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21.
The effects of viscous dissipation and heat source/sink on fully developed mixed convection for the laminar flow in a parallel-plate vertical channel are investigated.The plate exchanges heat with an external fluid.Both conditions of equal and different reference temperatures of the external fluid are considered.First,the simple cases of the negligible Brinkman number or the negligible Grashof number are solved analytically.Then,the combined effects of buoyancy forces and viscous dissipation in the presence of heat source/sink are analyzed by a perturbation series method valid for small values of the perturbation parameter.To relax the conditions on the perturbation parameter,the velocity and temperature fields are solved by using the Runge-Kutta fourth-order method with the shooting technique.The velocity,temperature,skin friction,and Nusselt numbers at the plates are discussed numerically and presented through graphs. 相似文献
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The main injector particle production (MIPP) experiment at Fermilab uses particle beams of charged pions, kaons, proton and antiproton with beam momenta of 5?C90 GeV/c to measure particle production cross-sections of various nuclei including liquid hydrogen, MINOS target and thin targets of beryllium, carbon, bismuth and uranium. The physics motivation to perform such cross-section measurements is described here. Recent results on the analysis of NuMI target and forward neutron cross-sections are presented here. Preliminary cross-section measurements for 58 GeV/c proton on liquid hydrogen target are also presented. A new method is described to correct for low multiplicity inefficiencies in the trigger using KNO scaling. 相似文献
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To understand the role of isospin effects on fragmentation due to the collisions of charge asymmetric nuclei, we have performed a complete systematical study using isospin-dependent quantum molecular dynamics model. Here simulations have been carried out for $^{124}{\rm X}_{n}+^{124}{\rm X}_{n}$ , where n varies from 47 to 59 and for $^{40}{\rm Y}_{m}+^{40}{\rm Y}_{m}$ , where m varies from 14 to 23. Our study shows that isospin-dependent cross-section shows its influence on fragmentation in the collision of neutron-rich nuclei. 相似文献
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An Rm-valued sequence (xk): = (xk : k = 1, 2, ...), e.g. generatedrecursively by xk = fk (xkk, Uk), is called averagepth power bounded if (1/K) is bounded uniformly in K= 1, 2,.... (The case p = 2 may correspond to powerin the physical sense.) This is a notion of stability. Givenestimates of the form: fk (x, u) < a x + ¶ k conditionsare obtained on the coefficient sequence (ak) and the inputestimates ek:=¶k (uk) which ensure this form of stabilityfor the output (xk). In particular, a condition (utilized inan application to adaptive control) is obtained which imposes(i) a bound b on (ak) and a sparsity measure m(K) on #{kK: ak>} as K ( >1) (ii) average pth power boundednesson (ek), and (iii) a growth condition on (ek) related to b andm (). This condition is sharp. 相似文献
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RUB MalikAbdul ASIRIAbdullah M KUMAR Dileep AZUM Naved KHAN Farah 《物理化学学报》2014,30(4):699-707
The mixed micellization behavior of an amphiphilic antidepressant drug amitriptyline hydrochloride(AMT)in the presence of the conventional anionic surfactant sodium bis(2-ethylhexyl)sulfosuccinate(AOT)was studied at five different temperatures and compositions by the conductometric technique.The critical micelle concentration(cmc)and critical micelle concentration at the ideal state(cmcid)values show mixed micelle formation between the components(i.e.,drug and AOT).The micellar mole fractions of the AOT(X1)values calculated using the Rubingh,Motomura,and Rodenas models show a higher contribution of AOT in the mixed micelles.The interaction parameter(β)is negative at all temperatures and the compositions show attractive interactions between the components.The activity coefficients(f1and f2)calculated using the different proposed models are always less than unity indicating non-ideality in the systems.TheΔGmΘ values were found to be negative for all the binary mixed systems.However,ΔHmΘ values for the pure drug as well as the drug-AOT mixed systems are negative at lower temperatures(293.15-303.15 K)and positive at higher temperatures(308.15 K and above).TheΔSmΘ values are positive at all temperatures but their magnitude was higher at T=308.15 K and above.The excess free energy of mixing(ΔGex)determined using the different proposed models also explains the stability of the mixed micelles compared to the pure drug(AMT)and surfactant micelles. 相似文献
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Nucleophilic Substitution Reactions of Meta‐ and Para‐Substituted Benzylamines with Benzyl Bromide in Methanol Medium 下载免费PDF全文
The rates of reactions of para‐ and meta‐substituted benzylamines with benzyl bromide were measured using conductivity technique in methanol medium. The reaction followed a total second‐order path. The end product of the reaction is identified as dibenzylamine (X‐C6H4CH2NHCH2C6H5) (where X = 4‐OCH3, 4‐CH3, H, 4‐Cl, 4‐CF3, 3‐CF3, 4‐NO2). Electron‐withdrawing groups such as chloro, trifluoromethyl, and nitro in the benzylamine moiety decrease the rate of the reaction, whereas the electron‐donating groups, such as methoxy and methyl, increase the rate compared to the unsubstituted compound. A mechanism involving formation of an SN2‐type transition state between the amine nucleophiles and the benzyl bromide and its subsequent decomposition is proposed. Hammett's reaction constant ρ of the reaction decreases with an increase in temperature. Activation parameters were calculated and discussed. 相似文献
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The pyrolysis of eucalyptus wood was carried out in a batch reactor to optimize the yield of bio-oil.Effect of various parameters like feed(particle) size,temperature,presence of catalyst and heating rate on the yield of bio-oil was investigated.The optimum conditions for high yield of bio-oil are for the particle size 2 mm~5 mm(average l/d=12.84/2.03 mm) at 450 ℃ in high heating rate.The reaction kinetics and the quality of bio-oil produced are independent of the presence of different catalysts like mordenite,kaoline clay,fly ash and silica alumina.The physical properties like odour,colour,PH,viscosity,heating value were determined.The FT-IR analysis of bio-oil indicates the presence of different functional groups such as monomeric alcohol,phenol,ketones,aldehydes,carboxylic acid,amines,and nitro compounds.The composition of the bio-oil at different conditions was analyzed using GC-MS and found that the components are temperature dependent but independent of catalysts used. 相似文献
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Optical fibre probes or optrodes often form the heart of multimode fibre-based measurements and sensors. An optrode usually comprises a bundle of multimode fibres, out of which one or more fibres are used for irradiating the sample, and the remaining fibres are used to collect the light reflected/scattered/fluoresced from the sample containing the measurand(s). The so-collected light carries the characteristic signature of the measurand. Here we present our work on the design and realization of optrodes for the measurement of scattered light from liquid samples. Optical properties of a solution are usually characterized by the parameters absorption coefficient μ a , scattering coefficient μ s , and anisotropy factor g. We have developed a simple method to determine μ a , μ s , and g, of a turbid medium, and a Monte–Carlo model was used to simulate the light scattering from the turbid medium. As an application, we describe the development of a turbidity sensor that has been designed and realized by employing an optrode in conjunction with a concave mirror. The estimation of turbidity is done on the basis of total interaction, by considering scattering and absorption of light from the sample solution. Details of the experiments and results are presented here. 相似文献