Development of micro‐XANES mapping in the diamond anvil cell

Energy‐dispersive X‐ray absorption spectroscopy is now a well established method that has been applied to a broad range of applications. At the energy‐dispersive EXAFS beamline of the ESRF, ID24, the recently achieved 5 × 5 µm focal spot combined with fast acquisition has allowed complex and non‐uniform samples to be mapped and images to be obtained where each pixel contains full XAS information. This method has been applied to a study under extreme conditions of pressure and temperature in a diamond anvil cell in transmission mode. The case study was the investigation of the Fe K‐edge XANES of (Mg,Fe)SiO₃‐perovskite and (Mg,Fe)O‐ferropericlase on decomposition of the spinel‐structured olivine [γ‐(Mg,Fe)₂SiO₄] at 78 (3) GPa after laser heating at 2200 (100) K.     

Dual cure composites: Could body temperature offset the absence of light activation?

Journal of Thermal Analysis and Calorimetry - Dual cure composites contain both chemically and light-induced polymerization initiators, taking advantage of both processes; however, some...     

Influence of shear stress and size on viability of endothelial cells exposed to gold nanoparticles

Screening nanoparticle toxicity directly on cell culture can be a fast and cheap technique. Nevertheless, to obtain results in accordance with those observed in live animals, the conditions in which cells are cultivated should resemble the one encountered in live systems. Microfluidic devices offer the possibility to satisfy this requirement, in particular with endothelial cell lines, because they are capable to reproduce the flowing media and shear stress experienced by these cell lines in vivo. In this work, we exploit a microfluidic device to observe how human umbilical vein endothelial cells (HUVEC) viability changes when subject to a continuous flow of culture medium, in which spherical citrate-stabilized gold nanoparticles of different sizes and at varying doses are investigated. For comparison, the same experiments are also run in multiwells where the cells do not experience the shear stress induced by the flowing medium. We discuss the results considering the influence of mode of exposure and nanoparticle size (24 and 13 nm). We observed that gold nanoparticles show a lower toxicity under flow conditions with respect to static and the HUVEC viability decreases as the nanoparticle surface area per unit volume increases, regardless of size.     

A method for correcting the reverberation times of enclosures as a function of humidity and temperature

The decay rate of sound within large enclosures depends on air humidity and temperature. This phenomenon must be taken into account in most problems of architectural acoustics; generally, the measurement data obtained in actual humidity and temperature conditions should be normalized to standard conditions. In this paper a simple procedure for correcting the measured reverberation time and the related program, implemented on a Texas Instruments T1–59 personal calculator, are presented.     

A reduction technique for discrete generalized algebraic and difference Riccati equations

This paper proposes a reduction technique for the generalized Riccati difference equation arising in optimal control and optimal filtering. This technique relies on a study on the generalized discrete algebraic Riccati equation. In particular, an analysis on the eigenstructure of the corresponding extended symplectic pencil enables to identify a subspace in which all the solutions of the generalized discrete algebraic Riccati equation are coincident. This subspace is the key to derive a decomposition technique for the generalized Riccati difference equation. This decomposition isolates a “nilpotent” part, which converges to a steady-state solution in a finite number of steps, from another part that can be computed by iterating a reduced-order generalized Riccati difference equation.