Mechanisms for thermal conduction in hydrogen hydrate

Extensive equilibrium molecular dynamics simulations have been performed to investigate thermal conduction mechanisms via the Green-Kubo approach for (type II) hydrogen hydrate, at 0.05 kbar and between 30 and 250 K, for both lightly filled H(2) hydrates (1s4l) and for more densely filled H(2) systems (2s4l), in which four H(2) molecules are present in the large cavities, with respective single- and double-occupation of the small cages. The TIP4P water model was used in conjunction with a fully atomistic hydrogen potential along with long-range Ewald electrostatics. It was found that substantially less damping in guest-host energy transfer is present in hydrogen hydrate as is observed in common type I clathrates (e.g., methane hydrate), but more akin in to previous results for type II and H methane hydrate polymorphs. This gives rise to larger thermal conductivities relative to common type I hydrates, and also larger than type II and H methane hydrate polymorphs, and a more crystal-like temperature dependence of the thermal conductivity.     

Tris(2,2'-bipyridyl)ruthenium(II) chemiluminescence

This paper critically reviews analytical applications of the chemiluminescence from tris(2,2'-bipyridyl)ruthenium(II) and related compounds published in the open literature between mid-1998 and October 2005. Following the introduction, which summarises the reaction chemistry and reagent generation, the review divides into three major sections that focus on: (i) the techniques that utilise this type of detection chemistry, (ii) the range of analytes that can be determined, and (iii) analogues and derivatives of tris(2,2'-bipyridyl)ruthenium(II).     

Polarographische Analyse

Ohne Zusammenfassung     

On caustics associated with the linearized vorticity equation

The linearized vorticity equation serves to model a number of wave phenomena in geophysical fluid dynamics. One technique that has been applied to this equation is the geometrical optics, or multi-dimensional WKB technique. Near caustics, this technique does not apply. A related technique that does apply near caustics is the Lagrange Manifold Formalism. Here we apply the Lagrange Manifold Formalism to determine an asymptotic solution of the linearized vorticity equation and to study associated wave phenomena on the caustic curve.     

Magnetoconductivity tensor analysis of anomalous transport effects in neutron irradiated HgCdTe epilayers

Hg_1−xCd_xTe(x0.22) samples grown by LPE on CdZnTe(111B)-oriented substrates were exposed to various doses of thermal neutrons (1.0×10¹⁶−1.7×10¹⁶ n/cm²) and subsequently annealed for 24 h in Hg overpressure to remove damage and reduce the presence of Hg vacancies. Extensive magnetotransport measurements were performed on these samples as part of an investigation into the use of elemental transmutation for efficient p-type doping of this material. The data were analyzed using a multi-carrier approach which incorporates various scattering mechanisms and the presence of two conduction channels of differing alloy content to describe the changes in the transport properties due to neutron irradiation.     

Fluidized and vibrofluidized shallow beds of fresh leaves

The fluid dynamics behavior of shallow fluidized and vibrofluidized beds operating with fresh leaves was investigated with the aim of exploring drying applications in a modified conveyor belt (MCB) system,which may be operated in a fixedor fluidized-bed mode.Leaves of the specimens Duranta repens,Schinus molle,Coleus barbatus,Buxus sempervirens,and Bougainvillea spectabilis were tested with a range of sphericities from 0.063 to 0.213,bulk densities from 0.038 to 0.251 g/cm 3,apparent densities from 0.52 to ...     

Standing up versus looping over: controlling the geometry of self-assembled monolayers of α,ω-diynes on gold

It is shown that self-assembled monolayers (SAMs) composed of α,ω-diynes on gold have different structures depending on the concentration of molecules used to make the SAM. Evidence for both hairpinned and standing-up molecules is provided. This behavior is in contrast to SAMs of α,ω-dithiols on gold, which generally form SAMs with only the straight conformation. The looped SAMs composed of α,ω-diynes offer a less densely packed and thus somewhat accessible surface that may be useful when the underlying surface is used as an electrode. Furthermore, biasing the structure of the molecules in the SAM between looped and standing-up may be useful in the design of dynamic surfaces.     

Ein neuer Abbau des Indolalkaloids Kopsin; chemische Korrelierung der Alkaloide vom Kopsin- und Pleiocarpin-Typ mit Minovincin

A new chemical degradation of (–)-kopsine is described which completely confirms the structure of this alkaloid. Correlation of (–)-aspidofractinine, (–)-pleiocarpine and (–)-kopsine with (–)-minovincine establishes the absolute stereochemistry of these bases. It appears that, in contrast to the aspidospermine group, all alkaloids containing the aspidofractinine skeleton possess the same absolute stereochemistry.     

An exact analytical approach to the free vibration analysis of rectangular plates with mixed boundary conditions

A comprehensive analytical technique is developed for the free vibration analysis of rectangular plates with discontinuities along the boundaries. For illustrative purposes a solution is obtained for plates with edges partially clamped and partially simply supported and plates with edges partially and partially simply supported. A vast array of first mode eigenvalues is provided for these families of plates. Solutions to the equations are obtained by exploiting a mathematical technique described by the author during an earlier publication. It is shown that eigenvalue matrices are easily generated for a wide range of plates with discontinuities in boundary conditions.