用于BNCT-SPECT的帕维亚TRIGA MARK II反应堆热柱优化设计

针对坐落于意大利帕维亚大学的TRIGA Mark II反应堆热柱结构进行优化设计,从而满足面向硼中子俘获治疗(BNCT)的单光子发射计算机断层成像(SPECT)研究要求。为提高计算效率并减小统计误差,对比分析使用SSW/SSR方法与直接使用反应堆为源项时热柱内照射位置处中子能谱,其结果基本一致,从而验证了SSW/SSR方法的可靠性。为在该反应堆开展BNCT中SPECT实验,热柱中子束需准直为笔形束。对比分析四种热柱优化方案下束流口处及探测器处热中子和光子通量：40 cm长石墨(射束口5 cm3 cm);0.5 cm厚硼包裹40 cm长石墨(射束口5 cm3 cm);30 cm长天然锂聚乙烯(射束口直径4 cm);30 cm长天然锂聚乙烯(20 cm长射束口直径5 cm,5 cm长射束口直径4 cm,5 cm长射束口直径2 cm)。结果显示,射束口处热中子通量分别为1.05108,2.52107,6.08107和5.10 107 #/(cm2s)。综合考虑中子准直效果及光子污染,方案三具有最优性能。为后续进行BNCT-SPECT理论和实验研究提供了基础,从而有效促进BNCT剂量准确评估方法的研究进程。     

强电磁脉冲上升时间对RS触发器损伤阈值仿真分析

对RS触发器中金属-氧化物-半导体场效应管（MOSFET）的烧毁作用进行研究,通过仿真分析在不同入射端口、不同上升时间的条件下RS触发器的损伤阈值,结合其内部温度分布图完成失效机理分析,进而得出对于上升时间长的强电磁脉冲,需要更高的峰值场强、更长的时间才能将RS触发器烧毁。     

平板型阶跃式变阻抗线特性

介绍了变阻抗线的工作原理,给出了类Blumlein线结构变阻抗线的倍压特性,变阻抗线能够实现能量的完全传输,输出电压为输入电压的(n+1)/2倍;以平板结构为例研究了变阻抗线中的阻抗偏差问题：传输线实际阻抗较理论设计值偏大,各级的偏差基本在20%以内;通过电磁仿真研究了三级类Blumlein线结构变阻抗线中各级阻抗偏差对于倍压系数的影响,在阻抗偏差范围内,倍压系数随着阻抗的增大而减小,倍压系数在1.9~2.1范围内,给出倍压系数受各级阻抗偏差的影响规律;设计了三级类Blumlein线结构平板传输线进行实验,输出电压为3833 V,与理论设计相符。     

金属氧化物半导体场效应管长期辐射效应的数值模拟

将粒子输运的蒙特卡罗方法与器件数值模拟的有限体积法相耦合来模拟典型金属氧化物半导体场效应管(MOSFET)的长期辐射效应。二氧化硅中的陷阱电荷及硅中的自由电子和空穴均使用漂移扩散模型来描述,入射粒子的能量沉积可作为源项耦合至漂移扩散模型方程,并根据有限体积法得到控制方程的离散格式,方程的数值解即为MOSFET的长期辐射响应结果。使用该方法模拟了MOSFET受射线粒子辐照后的阈值电压漂移与关态漏电流现象。结果表明,耦合方法适用于典型半导体器件长期辐射效应模拟,其阈值电压漂移及漏电流计算结果与文献符合较好。     

Nutritional Attributes and Phenolic Composition of Flower and Bud of Sophora japonica L. and Robinia pseudoacacia L.

Sophora japonica L. (SJL) and Robinia pseudoacacia L. (RPL) are widely cultivated in China. However, the utilization of their main by-products are limited due to a lack of comprehensive nutritional attributes. Herein, the proximate composition, mineral elements, fatty acids, amino acids, monosaccharides, and phenolics were analyzed to investigate the nutritional attributes of SJL and RPL. Dietary fiber was the main ingredient in SJL and RPL, followed by protein and lipids. The content of Fe in SJL and RPL was highest, especially in flowers of SJL, reaching about 1179.51 mg/kg. The total unsaturated fatty acids accounted for 89.67% of the bud of SJL. Meanwhile, the essential amino acids contents of the flower and bud of SJL and RPL accounted for 35.95–40.59% of total amino acids. The flower of SJL (373.75 mg/g) exhibited the most abundant monosaccharides. Meanwhile, the total phenolics and flavonoid contents in the buds of SJL and RPL were significantly higher than that of the flower, implying the buds possessed better biological activity. Moreover, the bud of SJL possessed the most abundant phenolics. The results provided a reference for the development of functional food derived from SJL and RPL.     

Thermally activated delayed fluorescence with dual-emission and pressure-induced bidirectional shifting: cooperative effects of intramolecular and intermolecular energy transfer

Different from the conventional piezochromic materials with a mono-redshift of single emission, our well-designed molecule demonstrates a sensitive turn-on and color-tunable piezochromic luminescence in response to the hydrostatic pressure. The molecule PXZ-W-SOF possesses dual-emission and pressure-induced bidirectional shifting characteristics. On the basis of in-depth experimental studies, on one hand, it is confirmed that the origin of the dual-emission behavior is the intramolecular charge transfer, namely thermally activated delayed fluorescence (TADF), and the intermolecular excimer; on the other hand, the emission of the excimer exhibits three-step variations with increasing pressure, which is mainly attributed to the molecular structure and its crystal packing state. The remarkable color change of PXZ-W-SOF from sky-blue to green to deep-blue during the whole process of boosting and releasing pressure is a result of intramolecular and intermolecular energy-transfer interactions. The PXZ-W-SOF molecular model is an extremely rare example of highly sensitive fluorescence tuning driven by TADF and excimer conversion under mechanical stimulation, thus providing a novel mechanism for the field of piezochromism. The unique molecular design also offers a new idea for rare deep-blue and ultraviolet TADF materials.

A high-contrast luminescent material exhibits dual-emission and pressure-induced bidirectional shifting, originating from the cooperative effects of TADF and excimers. It provides a novel mechanism for the piezochromic behavior.     

Self-recovery of chiral microphase separation in an achiral diblock copolymer system

Macroscopic regulation of chiral supramolecular nanostructures in liquid-crystalline block copolymers is of great significance in photonics and nanotechnology. Although fabricating helical phase structures via chiral doping and microphase separation has been widely reported, the chiral memory and self-recovery capacity of asymmetric phase structures are the major challenge and still deeply rely on the presence of chiral additives. Herein, we demonstrate the first controllable chiral microphase separation in an achiral amphiphilic block copolymer consisting of poly(ethylene oxide) and azobenzene (Azo) groups. Chirality can be transferred to the fabricated helical nanostructures by doping with chiral additives (tartaric acid, TA). After the removal of the chiral additives and then performing cross-linking, the formed helical nanostructures will completely dispense with the chiral source. The supramolecular chirality and the micron-scale phase structure can be maintained under UV irradiation and heating-cooling treatment, enabling a reversible “on–off” chiroptical switch feature. This work is expected to avoid the tedious synthesis and expensive raw materials and shows a great application prospect in chiral separation and so on.

A chirality-storing copolymer MPS structure will overcome the external chiral source dependence and avoid tedious synthesis and expensive raw materials.     

140 GHz菱形微带曲折线慢波 结构行波管的模拟计算

提出了一种新型的菱形微带曲折线慢波结构。该结构可适用于低电压、宽带宽、中等功率水平的高效率毫米波行波管。和传统的慢波结构相比,微带曲折线是一种平面结构,因此其加工工艺可采用2维微细加工技术。该结构可以用带状电子束进行注-波互作用,并且不需要额外的电子束通道。给出了菱形微带曲折线慢波结构在140 GHz的色散曲线和注-波互作用模拟分析。研究结果显示：在输入功率为40 mW,带状电子束的电流和工作电压分别为90 mA和7 kV的条件下,该微带曲折线行波管可以获得数十W功率输出,互作用效率可达14.3%,瞬时3 dB带宽为18 GHz(132～150 GHz)。     

卷绕式螺旋形薄膜介质脉冲形成线设计

采用模块化结构,设计了一种卷绕式螺旋形薄膜介质脉冲形成线,并且对绝缘材料、电极材料的选择依据进行了分析。基于模块化卷绕式脉冲形成线,研制的重复频率脉冲方波产生器采用4个开关同步触发四级形成线模块,从而实现多模块的电压串联叠加,以达到产生高压的目的。开关采用气体火花间隙开关,每级开关及充放电采用电感隔离。研制的脉冲产生器输出电压220 kV,脉冲宽度182 ns,前沿50 ns,可10 Hz重复频率稳定运行。     

电枢参数对电枢超导型高温超导电机性能的影响

高温超导材料存在背景磁场依赖性和各向异性的问题,针对超导感应电机采用双层绕组结构,提出了双重镜像法建立开口矩形槽内漏磁场垂直方向和水平方向的解析模型,利用该模型研究了超导线圈在传输不同电流情况下磁场分布规律,揭示了开口矩形槽电磁结构参数对槽内超导线圈所受表面磁场的影响规律。研究结果表明,适当增大槽宽尺寸可以有效降低超导线圈表面所受最大磁场,传输电流和线圈匝数均能够近乎线性增大超导线圈表面所受最大磁场。