An original perspective on variable-order fractional operators for viscoelastic materials

Meccanica - This work deals with viscoelastic constitutive models involving variable-order fractional operators. There exist two main fractional models in the literature representing the...     

Turning the Light on Phenols: New Opportunities in Organic Synthesis

Phenols ( I ) are extremely relevant chemical functionalities in natural, synthetic and industrial chemistry. Their corresponding electron-rich anions, namely phenolates ( I ), are characterized by interesting physicochemical properties that can be drastically altered upon light excitation. Specifically, phenolates ( I ) become strong reducing agents in the excited state and are able to generate reactive radicals from suitable precursors via single-electron transfer processes. Thus, these species can photochemically trigger strategic bond-forming reactions, including their direct aromatic C−H functionalization. Moreover, substituted phenolate anions can act as photocatalysts to enable synthetically useful organic transformations. An alternative mechanistic manifold is represented by the ability of phenolate derivatives I to form ground state electron donor-acceptor (EDA) complexes with electron-poor radical sources. These complementary scenarios have paved the way for the development of a wide range of relevant organic reactions. In this Minireview, we present the main examples of this research field, and give insight on emerging trends in phenols photocatalysis towards richer organic synthesis.     

Rapid Resolution Liquid chromatography/High Resolution Tandem Mass Spectrometry to Characterize Metabolic Changes in Subjects Involved in MARS500 Project

A rapid resolution liquid chromatography-tandem mass spectrometry analysis was applied to human urine samples to discover new molecular biomarkers of the alteration of psychophysical well-being due to the environmental, physiological and confinement stress conditions achieved in the MARS500 project. Urine samples of crew members were submitted to metabolomic studies by means of separative techniques coupled with mass spectrometric techniques and data analysis. More than 2,000 metabolite features were found in each comparison, and more than 150 metabolites were identified for every differential analysis. Significant modifications in eight metabolites were shared by the subjects under study.     

Evaluation of different light-curing lamps

The aim of this study has been to evaluate light-curing composites polymerization quality carried out by halogen and new-diode lamps through the thermal analysis (TG?CDTA). Samples have been polymerized at 3?C20?C40?C60?s by halogen lamp and 1?C3?C6?C9?s by new-diode lamp. The TG/DTA analysis shows that different light-curing times affect the degree of conversion of the composite, since by increasing the curing time the quantity of the monomer that has not reacted (residual) decreases. The new-diode lamp, according to the manufacturer, can cure composite restorations in few seconds; but at the conditions used in this study, the samples cured by the halogen lamp at the standard times of exposure, compared to the samples cured in few seconds by the new-diode lamp, show a lower mass loss.     

High-order divergence-free velocity reconstruction for free surface flows on unstructured Voronoi meshes

In this paper, we present an efficient semi-implicit scheme for the solution of the Reynolds-averaged Navier-Stokes equations for the simulation of hydrostatic and nonhydrostatic free surface flow problems. A staggered unstructured mesh composed by Voronoi polygons is used to pave the horizontal domain, whereas parallel layers are adopted along the vertical direction. Pressure, velocity, and vertical viscosity terms are taken implicitly, whereas the nonlinear convective terms as well as the horizontal viscous terms are discretized explicitly by using a semi-Lagrangian approach, which requires an interpolation of the three-dimensional velocity field to integrate the flow trajectories backward in time. To this purpose, a high-order reconstruction technique is proposed, which is based on a constrained least squares operator that guarantees a globally and pointwise divergence-free velocity field. A comparison with an analogous reconstruction, which is not divergence-free preserving, is also presented to give evidence of the new strategy. This allows the continuity equation to be satisfied up to machine precision even for high-order spatial discretizations. The reconstructed velocity field is then used for evaluating high-order terms of a Taylor method that is here adopted as ODE integrator for the flow trajectories. The proposed semi-implicit scheme is validated against a set of academic test problems, and proof of convergence up to fourth-order of accuracy in space is shown.     

Variational Convergences of Dual Energy Functionals for Elastic Materials with a ε-Thin Strong Inclusion

We give a new derivation, based on the complementary energy formulation, of a simplified model for a multi-structure made up of two anisotropic hyper-elastic bodies connected by a thin strong material layer. The model is obtained by identifying the Mosco-limit of the stored complementary energy functional when the thickness is of order ?? and the stiffness of order 1/?? where ?? is a positive real adimensional parameter. In order to prove the existence of the displacement associated with the stress we use a suitable weak version of the Saint-Venant compatibility condition also known as Donati??s theorem.