The large deformation of nonlinearly elastic rings in a two-dimensional compressible flow

The nonlinear nonlocal system of the equilibrium equations ofan elastic ring under the action of an external two-dimensionaluniformly subsonic potential barotropic steady-state gas flowis considered. The configurations of the elastic ring are identifiedby a pair of functions (, ). The simple curve represents theshape of the ring and the real-valued function identifies theorientation of the material sections of the ring. The pressurefield on the ring depends nonlocally on , and on two parametersU and P which represent the pressure and the velocity at infinity.The system is shown to be equivalent to a fixed-point problem,which is then treated with continuation methods. It is shownthat the solution branch ensuing from certain equilibrium states((₀, ₀), 0, P₀) in the solution-parameter space of ((₀, ₀),0, P₀) either approaches the boundary of the admissible ((,), U,p)'s in a well-defined sense, or is unbounded, or is homotopicallynontrivial in the sense that there exists a continuous map from the branch to a two-dimensional sphere which is not homotopicin the sphere to a constant, while restricted to the branchminus ((₀, ₀), 0, P₀) is homotopic to a constant in the sphere.Furthermore, by fixing the pressure parameter at P₀ and by consideringthe one-parameter problem in ((, ), U), the following holds.Every hyperplane in the solution-parameter space of the ((,), U)'s which contains the equilibrium state ((₀, ₀), 0) anddoes not include a welldetermined one-dimensional subspace intersectsthe solution branch above at a point different from ((₀, ₀),0).     

The wewakpeptins, cyclic depsipeptides from a Papua New Guinea collection of the marine cyanobacterium Lyngbya semiplena

Four new depsipeptides have been isolated from the marine cyanobacterium Lyngbya semiplena collected from Papua New Guinea. The amino and hydroxy acid partial structures of wewakpeptins A-D (1-4) were elucidated through extensive spectroscopic techniques, including HR-FABMS, 1D (1)H and (13)C NMR, as well as 2D COSY, HSQC, HSQC-TOCSY, and HMBC spectra. The sequence of the residues was determined through a combination of multifaceted approaches including ESI-MS/MS, HMBC, ROESY, and a modified 1D HMBC experiment. The absolute stereochemistry of each residue was determined by chiral HPLC and chiral GC-MS methods. The wewakpeptins represent an unusual arrangement of amino and hydroxy acid subunits relative to known cyanobacterial peptides and possess a bis-ester, a 2,2-dimethyl-3-hydroxy-7-octynoic acid (Dhoya) or 2,2-dimethyl-3-hydroxyoctanoic acid (Dhoaa) residue, and a diprolyl group reminiscent of dolastatin 15. Wewakpeptin A and B were the most cytotoxic among these four depsipeptides with an LC(50) of approximately 0.4 muM to both the NCI-H460 human lung tumor and the neuro-2a mouse neuroblastoma cell lines.     

THE INFLUENCE OF CYLINDER LUBRICATION ON PISTON SLAP

A model has been developed for determining the time history of piston slap impact force. This model takes into account the influence of the oil film on the impact behaviour, which was found to be an important factor. However, it was also found that entrapped gas bubbles in the oil are equally significant. Three test rigs were designed and built to study these effects on the impact phenomenon and extensive tests were carried out. The impact force time history has been determined using Reynolds' theory. Results have shown that Reynolds' theory for fluid film squeezing can be applied for oil film damping determination. However, the experimental results have also shown that when gas is entrapped during the impact, this theory considerably overpredicts the magnitude of the impact. An eight-degree-of-freedom lumped parameter model was developed through the dynamic analysis of each component of an internal combustion engine's reciprocating system. The effective damping factor derived from this model was found to be inversely proportional to the oil film thickness cubed, as expected from Reynolds' theory. A dynamic model has been proposed, where the oil film mixed with bubbles is considered to be analogous to a serial spring and damping system. By incorporating a spring in series with this damper, the effect of the bubbles can also be predicted.     

由混合激发钠分子—原子系统产生的强度振荡变化的红外受激喇曼散射

本文报道以等频二步激发钠分子-原子系统,观测到强度随泵浦光的调谐而呈振荡变化的3P—4P受激喇曼散射,以及对应4D—4P和4F—3D跃迁的红外受激辐射和由四波混频产生的816.8～822.1nm区内可调谐相干辐射。文中对这些过程进行了分析讨论。     

Electronic surface structure of <Emphasis Type="Italic">n</Emphasis>-ML Ag/Cu(111) and Cs/<Emphasis Type="Italic">n</Emphasis>-ML Ag/Cu(111) as investigated by 2PPE and STS

We investigated the electronic structure of epitaxially grown silver films on Cu(111) with and without adsorption of cesium by means of scanning tunneling spectroscopy and two-photon photoemission. This system has been chosen as a model system to engineer and measure the dynamics of charge-transfer processes between an adsorbate and a heterogeneous substrate. Special emphasis has been laid on the investigation of the energy shift of the Shockley-type surface state and an excited cesium resonance as a function of Ag film thickness. For the cesium resonance we observe an increase in line width with increasing layer thickness. PACS 68.37.Ef; 68.43.-h; 68.55.Jk; 73.20.-r     

Structure and biosynthesis of the jamaicamides, new mixed polyketide-peptide neurotoxins from the marine cyanobacterium Lyngbya majuscula

A screening program for bioactive compounds from marine cyanobacteria led to the isolation of jamaicamides A-C. Jamaicamide A is a novel and highly functionalized lipopeptide containing an alkynyl bromide, vinyl chloride, beta-methoxy eneone system, and pyrrolinone ring. The jamaicamides show sodium channelblocking activity and fish toxicity. Precursor feeding to jamaicamide-producing cultures mapped out the series of acetate and amino acid residues and helped develop an effective cloning strategy for the biosynthetic gene cluster. The 58 kbp gene cluster is composed of 17 open reading frames that show an exact colinearity with their expected utilization. A novel cassette of genes appears to form a pendent carbon atom possessing the vinyl chloride functionality; at its core this contains an HMG-CoA synthase-like motif, giving insight into the mechanism by which this functional group is created.     

A Study of the Oxidation Pathway of Adrenaline by Cyclic Voltammetry: An Undergraduate Analytical Chemistry Laboratory Exercise

An undergraduate laboratory exercise to be used in an undergraduate instrumental methods course is presented for the electrochemical characterization of oxidation products of adrenaline. An objective of this experiment is to use information obtained through cyclic voltammetry and simulation software to develop a qualitative understanding of the oxidation mechanism of adrenaline.     

Magnetic hyperfine fields in Heusler alloys Co YZ (Y=Ti,Zr; Z=Al,Ga,Sn)

Magnetic hyperfine fields (mhf) acting on Ta at the Ti and Zr sites have been measured in Heusler alloys Co₂TiAl(Ga,Sn) and Co₂ZrAl(Sn) by the TDPAC technique utilizing the 133–482 keV gamma cascade in¹⁸¹Hf. Curie temperatures of all the alloys have also been measured using a vibrating sample magnetometer. Present data together with the existing results on the Co₂HfAl(Ga,Sn) are discussed and compared with the mhf systematics in Heusler alloys.work partially supported by CNEN and CNPq