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81.
E. I. Klimova C. Alvarez Toledano M. Martinez Garcia L. Gomez Lara N. N. Meleskonkova I. G. Bolesov 《Russian Chemical Bulletin》1996,45(3):613-619
Crystalline 3-ferrocenyl-3-phenylcyclopropene was obtained by dehydrobromination of 2-bromo-l-ferrocenyl-l-phenylcyclopropane with potassiumtert-butoxide in dimethyl sulfoxide. The compound synthesized undergoes catalytic hydrogenation to l-ferrocenyl-I-phenylcyclopropane, reacts with 1,3-diphenylisobenzofuran to give the expected product of stereospecific [4+2[-cycloaddition and 3-ferrocenylindene, and also undegoes opening of the small ring on treatment with superacids to give 3-ferrocenylindene as the major product. The data of single crystal X-ray diffraction analysis of 1-ferrocenyl-l-phenylcyclopropane and the diene adduct of 3-ferrocenyl-3-phenylcyclopropene with 1,3-diphenylisobenzofuran are given. 相似文献
82.
W. Ochs V. Davidson A. Dzierba A. Firestone W. Ford R. Gomez F. Nagy C. Peck C. Rosenfeld J. Ballam J. Carroll G. Chadwick D. Linglin K. Moffeit R. Ely D. Grether P. Oddone 《Nuclear Physics B》1976,102(3):405-428
We present data on momentum correlations both in and out of the production plane for the reactions π+p→πf+(π+n) and π?p→πf?(π?Δ++). The dissociation products show strikingly similar transverse momentum distributions which in terms of exchange models suggest an equal amount of pion and baryon exchange. For both reactions, we find an approximate factorization in the projectile frame between the transverse momentum of πf and the longitudinal momenta of the dissociation products. Exchange models predict this result equally in both reactions, but it appears much more clearly in the Δ reaction. Finally, we relate the observed longitudinal and transverse momentum distributions in a way suggested by an isotropic decay model. 相似文献
83.
Agustin Campos Rafael Gavara Roberto Tejero Clara Gomez Bernardo Celda 《Journal of Polymer Science.Polymer Physics》1989,27(8):1559-1597
The Flory–Huggins theory as modified by Pouchlý has been applied to calculate preferential (λ) and total (Y) sorption coefficients for a ternary polymer system. The ternary interaction function (?1?2?3GT(u1, ?3)) is described as the product of three independent binary functions. This expression allows prediction of λ and Y from binary interaction parameters χ, χ, g, g, and g12(?10). Three ternary polymer systems are used to check the validity of the expression. Moreover for polymer systems in which the parameters g and/or g are unknown, a procedure to evaluate them has been developed and verified on systems for which sufficient experimental information is available. 相似文献
84.
85.
Rodrigo P. Gomez 《manuscripta mathematica》1997,93(1):325-335
In this article we study the behavior of harmonic maps from compact connected Lie groups with bi-invariant metrics into a
Hilbert orthogonal group. In particular, we will demonstrate that any such harmonic map always has image contained within
someO(n),n<∞. Since homomorphisms are a special subset of the harmonic maps we get as a corollary an extension of the Peter-Weyl theorem,
namely, that every representation of a connected compact Lie group is finite dimensional.
This article was processed by the author using the LATEX style filecljour1 from Springer-Verlag. 相似文献
86.
J. L. C. Ford Jr. J. Gomez del Campo R. L. Robinson P. H. Stelson S. T. Thornton 《Zeitschrift für Physik A Hadrons and Nuclei》1974,269(2):147-153
States in20Ne were populated by the10B(16O,6Li) reaction, and levels were observed up to 11 MeV in excitation energy. Cross sections were measured at 7° (lab) for bombarding energies from 44.4 to 46 MeV in 400 keV intervals. The reaction appears to be predominantly due to compound nucleus formation, and good agreement was found between the measured cross sections and Hauser-Feshbach calculations, assuming the known spin values of20Ne. 相似文献
87.
J. L. Gomez Ribelles R. Diaz Calleja 《Journal of Polymer Science.Polymer Physics》1985,23(8):1505-1511
Some years ago, Brather proposed a method for calculation of the real and imaginary parts of the complex dielectric permittivity starting from measurements of isothermal polarization current. This method shows some advantages over the Hamon method, which is normally used. Both methods are applied in this work to the β relaxation of poly(butyl methacrylate). It is concluded that, with the usual accuracy of measurement, a combination of the two methods is advisable; Hamon's method is taken to be a first approximation to that of Brather. Results following the two procedures are compared, and their respective advantages and disadvantages are discussed. 相似文献
88.
Park J Gomez AL Walser ML Lin A Nizkorodov SA 《Physical chemistry chemical physics : PCCP》2006,8(21):2506-2512
Photolysis of alkene-terminated self assembled monolayers (SAM) deposited on Degussa SiO(2) nanoparticles is studied following oxidation of SAM with a gaseous ozone/oxygen mixture. Infrared cavity ring-down spectroscopy is used to observe gas-phase products generated during ozonolysis and subsequent photolysis of SAM in real time. Reactions taking place during ozonolysis transform alkene-terminated SAM into a photochemically active state capable of photolysis in the tropospheric actinic window (lambda > 295 nm). Formaldehyde and formic acid are the observed photolysis products. Photodissociation action spectra of oxidized SAM and the observed pattern of gas-phase products are consistent with the well-established Criegee mechanism of ozonolysis of terminal alkenes. There is strong evidence for the presence of secondary ozonides (1,3,4-trioxalones) and other peroxides on the oxidized SAM surface. The data imply that photolysis plays a role in atmospheric aging of primary and secondary organic aerosol particles. 相似文献
89.
Gomez AL Park J Walser ML Lin A Nizkorodov SA 《The journal of physical chemistry. A》2006,110(10):3584-3592
Oxidation of thin multilayered films of undecylenic (10-undecenoic) acid by gaseous ozone was investigated using a combination of spectroscopic and mass spectrometric techniques. The UV absorption spectrum of the oxidized undecylenic acid film is significantly red-shifted compared to that of the initial film. Photolysis of the oxidized film in the tropospheric actinic region (lambda > 295 nm) readily produces formaldehyde and formic acid as gas-phase products. Photodissociation action spectra of the oxidized film suggest that organic peroxides are responsible for the observed photochemical activity. The presence of peroxides is confirmed by mass-spectrometric analysis of the oxidized sample and an iodometric test. Significant polymerization resulting from secondary reactions of Criegee radicals during ozonolysis of the film is observed. The data strongly imply the importance of photochemistry in aging of atmospheric organic aerosol particles. 相似文献
90.
The ion complexes NO3-(HNO3)n, n = 1-3, have been studied by means of ab initio calculations at the B3LYP/aug-cc-pVTZ level of theory. These systems are the most abundant anionic clusters below approximately 30 km altitude in the stratosphere and also in the upper troposphere. These complexes display short strong hydrogen bonds, which should be considered to explain their abundance in the atmosphere. Equilibrium geometries, harmonic frequencies, relative energies, and thermochemical data have been calculated for these anions for the first time. The calculations indicate small differences of energy in the variation of the two nitrate groups from planarity to an almost perpendicular form for n = 1. Planar geometries are found for n = 2 and 3 to give rise to a highly symmetric C(3h) NO3-(HNO3)3. In all the cases, binding energies close to those of covalent compounds are estimated. When experimental data are available, good correlations are found with our results. 相似文献