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11.
A linear projection R on a Jordan*-triple A is said to be structuralprovided that, for all elements a, b and c in A, the equality{Rab Rc} = R{a Rbc} holds. A subtriple B of A is said to becomplemented if A = B + Ker(B), where Ker(B) = {aA: {B a B}= 0}. It is shown that a subtriple of a JBW*-triple is complementedif and only if it is the range of a structural projection. A weak* closed subspace B of the dual E* of a Banach space Eis said to be an N*-ideal if every weak* continuous linear functionalon B has a norm preserving extension to a weak* continuous linearfunctional on E* and the set of elements in E which attain theirnorm on the unit ball in B is a subspace of E. It is shown thata subtriple of a JBW*-triple A is complemented if and only ifit is an N*-ideal, from which it follows that complemented subtriplesof A are weak* closed, and structural projections on A are weak*continuous and norm non-increasing. It is also shown that everyN*-ideal in A possesses a triple product with respect to whichit is a JBW*-triple which is isomorphic to a complemented subtripleof A. 相似文献
12.
The “Thermo-Stat” — a new device for the determination of catalyticaily active substancesA device for the determination of catalytically active substances, called a “ThermoStat”, is described. An additional heater is used to keep constant an arbitrarily preset temperature gradient between the reaction mixture and a cooling coil. Any heat produced by the catalysed reaction induces a deviation from the preset parameter and thus cuts out the additional heater. These breaks are plotted versus time by an integrating recorder. The slope of the reaction curve obtained is a measure of the concentration of the catalyst. As examples, determinations of copper in the range 0.1–2.0μg and molybdenum in the range 5–50 μg are discussed. 相似文献
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14.
Gottfried Lichti Brian S. Hawkett Robert G. Gilbert Donald H. Napper David F. Sangster 《Journal of polymer science. Part A, Polymer chemistry》1981,19(4):925-938
Data are presented on the time evolution of particle-size distributions (PSDs) in seeded and ab initio styrene emulsion polymerization systems. Initiation was by chemical reagent (potassium persulfate) or γ-radiation. The unswollen PSDs at various times during interval II of the polymerization were obtained by direct measurement of calibrated electron micrographs. Experimental results were fitted with the equations that describe the time evolution of an initial PSD. Analytic solutions to these equations that allow for entry, exit, and propagation of free radicals were obtained. The values of the rate coefficients for these processes used to fit the experimental data were in excellent agreement with those obtained from dilatometric kinetics experiments. 相似文献
15.
Gottfried Kempe 《Fresenius' Journal of Analytical Chemistry》1961,180(1):9-14
Zusammenfassung Vom Rf-Wert der Amidosulfonsäure ausgehend ist es möglich, die Rf-Werte aller anderen kettenförmig kondensierten Ammoniakderivate der Schwefelsäure zu berechnen. Im Falle des Diimidodisulfamids konnte eine Identifizierung der Substanz mit Hilfe des berechneten Rf-Wertes mit großer Wahrscheinlichkeit erfolgen, bei längeren Ketten wird dieses Verfahren jedoch infolge der starken Anhäufung von Verbindungen im unteren Teil des Chromatogramms nahezu unmöglich gemacht. 相似文献
16.
Paramagnetic metal ions bound to proteins generate a dipolar field that can be accurately probed by pseudocontact shifts (PCS) displayed by the protein's nuclear spins. PCS are highly useful for determining the coordinates of individual spins in the molecule and for rapid structure determinations of entire protein-protein and protein-ligand complexes. However, PCS measurements require reliable resonance assignments for the molecule in its paramagnetic state and in a diamagnetic reference state. This article discusses different approaches for pairwise resonance assignments, with emphasis on a strategy which exploits chemical exchange between the two states. 相似文献
17.
Wolf-Dieter Fessner Gottfried Sedelmeier Lothar Knothe Horst Prinzbach Grety Rihs Zhong-Zhi Yang Branka Kova
Edgar Heilbronner 《Helvetica chimica acta》1987,70(7):1816-1842
‘Face-to-Face’ Benzo-anellated Homologous Hypostrophenes. Syntheses, X-Ray-Structure Analyses and PE Spectra ‘Face-to-face’ Benzo-anellated homologous hypostrophenes (series M ), of interest as substrates for [6 + 6]-photocycloaddition reactions, have been synthesized. From X-ray structural analyses of 13b and 13c shortest C? C distances of 2.80(2.76)/2.71 Å and interorbital angles (ω) of 129° (128°)/130° between the benzene rings have been determined. The PE spectra are discussed in the context of transannular π,π interactions. 相似文献
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19.
Individual hydration water molecules in aqueous protein solutions have been observed using experimental schemes for homonuclear two-dimensional and heteronuclear three-dimensional NMR experiments in H2O solution, which do not require suppression of the solvent line by presaturation. In these experiments, the location of the hydration waters is determined from their nuclear Overhauser effects (NOE s) with individual hydrogen atoms of distinct amino acid residues. In the basic pancreatic trypsin inhibitor (BPTI ), four internal water molecules that had been reported in three different crystal forms were also found to be in the same locations in the solution structure, with lifetimes with respect to exchange of the water protons in excess of 0.3 ns. Additional NOE s with polypeptide protons located on the protein surface may involve either hydration water molecules or hydroxyl protons of amino acid side chains. Their total number is small compared to the number of NOE s expected from the hydration water molecules identified in the crystal structures of BPTI . 相似文献
20.
Vinzenz Bachler Gottfried Olbrich Oskar E. Polansky Yuh-Kang Pan 《Theoretical chemistry accounts》1979,50(4):327-342
A CNDO/2 SCF perturbation theory is presented for interpreting the form of CNDO/2 potential energy surfaces of unimolecular reactions. The analysis is performed by calculating the energy change E arising from a distortion of the molecular geometry along the reaction coordinate. E is decomposed into different perturbational contributions which are appropriate for an interpretation of the perturbation energy E. Moreover, E is resolved into energy parts arising from a single occupied orbital and contributions due to pairwise orbital interactions. In this way one evaluates numerically how the form of the occupied and unoccupied orbitals determines the magnitude of E. If the distortion occurs along a definite symmetry coordinate, group-theoretical arguments can be applied to discuss the magnitude of characteristic components of the perturbation energy. The SCF perturbation theory is used to analyze the isomerization of ethylene, cis-2-butene and cis-2-butenenitrile.This work was partially supported by Nato-Grant No. 1072 相似文献