Efficient cleavage of terminal acetonide group: Chirospecific synthesis of 2,5-dideoxy-2,5-imino-D-mannitol

Dowex 50W-X8 was efficient catalyst for selective cleavage of terminal actonide including acid-sensitive multifunctional groups. A facile and economically synthesis of DMDP (2,5-dideoxy-2,5-imino-D-mannitol) is described via selective hydrolysis and intramolecular nucleophilic amination.     

Fuzzy flows on networks

We present a theory of fuzzy flows on networks generalizing [2] and find closed formulas giving necessary and sufficient conditions for admissible flows to exist and for the maximal admissible flow.     

Synthesis of metallic ReO3 nanowires

We present the synthesis of highly crystalline metallic rhenium trioxide (ReO₃) nanowires via a simple physical vapor transport at 300 °C for the first time. Based on HRTEM, the ReO₃ nanowires exhibit a core of perfect cubic perovskite‐type single crystal structure with a shell of thin amorphous and disordered structures of less than 2 nm in the near surface layers. Possibly this is due to proton intercalation induced by the surface reaction of single crystal ReO₃ with water.

     

Broadband GHz frequency characterizations of Permalloy nanorods’ array

The radio frequency characteristics of Permalloy nanorods’ array have been examined by coplanar waveguide (CPW) cell. The Permalloy nanorods’ array was grown in anodic aluminum oxide porous templates with a diameter of 20 nm. As the Permalloy nanorods’ array was placed on CPW, the characteristic impedances of the CPW were changed from 50 to at 1 GHz. The magnitude of inductance was decreased from 3 GHz and the capacitance was increased up to twice in comparison with that of CPW. The signal attenuations were abruptly increased over 1 GHz. The propagation wavelengths due to the insertion of Permalloy nanorods’ array were decreased about 30% at 1 GHz in comparison with that of CPW without magnetic materials.     

In vivo high‐resolution synchrotron radiation imaging of collagen‐induced arthritis in a rodent model

In vivo microstructures of the affected feet of collagen‐induced arthritic (CIA) mice were examined using a high‐resolution synchrotron radiation (SR) X‐ray refraction technique with a polychromatic beam issued from a bending magnet. The CIA models were obtained from six‐week‐old DBA/1J mice that were immunized with bovine type II collagen and grouped as grades 0–3 according to a clinical scoring for the severity of arthritis. An X‐ray shadow of a specimen was converted into a visual image on the surface of a CdWO₄ scintillator that was magnified using a microscopic objective lens before being captured with a digital charge‐coupled‐device camera. Various changes in the joint microstructure, including cartilage destruction, periosteal born formation, articular bone thinning and erosion, marrow invasion by pannus progression, and widening joint space, were clearly identified at each level of arthritis severity with an equivalent pixel size of 2.7 µm. These high‐resolution features of destruction in the CIA models have not previously been available from any other conventional imaging modalities except histological light microscopy. However, thickening of the synovial membrane was not resolved in composite images by the SR refraction imaging method. In conclusion, in vivo SR X‐ray microscopic imaging may have potential as a diagnostic tool in small animals that does not require a histochemical preparation stage in examining microstructural changes in joints affected with arthritis. The findings from the SR images are comparable with standard histopathology findings.     

First measurement of inclusive B→Xsη decays

We report a first measurement of inclusive B→Xsη decays, where Xs is a charmless state with unit strangeness. The measurement is based on a pseudoinclusive reconstruction technique and uses a sample of 657×10(6)BB pairs accumulated with the Belle detector at the KEKB e+e- collider. For MXs < 2.6 GeV/c2, we measure a branching fraction of [26.1±3.0(stat)-2.1+1.9(syst)-7.1+4.0(model)]×10(-5) and a direct CP asymmetry of ACP=-0.13±0.04-0.03+0.02. Over half of the signal occurs in the range MXs > 1.8 GeV/c2.     

Comments on conjectures of trace inequalities on a generalized Wigner-Yanase skew information

Furuichi, Yanagi and Kuriyama gave three conjectures of trace inequalities on the Wigner-Yanase-Dyson skew information and a generalized Wigner-Yanase skew information (Furuichi et al. (2009) [1]) and Yanagi found a counterexample showing that two of the three conjectures don't hold (Yanagi (2010) [6]). In this note, we show that the last conjecture does not hold in general. In addition, we show that in the case of 2×2 matrices the conjecture is true.     

Photoluminescence properties of a perfluorinated supramolecular columnar liquid crystal with a pyrene core: effects of the ordering and orientation of the columns

We investigated the effects of the alignment and ordering of pi-conjugated perfluorinated dendrimers containing pyrene moieties in their cores on their photoluminescence (PL) properties. The pyrene molecules are stacked in columns surrounded by aromatic and semifluorinated tails, which can be conjugated and act as chromophores. Polarized light microscopy (PLM), cross-sectional scanning electron microscopy (SEM), and atomic force microscopy (AFM) results show that variation of the cooling rate of the dendrimers produces variation in their orientation and ordering: Slow cooling (approximately <0.5 degrees C/min) of the isotropic melt in a sandwich glass cell results in a high degree of ordering and the vertical alignment of the columns on the substrate, in which the stacked pyrene molecules are oriented parallel to the surface over large areas. In contrast, rapid cooling (approximately >10 degrees C/min) leads to the planar alignment of the columns with significant disorder on the same substrate. UV-vis, PL, SEM, and AFM results show that the quenched columns with a planar orientation produce a broad emission band and a second weak shoulder, which indicates the presence of isolated molecules. However, the high degree of ordering of the columns with a vertical alignment produces a red-shift in the PL spectrum, with very few isolated molecules. By comparing two films with different alignments but similar ordering, we show that the ordering of this material has a greater influence on the PL spectrum than the alignment. This effect of the ordering of the columns was further verified by comparing the optical properties of the isolated dendrimers with those of small pi-conjugated molecules in solution and solid films.     

Fuzzy delayed output feedback synchronization for time-delayed chaotic systems

In this paper, we propose a new fuzzy delayed output feedback synchronization (FDOFS) method for time-delayed chaotic systems. Based on Lyapunov–Krasovskii theory, T–S fuzzy model, and delayed feedback control scheme, the FDOFS controller is designed and an analytic expression of the controller is shown. The proposed controller can guarantee asymptotical synchronization of both drive and response systems. The FDOFS controller can be obtained by solving the linear matrix inequality (LMI) problem. A numerical example for time-delayed Lorenz system is presented to demonstrate the validity of the proposed FDOFS method.