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141.
The nonlinear nonlocal system of the equilibrium equations ofan elastic ring under the action of an external two-dimensionaluniformly subsonic potential barotropic steady-state gas flowis considered. The configurations of the elastic ring are identifiedby a pair of functions (, ). The simple curve represents theshape of the ring and the real-valued function identifies theorientation of the material sections of the ring. The pressurefield on the ring depends nonlocally on , and on two parametersU and P which represent the pressure and the velocity at infinity.The system is shown to be equivalent to a fixed-point problem,which is then treated with continuation methods. It is shownthat the solution branch ensuing from certain equilibrium states((0, 0), 0, P0) in the solution-parameter space of ((0, 0),0, P0) either approaches the boundary of the admissible ((,), U,p)'s in a well-defined sense, or is unbounded, or is homotopicallynontrivial in the sense that there exists a continuous map from the branch to a two-dimensional sphere which is not homotopicin the sphere to a constant, while restricted to the branchminus ((0, 0), 0, P0) is homotopic to a constant in the sphere.Furthermore, by fixing the pressure parameter at P0 and by consideringthe one-parameter problem in ((, ), U), the following holds.Every hyperplane in the solution-parameter space of the ((,), U)'s which contains the equilibrium state ((0, 0), 0) anddoes not include a welldetermined one-dimensional subspace intersectsthe solution branch above at a point different from ((0, 0),0). 相似文献
142.
Four new depsipeptides have been isolated from the marine cyanobacterium Lyngbya semiplena collected from Papua New Guinea. The amino and hydroxy acid partial structures of wewakpeptins A-D (1-4) were elucidated through extensive spectroscopic techniques, including HR-FABMS, 1D (1)H and (13)C NMR, as well as 2D COSY, HSQC, HSQC-TOCSY, and HMBC spectra. The sequence of the residues was determined through a combination of multifaceted approaches including ESI-MS/MS, HMBC, ROESY, and a modified 1D HMBC experiment. The absolute stereochemistry of each residue was determined by chiral HPLC and chiral GC-MS methods. The wewakpeptins represent an unusual arrangement of amino and hydroxy acid subunits relative to known cyanobacterial peptides and possess a bis-ester, a 2,2-dimethyl-3-hydroxy-7-octynoic acid (Dhoya) or 2,2-dimethyl-3-hydroxyoctanoic acid (Dhoaa) residue, and a diprolyl group reminiscent of dolastatin 15. Wewakpeptin A and B were the most cytotoxic among these four depsipeptides with an LC(50) of approximately 0.4 muM to both the NCI-H460 human lung tumor and the neuro-2a mouse neuroblastoma cell lines. 相似文献
143.
A model has been developed for determining the time history of piston slap impact force. This model takes into account the influence of the oil film on the impact behaviour, which was found to be an important factor. However, it was also found that entrapped gas bubbles in the oil are equally significant. Three test rigs were designed and built to study these effects on the impact phenomenon and extensive tests were carried out. The impact force time history has been determined using Reynolds' theory. Results have shown that Reynolds' theory for fluid film squeezing can be applied for oil film damping determination. However, the experimental results have also shown that when gas is entrapped during the impact, this theory considerably overpredicts the magnitude of the impact. An eight-degree-of-freedom lumped parameter model was developed through the dynamic analysis of each component of an internal combustion engine's reciprocating system. The effective damping factor derived from this model was found to be inversely proportional to the oil film thickness cubed, as expected from Reynolds' theory. A dynamic model has been proposed, where the oil film mixed with bubbles is considered to be analogous to a serial spring and damping system. By incorporating a spring in series with this damper, the effect of the bubbles can also be predicted. 相似文献
144.
145.
M.?Wessendorf C.?Wiemann M.?BauerEmail author M.?Aeschlimann M.A.?Schneider H.?Brune K.?Kern 《Applied Physics A: Materials Science & Processing》2004,78(2):183-188
We investigated the electronic structure of epitaxially grown silver films on Cu(111) with and without adsorption of cesium by means of scanning tunneling spectroscopy and two-photon photoemission. This system has been chosen as a model system to engineer and measure the dynamics of charge-transfer processes between an adsorbate and a heterogeneous substrate. Special emphasis has been laid on the investigation of the energy shift of the Shockley-type surface state and an excited cesium resonance as a function of Ag film thickness. For the cesium resonance we observe an increase in line width with increasing layer thickness. PACS 68.37.Ef; 68.43.-h; 68.55.Jk; 73.20.-r 相似文献
146.
Edwards DJ Marquez BL Nogle LM McPhail K Goeger DE Roberts MA Gerwick WH 《Chemistry & biology》2004,11(6):817-833
A screening program for bioactive compounds from marine cyanobacteria led to the isolation of jamaicamides A-C. Jamaicamide A is a novel and highly functionalized lipopeptide containing an alkynyl bromide, vinyl chloride, beta-methoxy eneone system, and pyrrolinone ring. The jamaicamides show sodium channelblocking activity and fish toxicity. Precursor feeding to jamaicamide-producing cultures mapped out the series of acetate and amino acid residues and helped develop an effective cloning strategy for the biosynthetic gene cluster. The 58 kbp gene cluster is composed of 17 open reading frames that show an exact colinearity with their expected utilization. A novel cassette of genes appears to form a pendent carbon atom possessing the vinyl chloride functionality; at its core this contains an HMG-CoA synthase-like motif, giving insight into the mechanism by which this functional group is created. 相似文献
147.
148.
An undergraduate laboratory exercise to be used in an undergraduate instrumental methods course is presented for the electrochemical characterization of oxidation products of adrenaline. An objective of this experiment is to use information obtained through cyclic voltammetry and simulation software to develop a qualitative understanding of the oxidation mechanism of adrenaline. 相似文献
149.
Magnetic hyperfine fields (mhf) acting on Ta at the Ti and Zr sites have been measured in Heusler alloys Co2TiAl(Ga,Sn) and Co2ZrAl(Sn) by the TDPAC technique utilizing the 133–482 keV gamma cascade in181Hf. Curie temperatures of all the alloys have also been measured using a vibrating sample magnetometer. Present data together with the existing results on the Co2HfAl(Ga,Sn) are discussed and compared with the mhf systematics in Heusler alloys.work partially supported by CNEN and CNPq 相似文献
150.
用真空电弧熔炼法制备了Ce2 Co17-xMx(M =Ga ,Al和Si)化合物。通过X射线衍射和磁性测量手段 ,研究了非磁性替代原子Ga,Al和Si的加入对Ce2 Co17化合物的居里温度和饱和磁化强度的影响 ,其中Si在Ce2 Co17化合物中的固溶度最小 ,并使居里温度和饱和磁化强度下降幅度最大。 相似文献