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11.
Using an iterative solution in Laplace-Fourier space, we supply a rigorous mathematical proof for the long-time asymptotics of reversible binding in one dimension. The asymptotic power law and its concentration dependent prefactor result from diffusional and many-body effects which, unlike for the corresponding irreversible reaction and in classical chemical kinetics, play a dominant role in shaping the approach to equilibrium. 相似文献
12.
13.
We prove that when q is any odd prime power, the distance-2 graph on the set of vertices at maximal distance D from any fixed vertex of the Hemmeter graph HemD(q) is isomorphic to the graph QuadD-1(q) of quadratic forms on . 相似文献
14.
Reversible Modulation of Surface Plasmons in Gold Nanoparticles Enabled by Surface Redox Chemistry
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Dr. Zheng Li Dr. Jonathan J. Foley IV Dr. Sheng Peng Dr. Cheng‐Jun Sun Dr. Yang Ren Dr. Gary P. Wiederrecht Dr. Stephen K. Gray Dr. Yugang Sun 《Angewandte Chemie (International ed. in English)》2015,54(31):8948-8951
Switchable surface redox chemistry is demonstrated in gold@iron/iron oxide core–shell nanoparticles with ambient oxidation and plasmon‐mediated reduction to modulate the oxidation state of shell layers. The iron shell can be oxidized to iron oxide through ambient oxidation, leading to an enhancement and red‐shift of the gold surface plasmon resonance (SPR). This enhanced gold SPR can drive reduction of the iron oxide shell under broadband illumination to reversibly blue‐shift and significantly dampen gold SPR absorption. The observed phenomena provide a unique mechanism for controlling the plasmonic properties and surface chemistry of small metal nanoparticles. 相似文献
15.
Catarina IV Ramos Flávio Figueira Marcelo D Polêto Francisco ML Amado Hugo Verli João PC Tomé M Graça PMS Neves 《Journal of mass spectrometry : JMS》2016,51(5):342-349
Electrospray mass spectrometry/mass spectrometry was used to investigate the gas‐phase properties of protonated expanded porphyrins, in order to correlate those with their structure and conformation. We have selected five expanded meso‐pentafluorophenyl porphyrins, respectively, a pair of oxidized/reduced fused pentaphyrins (22 and 24 π electrons), a pair of oxidized/reduced regular hexaphyrins (26 and 28 π electrons) and a regular doubly N‐fused hexaphyrin (28 π electrons). The gas‐phase behavior of the protonated species of oxidized and reduced expanded porphyrins is different. The oxidized species (aromatic Hückel systems) fragment more extensively, mainly by the loss of two HF molecules. The reduced species (Möbius aromatic or Möbius‐like aromatic systems) fragment less than their oxidized counterparts because of their increased flexibility. The protonated regular doubly fused hexaphyrin (non‐aromatic Hückel system) shows the least fragmentation even at higher collision energies. In general, cyclization through losses of HF molecules decreases from the aromatic Hückel systems to Möbius aromatic or Möbius‐like aromatic systems to non‐aromatic Hückel systems and is related to an increase in conformational distortion. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
16.
Baldwin Rusty O. Davis IV Nathaniel J. Kobza John E. Midkiff Scott F. 《Queueing Systems》2000,35(1-4):1-21
Real-time scheduling, or scheduling with respect to a deadline, is critical in many application areas such as telecommunications,
control systems, and manufacturing. This paper presents a novel approach to real-time scheduling based on a queueing theory
model. Using real-time queueing theory (RTQT), one can analytically determine the distribution of the lead-time profile (i.e.,
the time until the deadline is reached) of customers waiting for service. Emphasis is placed on the development of the equations
used to determine the lead-time profile distribution. The development of the GI/G/1 case is presented and confirmed using
simulation. Simulation results confirm prior research for the M/M/1 and GI/M/1 case. As a practical application, RTQT is used
to implement a packet admission control algorithm for a telecommunications network. Using this algorithm, packet lateness
was reduced by up to 31%.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
17.
Synthetically Tuning the 2‐Position of Halogenated Quinolines: Optimizing Antibacterial and Biofilm Eradication Activities via Alkylation and Reductive Amination Pathways
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Akash Basak Yasmeen Abouelhassan Verrill M. Norwood IV Dr. Fang Bai Minh Thu Nguyen Prof. Shouguang Jin Prof. Robert W. Huigens III 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(27):9181-9189
Agents capable of eradicating bacterial biofilms are of great importance to human health as biofilm‐associated infections are tolerant to our current antibiotic therapies. We have recently discovered that halogenated quinoline (HQ) small molecules are: 1) capable of eradicating methicillin‐resistant Staphylococcus aureus (MRSA), methicillin‐resistant Staphylococcus epidermidis (MRSE) and vancomycin‐resistant Enterococcus faecium (VRE) biofilms, and 2) synthetic tuning of the 2‐position of the HQ scaffold has a significant impact on antibacterial and antibiofilm activities. Here, we report the chemical synthesis and biological evaluation of 39 HQ analogues that have a high degree of structural diversity at the 2‐position. We identified diverse analogues that are alkylated and aminated at the 2‐position of the HQ scaffold and demonstrate potent antibacterial (MIC≤0.39 μm ) and biofilm eradication (MBEC 1.0–93.8 μm ) activities against drug‐resistant Staphylococcus aureus, Staphylococcus epidermidis and Enterococcus faecium strains while demonstrating <5 % haemolysis activity against human red blood cells (RBCs) at 200 μm . In addition, these HQs demonstrated low cytotoxicity against HeLa cells. Halogenated quinolines are a promising class of antibiofilm agents against Gram‐positive pathogens that could lead to useful treatments against persistent bacterial infections. 相似文献
18.
John S. Caughman IV 《Journal of Algebraic Combinatorics》2002,15(3):223-229
Let denote a bipartite distance-regular graph with diameter D 3 and valency k 3. Suppose 0, 1, ...,
D
is a Q-polynomial ordering of the eigenvalues of . This sequence is known to satisfy the recurrence
i – 1 –
i
+
i + 1 = 0 (0 > i > D), for some real scalar . Let q denote a complex scalar such that q + q
–1 = . Bannai and Ito have conjectured that q is real if the diameter D is sufficiently large.We settle this conjecture in the bipartite case by showing that q is real if the diameter D 4. Moreover, if D = 3, then q is not real if and only if 1 is the second largest eigenvalue and the pair (, k) is one of the following: (1, 3), (1, 4), (1, 5), (1, 6), (2, 4), or (2, 5). We observe that each of these pairs has a unique realization by a known bipartite distance-regular graph of diameter 3. 相似文献
19.
William F. Doran IV 《Journal of Algebraic Combinatorics》1998,8(3):253-272
This paper gives a new formula for the plethysm of power-sum symmetric functions and Schur symmetric functions with one part. The form of the main result is that for b,
where the sum is over semistandard tableaux T of weight a
b
,
is a root of unity, and maj(T) is a major index like statistic on semistandard tableaux.An Sb-representation, denoted S,b, is defined. In the special case when b, S,b is the Specht module corresponding to . It is shown that the character of S,b on elements of cycle type is
where the sum is over semistandard tableaux T of shape and weight ab. Moreover, the eigenvalues of the action of an element of cycle type acting on S,b are {
}. This generalizes J. Stembridge's result [11] on the eigenvalues of elements of the symmetric group acting on the Specht modules. 相似文献
20.