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Sergio Deflorian Nir Barnea Winfried Leidemann Giuseppina Orlandini 《Few-Body Systems》2014,55(8-10):831-834
The Schrödinger equation is solved for an A-nucleon system using an expansion of the wave function in nonsymmetrized hyperspherical harmonics. The present approach is based on a formalism developed by Gattobigio et al. (Phys. Rev. A 79:032513, 2009; Few-Body Syst. 45:127–131, 2009; Phys. Rev. C 83:024001, 2011). Spin and isospin degrees of freedom are included; this makes possible calculations with realistic NN potential models. The fermionic ground state is determined by introducing an additional potential term involving the Casimir operator such that the antisymmetric ground state becomes the lowest eigenstate of the A-body system. Results are discussed for 4He with the realistic AV18 NN potential and for 6Li with the semirealistic MTI/III NN potential. 相似文献
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E Ghedini V Nichele M Signoretto G Cerrato 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(34):10653-10660
A series of titanium oxides was prepared by using a surfactant-template method (STM) and used as a carrier for the sustained release of ibuprofen, which was chosen as a model drug. This STM provides an efficient route to TiO(2) matrices with both high surface area (when compared with those that were obtained by using traditional synthetic approaches) and well-defined mesoporous textures. Some parameters of the synthetic procedure were varied: pH value, surfactant, and thermal treatment. The physicochemical nature of the surface carriers were investigated by means of N(2) -physisorption measurements and FTIR spectroscopy. The effect of the amount of drug on the release kinetics was also investigated. The drug delivery was evaluated in vitro in four different physiological solutions (that simulated the gastrointestinal tract) to analyze the behavior of the TiO(2) -based systems if they were to be formulated as oral DDSs. Our optimized approach is a good alternative to the classical methods that are used to prepare efficient TiO(2) -based drug-delivery systems. 相似文献
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The aim of this paper is to establish the existence of an unbounded sequence of weak solutions for a class of differential equations with p(x)-Laplacian and subject to small perturbations of nonhomogeneous Neumann conditions. The approach is based on variational methods. 相似文献
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Maria Enrica Di Pietro Giorgio Celebre Giuseppina De Luca Herbert Zimmermann Giorgio Cinacchi 《The European physical journal. E, Soft matter》2012,35(10):1-10
Solute molecules were dissolved in the liquid crystal 4-cyano-4??-n-octyloxybiphenyl (8OCB), known to form a partial bilayer smectic-A phase. Through measurement of solutes?? and solvent??s orientational order parameters via nuclear magnetic resonance spectroscopy, and their analysis via a statistical thermodynamic density functional theory, values of the solvent??s positional order parameters and solutes?? positional-orientational distribution functions were obtained. Near to the transition to the nematic phase, the main positional order parameter of the smectic liquid crystal turned out to be comprised in the interval 0.4?C0.6, though the quality of the fittings assuming the phase as nematic all across the temperature range investigated was only slightly worse. This may be ascribed to the looseness of the partial bilayer smectic structure. Solutes were found to preferentially lie in those regions where liquid crystal molecule terminal chains are located. 相似文献
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A Di Fiore A Maresca CT Supuran G De Simone 《Chemical communications (Cambridge, England)》2012,48(70):8838-8840
Hydroxamates (R-CONHOH) have been scarcely investigated as carbonic anhydrase (CA, EC 4.2.1.1) inhibitors (CAIs). An inhibition/structural study of PhCONHOH is reported against all human isoforms. Comparing aliphatic (R = Me and CF(3)) and aromatic (R = Ph) hydroxamates as CAIs, we prove that CONHOH is a versatile zinc binding group. Depending on the nature of the R moiety, it can adopt different coordination modes to the catalytic ion within the CA active site. 相似文献
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James E. Castle Anna Maria Salvi Roberta Flamia Giuseppina Satriano 《Surface and interface analysis : SIA》2012,44(2):246-257
Polypeptides can form helical fibres in aqueous media: potentially useful for the production of biocompatible fabric and yarns. A previous work has shown that fibre formation occurs readily with elastin‐like polypeptides constructed from hydrophobic amino acids, such as valine, glycine and leucine. However, elastin‐like polypeptides, when suspended in methyl alcohol, are observed to form globules and ‘string of bead’ structures. Thus, it seems probable that the interface energy is important. Interface energy is minimised by the formation of bonds extending from one phase to the other: a phenomenon that is central to adhesion science. We have looked for evidence of such bonding using XPS to study structures formed by poly(ValGlyGlyLeuGly). The structures formed were first characterised by atomic force microscopy. Differences were found between structures and spectra formed in either water or methanol. No evidence for the presence of unique bonds characterising the interface was found, but evidence was found for the influence of a water environment on the internal structure, suggesting that it is the increase in intermolecular bonding opportunities associated with the influence of water on the growth of fibres that is the thermodynamic driver for the observed transformation into fibre deposits. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献