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81.
Harvey SD Mong GM Ozanich RM McLean JS Goodwin SM Valentine NB Fredrickson JK 《Analytical and bioanalytical chemistry》2006,386(2):211-219
A novel, affinity-augmented, bacterial spore-imprinted, bead material was synthesized, based on a procedure developed for
vegetative bacteria. The imprinted beads were intended as a front-end spore capture/concentration stage of an integrated biological
detection system. Our approach involved embedding bead surfaces with Bacillus thuringiensis kurstaki (Bt) spores (as a surrogate for Bacillus anthracis) during synthesis. Subsequent steps involved lithographic deactivation using a perfluoroether; spore removal to create imprint
sites; and coating imprints with the lectin, concanavalin A, to provide general affinity. The synthesis of the intended material
with the desired imprints was verified by scanning electron and confocal laser-scanning microscopy. The material was evaluated
using spore-binding assays with either Bt or Bacillus subtilis (Bs) spores. The binding assays indicated strong spore-binding capability and a robust imprinting effect that accounted for 25%
additional binding over non-imprinted controls. The binding assay results also indicated that further refinement of the surface
deactivation procedure would enhance the performance of the imprinted substrate. 相似文献
82.
氯化钠相转变 K-型卡拉胶/聚 N-异丙基丙烯酰胺共混凝胶的辐射合成及性质研究 总被引:6,自引:0,他引:6
用γ辐射技术合成了K 型卡拉胶 (KC)与聚N 异丙基丙烯酰胺共混凝胶 (Blendgels) .合成产物透明 ,有弹性和较好的力学强度 .对不同条件下共混凝胶性能的测定结果表明 ,所形成的共混凝胶有明显的氯化钠相转变性质 ,也保持了聚N 异丙基丙烯酰胺 (PNIPAM)特有的温度敏感性 (LCST为 34℃ ) 相似文献
83.
Graham C. Goodwin Juan I. Yuz Mario E. Salgado Juan C. Agüero 《Journal of Global Optimization》2012,52(2):335-351
Most physical systems operate in continuous time. However, to interact with such systems one needs to take samples. This raises the question of the relationship between the sampled response and the response of the underlying continuous-time system. In this paper we review several aspects of the sampling process. In particular, we examine the role played by variance and spectral density in describing discrete random processes. We argue that spectral density has several advantages over variance. We illustrate the ideas by reference to the problem of state estimation using the discrete-time Kalman filter. 相似文献
84.
高效液相色谱-串联质谱法测定动物源食品中粘杆菌素、多粘菌素B的残留量 总被引:2,自引:0,他引:2
建立了动物源食品中粘杆菌素和多粘菌素B残留的高效液相色谱-串联质谱(HPLC-MS/MS)测定方法。样品用V(10%三氯乙酸水溶液):V(乙腈)=30:70提取,Oasis WCX SPE柱净化,LC-MS/MS电喷雾正离子多反应监测模式(ESI+-MRM)检测。分析物在0~250μg/kg的浓度范围内呈良好线性,线性相关系数>0.995。方法的定量限为10μg/kg。方法在三个添加水平的平均回收率在71.6%~78.9%之间,相对标准偏差在6.2%~12%之间。方法适用于动物源食品中粘杆菌素和多粘菌素B的定量及确证检测。 相似文献
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86.
合同节水管理(WSMC)是一种用节约的水费支付改造成本并获取收益的节水模式,主要涉及用户与节水服务公司两个参与方。本文研究用户无法观测节水服务公司行动条件下固定投资回报型WSMC中的收益分配问题,该模式优先偿还投资,其次分享收益的特征需要激励机制诱使节水服务公司增加节水收益。首先,选取改造成本和节水量作为激励因素,设计用户对节水服务公司的激励合同,并构建节水量产出函数。其次,以用户的期望效用最大化为目标,建立用户对节水服务公司的激励模型并采用逆推法求解模型。再次,对均衡结果进行分析,结果表明:节水服务公司的最优成本分享比例和最优节水量分享比例与风险规避程度、努力成本系数和项目不确定性负相关;此外,最优节水量分享比例与综合能力正相关。最后,通过数值分析探讨分享比例和努力程度随合同参数的变化情况。 相似文献
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90.
Kieran W. P. Orr Sean M. Collins Emily M. Reynolds Frank Nightingale Hanna L. B. Bostrm Simon J. Cassidy Daniel M. Dawson Sharon E. Ashbrook Oxana V. Magdysyuk Paul A. Midgley Andrew L. Goodwin Hamish H.-M. Yeung 《Chemical science》2021,12(12):4494
Control over the spatial distribution of components in metal–organic frameworks has potential to unlock improved performance and new behaviour in separations, sensing and catalysis. We report an unprecedented single-step synthesis of multi-component metal–organic framework (MOF) nanoparticles based on the canonical ZIF-8 (Zn) system and its Cd analogue, which form with a core–shell structure whose internal interface can be systematically tuned. We use scanning transmission electron microscopy, X-ray energy dispersive spectroscopy and a new composition gradient model to fit high-resolution X-ray diffraction data to show how core–shell composition and interface characteristics are intricately controlled by synthesis temperature and reaction composition. Particle formation is investigated by in situ X-ray diffraction, which reveals that the spatial distribution of components evolves with time and is determined by the interplay of phase stability, crystallisation kinetics and diffusion. This work opens up new possibilities for the control and characterisation of functionality, component distribution and interfaces in MOF-based materials.Core–shell metal–organic framework nanoparticles have been synthesised in which the internal interface and distribution of components is found to be highly tunable using simple variations in reaction conditions. 相似文献