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761.
762.
In the present work, the effect of the oxidizing treatment with nitric acid on three activated carbon samples has been studied. The influence of the acid treatment on the surface groups of the different samples has been investigated by means of FT-IR spectroscopy. The pore size distributions of the different samples were determined by means of the HK and DFT methods. The HK method points out a moderate increment of the microporosity due to the action of the nitric acid, whereas the DFT method shows an increase in the microporosity range above 17 Å. Finally, the values of the fractal dimension reveal that the treatment of the samples with nitric acid leads to chemical reactions of a limited extent. 相似文献
763.
We apply a Bayesian approach to the problem of prediction in an unbalanced growth curve model using noninformative priors. Due to the complexity of the model, no analytic forms of the predictive densities are available. We propose both approximations and a prediction-oriented Metropolis-Hastings sampling algorithm for two types of prediction, namely the prediction of future observations for a new subject and the prediction of future values for a partially observed subject. They are illustrated and compared through real data and simulation studies. Two of the approximations compare favorably with the approximation in Fearn (1975, Biometrika, 62, 89–100) and are very comparable to the more accurate Rao-Blackwellization from Metropolis-Hastings sampling algorithm. 相似文献
764.
This report focuses on a theoretical study of the cobalt-cabon bond activation mechanism in Vitamin B12, its co enzyme complexes, and model compounds such as cobalamins (Cbl), cobaloximes and cobalt porphyrins. In particular, emphasis is placed on the nucleotide loop and its role in the base on and base off mechanism. 相似文献
765.
C.-S. Huang T. Li L. Wei Q.-S. Yan 《The European Physical Journal C - Particles and Fields》2002,23(1):195-199
It is shown that new sources of CP violation can be generated in models with more than one extra dimension. In the supersymmetric models on the space-time , where the radius moduli have auxiliary vacuum expectation values and the supersymmetry breaking is mediated by the Kaluza–Klein
states of the gauge supermultiplets, we analyze the gaugino masses and trilinear couplings for two scenarios and obtain the
result that there exist relative CP violating phases among the gaugino masses and trilinear couplings.
Received: 10 October 2001 / Published online: 20 December 2001 相似文献
766.
T.M. Mishonov N. Chéenne D. Robbes J.O. Indekeu 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(3):291-296
The generation of harmonics of the voltage response is considered when an AC current is applied through a superconducting
film above Tc. It is shown that almost at all temperatures the mechanism of the temperature oscillations created by the AC current and
the temperature dependence of the resistance dominates over the isothermal nonlinear electric conductivity. Only in a narrow
critical region close to Tc the latter is essential for the generation of the harmonics. A detailed investigation of harmonics generation provides an
accurate method for measuring the thermal boundary conductance between the film and the insulating substrate. The critical
behaviour of the third harmonic will give a new method for the determination of the lifetime of metastable Cooper pairs above
Tc. The comparison of the calculated fifth harmonics of the voltage with the experiment is proposed as an important test for
the applicability of the employed theoretical models.
Received 8 September 2001 相似文献
767.
Ying Zhang Gang Hu Shigang Chen H.A. Cerdeira 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,27(3):381-384
A method of controlling global stochasticity in Hamiltonian systems by applying nonlinear perturbation is proposed. With the
well-known standard map we demonstrate that this control method can convert global stochasticity into regular motion in a
wide chaotic region for arbitrary initial condition, in which the control signal remains very weak after a few kicks. The
system in which chaos has been controlled approximates to the original Hamiltonian system, and this approach appears robust
against small external noise. The mechanism underlying this high control efficiency is intuitively explained.
Received 15 January 2002 Published online 6 June 2002 相似文献
768.
R. Németh 《Journal of statistical physics》1991,63(1-2):419-424
We calculate the site occupation probabilities of one-dimensional lattice gas models within the canonical and grand canonical ensembles. The appearing differences do not vanish if we increase the system size keeping the site energies discrete. In this way one can explain the surprising numerical results of Barszczak and Kutner. This effect in the single-site occupation number disappears in higher dimensions. 相似文献
769.
Barotropic FRW cosmologies are presented from the standpoint of nonrelativistic supersymmetry. First, we reduce the barotropic FRW system of differential equations to simple harmonic oscillator differential equations. Employing the factorization procedure, the solutions of the latter equations are divided into the two classes of bosonic (nonsingular) and fermionic (singular) cosmological solutions. We next introduce a coupling parameter denoted by K between the two classes of solutions and obtain barotropic cosmologies with dissipative features acting on the scale factors and spatial curvature of the universe. The K-extended FRW equations in comoving time are presented in explicit form in the low coupling regime. The standard barotropic FRW cosmologies correspond to the dissipationless limit K = 0. 相似文献
770.
Apurba Bhattacharya Nitin C. Patel Michael Peddicord Luca Parlanti John A. Grosso 《Tetrahedron letters》2006,47(30):5341-5343
An efficient, one-pot, phase transfer N-amination technology was developed. The protocol utilizes chloramine, an inexpensive and safe electrophilic aminating agent potentially viable for commercial manufacturing. 相似文献