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61.
and
provided a variety of
and
alkaloids as well as novel ring-opened indole alkaloids including leuconolam (6), rhazinilam (8) and 5,21-dihydrorhazinilam (9). Facile acid and base reactions of leuconolam lead to ring reclosure products. Physical and spectral data of norfluorocurarine (
), norfluorocurarine-Nb-oxide (
), eburnamine (2), kopsinine (5) and epileuconolam (7) as well as some derivatives of leuconolam are also provided. 相似文献
62.
63.
We find that the fractal scaling in a class of scale-free networks originates from the underlying tree structure called a skeleton, a special type of spanning tree based on the edge betweenness centrality. The fractal skeleton has the property of the critical branching tree. The original fractal networks are viewed as a fractal skeleton dressed with local shortcuts. An in silico model with both the fractal scaling and the scale-invariance properties is also constructed. The framework of fractal networks is useful in understanding the utility and the redundancy in networked systems. 相似文献
64.
Ang CY Boeré RT Goh LY Koh LL Kuan SL Tan GK Yu X 《Chemical communications (Cambridge, England)》2006,(45):4735-4737
The title heterocyclic radicals coordinate to either 17e CpCr(CO)3 or 15e CpCr(CO)2 moieties as one-electron or as three-electron donors, respectively; in the former the bonding is via the perpendicular p orbital of the sulfur atom, while in the latter bonding is via p(pi) orbitals on both sulfur and nitrogen. 相似文献
65.
Testing is an important activity in product development. Past studies, which are developed to determine the optimal scheduling of tests, often focused on single-stage testing of sequential design process. This paper presents an analytical model for the scheduling of tests in overlapped design process, where a downstream stage starts before the completion of upstream testing. We derive optimal stopping rules for upstream and downstream stages’ testing, together with the optimal time elapsed between beginning the upstream tests and beginning the downstream development. We find that the cost function is first convex then concave increasing with respect to upstream testing duration. A one-dimensional search algorithm is then proposed for finding the unique optimum that minimizes the overall cost. Moreover, the impact of different model parameters, such as the problem-solving capacity and opportunity cost, on the optimal solution is discussed. Finally, we compare the testing strategies in overlapped process with those in sequential process, and get some additional results. The methodology is illustrated with a case study at a handset design company. 相似文献
66.
Takami T Arnold DP Fuchs AV Will GD Goh R Waclawik ER Bell JM Weiss PS Sugiura K Liu W Jiang J 《The journal of physical chemistry. B》2006,110(4):1661-1664
Initial stages of two-dimensional crystal growth of the double-decker sandwich complex Lu(Pc*)2 [Pc* = 2,3,9,10,16,17,23,24-octakis(octyloxy)phthalocyaninato] have been studied by scanning tunneling microscopy at the liquid/solid interface between 1-phenyloctane and highly oriented pyrolytic graphite. High-resolution images strongly suggest alignment of the double-decker molecules into monolayers with the phthalocyanine rings parallel to the surface. Domains were observed with either hexagonal or quadrate packing motifs, and the growing interface of the layer was imaged. Molecular resolution was achieved, and the face of the phthalocyanine rings appeared as somewhat diffuse circular features. The alkyl chains are proposed to be interdigitating to maintain planar side-by-side packing. 相似文献
67.
Extending band-limited constructions of orthonormal refinable functions, a special class of periodic functions is used to generate a family of band-limited refinable functions. Characterizations of Riesz bases and frames formed by integer shifts of these refinable functions are obtained. Such families of refinable functions are employed to construct band-limited biorthogonal wavelet bases and biframes with desirable time-frequency localization. 相似文献
68.
Nickel(II) meso‐Hydroxyporphyrin Complexes Revisited: Palladium‐Catalysed Synthesis,Electronic Structures of Derived Oxy Radicals,and Oxidative Coupling to a Dioxoporphodimethene Dyad 下载免费PDF全文
Dr. Louisa J. Esdaile Dr. Llew Rintoul Mean See Goh Khalissa Merahi Dr. Nathalie Parizel Dr. R. Mark Wellard Dr. Sylvie Choua Prof. Dennis P. Arnold 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(10):3430-3446
We report the synthesis and characterisation of new examples of meso‐hydroxynickel(II) porphyrins with 5,15‐diphenyl and 10‐phenyl‐5,15‐diphenyl/diaryl substitution. The OH group was introduced by using carbonate or hydroxide as nucleophile by using palladium/phosphine catalysis. The NiPor?OHs exist in solution in equilibrium with the corresponding oxy radicals NiPor?O.. The 15‐phenyl group stabilises the radicals, so that the 1H NMR spectra of {NiPor?OH} are extremely broad due to chemical exchange with the paramagnetic species. The radical concentration for the diphenylporphyrin analogue is only 1 %, and its NMR line‐broadening was able to be studied by variable‐temperature NMR spectroscopy. The EPR signals of NiPor?O. are consistent with somewhat delocalised porphyrinyloxy radicals, and the spin distributions calculated by using density functional theory match the EPR and NMR spectroscopic observations. Nickel(II) meso‐hydroxy‐10,20‐diphenylporphyrin was oxidatively coupled to a dioxo‐terminated porphodimethene dyad, the strongly red‐shifted electronic spectrum of which was successfully modelled by using time‐dependent DFT calculations. 相似文献
69.
70.
Amanda M Goh Kylie J Walters Suzanne Elsasser Rati Verma Raymond J Deshaies Daniel Finley Peter M Howley 《BMC biochemistry》2008,9(1):4