problem related to a Signorini-like Elliptic Variational Inequality. 相似文献
90.
Maria Bernadette Donato Monica Milasi Antonio Villanacci 《Journal of Mathematical Analysis and Applications》2018,457(2):1353-1369
We deal with the analysis of the general equilibrium model with incomplete financial markets and nominal assets. We assume that there are 2 periods of time, say today and tomorrow. We define a consumption, portfolio holding, commodity and asset price vector as an equilibrium vector associated with a given economy if at those prices and economies households maximize utility under a budget constraints and markets clear. While the path breaking proofs of existence by Cass [6] and Werner [25] use a fixed point argument, we provide an independent existence proof in terms of variational inequalities (about the variational approach for the analysis of general equilibrium models see for example [9] and [10]). The analysis presented in this paper indicates that the variational inequality approach promises to be applicable in many specifications of the incomplete market model. 相似文献