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891.
Joshua Avossa Francesco Branda Francesco Marulo Giuseppe Petrone Stefano Guido Giovanna Tomaiuolo Aniello Costantini 《高分子科学》2018,36(12):1368-1374
Light polymeric soundproofing materials(density = 63 kg/m~3) of interest for the transportation industry were fabricated through electrospinning. Blankets of electrospun polyvinylpyrrolidone(average fiber diameter =(1.6 ± 0.5) or(2.8 ± 0.5) μm) were obtained by stacking disks of electrospun mats. The sound absorption coefficients were measured using the impedance tube instrument based on ASTM E1050 and ISO 10534-2. For a given set of disks(from a minimum of 6) the sound absorption coefficient changed with the frequency(in the range 200–1600 Hz) following a bell shape curve with a maximum(where the coefficient is greater than 0.9) that shifts to lower frequencies at higher piled disks number and greater fiber diameter. This work showed that electrospinning produced sound absorbers with reduced thickness(2–3 cm) and excellent sound-absorption properties in the low and medium frequency range. 相似文献
892.
In this paper we study the remarkable subsets of a semilinear space like cliques, anticliques, blocking sets and ovoids.to Helmut Mäurer on his 60th birthday 相似文献
893.
This paper deals with polarized pairs
, where
is a nonsingular projective threefold and
is a very ample line bundle on it, such that for one smooth member  |
|, one has (Â)=2. A large class of pairs whose adjoint line bundle is nef and big was indirectedly studied by Beltrametti and co-workers. We add some more information, both in this general case and also when the adjoint line bundle fails to be nef and big. 相似文献
894.
LetC(X,Y) be the space of continuous functions from a metric space (X,d) to a metric space (Y, e).C(X, Y) can be thought as subset of the hyperspaceCL(X×Y) of closed and nonempty subsets ofX×Y by identifying each element ofC(X,Y) with its graph. We considerC(X,Y) with the topology inherited from the Wijsman topology induced onCL(X×Y) by the box metric ofd ande. We study the relationships between the Wijsman topology and the compact-open topology onC(X,Y) and also conditions under which the Wijsman topology coincide with the Fell topology. Sufficient conditions under which the
compactopen topology onC(X,Y) is weaker than the Wijsman topology are given (IfY is totally bounded, then for every metric spaceX the compactopen topology onC(X,Y) is weaker than the Wijsman topology and the same is true forX locally connected andY rim-totally bounded). We prove that a metric spaceX is boundedly compact iff the Wijsman topology onC(X, ℝ) is weaker than the compact-open topology. We show that ifX is a σ-compact complete metric space andY a compact metric space, then the Wijsman topology onC(X,Y) is Polish. 相似文献
895.
896.
Giuseppe Arena Raffaele P. Bonomo Annalinda Contino Fabio G. Gulino Antonio Magrì Domenico Sciotto 《Journal of inclusion phenomena and macrocyclic chemistry》1997,29(3-4):347-363
A new water soluble receptor 5,11,17,23-tetrasulphonato-25,27-di(hydroxycarbonylmethoxy)-26,28-dihydroxycalix[4]arene was synthesized andcharacterized and its proton and copper(II) complexes were studied andcompared with the analogous species of the fully carboxylated ligand5,11,17,23-tetrasulphonato-25,26,27,28-tetrakis(hydroxycarbonylmethoxy)calix[4]arene. H° and S° values are crucial for understanding thepeculiar acid-base properties of the ligand. EPR spectra together with theUV-VIS spectral data reveal the coordination stereochemistry of thecopper(II) species. 相似文献
897.
898.
Biosynthetic studies have shown that pheomelanins, the distinctive pigments of red human hair, arise from oxidative polymerization of cysteinyldopas via 1,4-benzothiazinylalanine intermediates. However, the mode of formation of the pigment polymer remains controversial. To address this point, we have investigated the conversion of the major biosynthetic precursor 5-S-cysteinyldopa (2a) to pheomelanin under biomimetic conditions. Peroxidase/H(2)O(2) oxidation of 2a was shown to lead in the early stages to the 1,4-benzothiazinylalanine 8a, which rapidly declines with concomitant formation of a distinct pattern of oligomeric products. Reduction of the reaction mixture at this stage allowed the isolation of dimer 17 in 10% yield, along with trimers 18 and 19 in smaller amounts. A restricted rotation about the ethereal C-O bond of 17 was apparent by the presence of two NMR-detectable conformational isomers, separated by an activation energy barrier of 17.83 +/- 0.03 kcal mol(-)(1). Under similar oxidation conditions, the model catechol 2b gave the related dimers 15 and 16. The structure of oligomers 17-19, all characterized by C-C and C-O bonds between the benzothiazine units, would suggest that the peroxidase-promoted polymerization proceeds by phenol-type coupling of an aryloxy radical generated by initial one-electron oxidation of 8a. Overall, these results point to a structural model for the pheomelanin polymer which is basically different from that proposed on the basis of degradative studies. 相似文献
899.
Antonello Santini Ettore Benedetti Carlo Pedone Giuseppe Caliendo Vincenzo Santagada Paolo Grieco Elisa Perissutti 《Structural chemistry》1996,7(3):173-181
The solid-state molecular conformations and crystal structures of three analogues of the CP-96,345 molecule, an important nonpeptidic SP antagonist, namely the (±)-2-(3-phenylbenzilidene)-3-(2-benzylamino) quinuclidine, theo-chloro- and theo-methoxy-derivatives, have been determined by X-ray diffusion analyses and refined to finalR values of 0.055, 0.045, and 0.056, respectively. All three molecules in the solid state show the same disposition of the substituents of the double bond and differences in the conformation mainly caused by the need of releasing intramolecular strains and/or nonbonded interactions. The observed molecular structures are compared to the reported solid-state structure of the CP-96,345 and correlated to the biological activity as NK antagonists. 相似文献
900.
Nicol Vivona Giuseppe Cusmano Michele Ruccia Domenico Spinelli 《Journal of heterocyclic chemistry》1975,12(5):985-988
The first example of mononuclear isoheterocyclic rearrangement is reported. The 3-benzoylamino-5-methyl-1,2,4-oxadiazole ( 5 ) furnishes through a reversible process (slowly at room temperature in methanol, acetone or dioxane, fast in DMSO or in methanol in the presence of strong bases) a mixture of 5 and 3-acethylamino-5-phenyl-1,2,4-oxadiazole ( 6 ). The equilibrium process can be achieved also by heating 5 at 181° and the same reaction mixture can be obtained using 6 as the starting material. 3-Trichloroacetylamino-5-methyl-1,2,4-oxadiazole ( 7 ) was unaffected by similar treatment. The results obtained are discussed. 相似文献