Deformation produced by a simple tensile load in an isotropic elastic body

It is shown that a simple tensile load produces a simple extension provided the empirical inequalities (Truesdell and Noll [1], eqn. 51.27) hold.     

Rheodynamic lubrication of a journal bearing

Summary The problem of a journal bearing lubricated by a Bingham material has been solved. It has been found that the load capacity, and the moment of friction of the bearing are larger than in a journal bearing, lubricated with a Newtonian material.Nomenclature r radius of the journal - c radial clearance - r + c radius of the bearing - e eccentricity - w angular velocity of the journal - h thickness of the lubricant film at any point - thickness of the core - ø angular distance of a point, from the point, where film thickness is maximum - eccentricity ratio (e/c) - x distance along the bearing surface - y distance normal to the bearing surface - T shear stress in the lubricant - T ₀ yield value of a Bingham solid - viscosity of a Newtonian fluid - plastic viscosity of a Bingham solid - p fluid pressure in the lubricant film - Q volume flow of the lubricant - W ₀ load capacity of the bearing for ordinary lubricants - W load capacity of the bearing - M moment of friction - F coefficient of friction - ₁ maximum thickness of the inlet core - ₂ maximum thickness of the outlet core - ₁ circumferential extent of the inlet core in the journal bearing - ₂ circumferential extent of the outlet core in the journal bearing - h ₀ minimum hieght of core formation in the slider bearing - h _p maximum height of core formation in the slider bearing - u velocity of the fluid in the direction of x in the slider bearing - V velocity in the y direction - h ₁ height of the inlet core at the circumferential extent ₁ - h ₂ height of the outlet core at the circumferential extent ₂ - h ₃ height of the outlet core in the region ₂ - q Q/(cwr) - q ₀ value of q for Newtonian lubricants - p ₀ pressure at =0 - H h/c - H ₁ h ₁/c - H ₂ h ₂/c - B T ₀ C/wr = Bingham number     

A Second-Order Solution of Saint-Venant's Problem for an Elastic Pretwisted Bar Using Signorini's Perturbation Method

We use Signorini's expansion to analyse deformations of a straight, prismatic, isotropic, stress free, homogeneous body made of a second-order elastic material and loaded as follows. It is first twisted by an infinitesimal amount and then loaded by applying surface tractions, with nonzero resultant forces and/or moments, only at its end faces. The centroid of one end face is taken to be rigidly clamped. By using a semi-inverse method, the problem is reduced to that of solving two plane elliptic problems involving six arbitrary constants that characterize flexure, bending, extension, and torsion superimposed upon the infinitesimal twist. It is shown that the Clebsch hypothesis is not valid for this problem. A second-order Poisson's effect, not of the Saint-Venant type, and generalized Poynting effects may also occur in these problems. This revised version was published online in August 2006 with corrections to the Cover Date.     

Chemical kinetics of dissolution of BaMoO4 crystals

An etchant capable of revealing the sites of dislocations in the flux-grown crystals of BaMoO₄ has been established. Using this etchant (HNO₃), effect of etching time, acid concentration and temperature on the selective etch rate is demonstrated. It is established that the process of dissolution in unstirred HNO₂ solutions is one of the diffusion rate controlled; an empirical equation governing the kinetics has been suggested.     

Mixed Chloro Bis[Alkylenedithiophosphato] Antimony(III) and Their Heterobinuclear Derivatives with Boron Tetraisopropoxide: Synthesis and Characterization

Chloro bis(alkylenedithiophosphato)antimony(III) complexes of the type [OGOP(S)S]₂SbCl (1–5) [where G = —C(Me)₂—CH₂—CH(Me)—1 —C(Me)₂—C(Me)₂—2, —CH₂—C(Me)₂—CH₂—3, —CH(Me)—CH(Me)—4 and –CH(Me)—CH₂—CH₂—5] have been synthesized by the reaction of SbCl₃ with sodium salts of alkylenedithiophosphoric acids in a 1:2 molar ratio in refluxing benzene. Reactions of chloro bis(alkylenedithiophosphato) antimony(III) compounds, [OGOP(S)S]₂SbCl with sodium tetraisopropoxoborate, NaB(OPrⁱ)₄, in a 1:1 molar ratio in refluxing benzene yielded some new heterobinuclear derivatives of antimony(III) and boron(III) of the type[OGOP(S)S]₂Sb(μ—OPrⁱ)₂B(OPrⁱ)₂. These newly synthesized complexes have been characterized by elemental analysis and molecular weight measurement, and their plausible structures have been proposed on the basis of IR, NMR (¹H, ¹³C,³¹P,¹¹B), and FAB-mass spectral studies. On the basis of the spectroscopic evidence, a pseudo octahedral geometry around antimony and tetrahedral geometry around boron atom has been proposed. Cyclic O,O′-alkylenedithiophosphate ligands and their corresponding chloro bis(alkylenedithiophosphato)antimony(III) compounds have been screened for microbial activities. These compounds showed significant antifungal activity against Fusarium and Trichoderma and antibacterial activity against E. Coli and Pseudomonas.

Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.     

NaNO2/I2 as an alternative reagent for the synthesis of 1,2,3-benzotriazin-4(3H)-ones from 2-aminobenzamides

An efficient transformation of 2-aminobenzamides to 1,2,3-benzotriazin-4(3H)-ones in the presence of sodium nitrite (NaNO₂) and Iodine (I₂) is described. The reaction is proposed to proceed via formation of nitrosyl halide that induces nitrosylation of the amino group of 2-aminobenzamide leading to diazotization followed by intramolecular cyclization.     

Phosphorylation and Thiophosphorylation of 2-Substituted Benzoxazoles and Their Biological Activities

Novel organophosphorus compounds have been conveniently prepared using 2-(2′-hydroxynapthyl)benzoxazole and 2-(2′-aminophenyl)benzoxazole as starting materials. Phosphorylation and thiophosphorylation was performed using different molar ratio (1:1, 1:2 and 1:3) of phosphorus oxychloride/thiophosphoryl chloride and substituted benzoxazole. The toxicity of newly synthesized phosphorylated/thiophosphorylated compounds was tested on Aspergillus niger and Fusarium oxysporium. All were found antifungal agents. Plausible structures have been proposed on the basis of IR, ¹ H NMR, ³¹ P NMR spectral studies.     

Synthesis and Antimicrobial Studies of Organophosphates Derived From 2-(2″-Hydroxynaphthyl)Benzoxazole

Abstract

A series of biologically active phenoxy derivatives of 2-substituted benzoxazole organophosphates have been synthesized by the reaction of O-(naphthyl benzoxazolyl-2-) phosphorodichloridate/phosphorodichloridothioate with phenol/4-chlorophenol/4-nitroph- enol in 1:1 and 1:2 molar ratios. These compounds have been characterized on the basis of elemental analysis, IR, ¹H NMR, ³¹P NMR, and mass spectral studies. The antibacterial activity of these 2-substituted benzoxazole phenoxy derivatives has been evaluated against pathogenic bacteria Staphylococcus aureus (+ve) and Escherichia coli (?ve). The antifungal activity of these 2-substituted benzoxazole phenoxy derivatives has been evaluated against pathogenic fungi Aspergillus niger and Fusarium oxysporium. All compounds were found to have significant antibacterial and antifungal activity.     

Straightforward copper-catalyzed synthesis of pyrrolopyrazoles from halogenated pyrazolecarbaldehydes

Straightforward synthesis of a variety of pyrrolo-fused pyrazoles via a cascade reaction between halopyrazolecarbaldehydes and ethylisocyanoacetate in the presence of copper and a base is described.     

Fabrication of an amperometric tyramine biosensor based on immobilization of tyramine oxidase on AgNPs/l-Cys-modified Au electrode

An amperometric tyramine biosensor was constructed based on covalent immobilization of black gram tyramine oxidase onto citric acid-capped silver nanoparticles bound to surface of Au electrode through cysteine self-assembled monolayer. The enzyme electrode was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, and cyclic voltametry. The biosensor showed optimum response within 8 s, when polarized at 0.25 V, pH 8.5, and 35 °C, with linearity from 0.017 to 0.25 mM and a detection limit of 0.01 mM. The biosensor was employed for measurement of tyramine in beer and sauce. The mean analytical recovery of added tyramine in beer at 0.36 and 0.72 mM were 97.2?±?2.7 and 95.8?±?4.1 %, respectively, and within and between batches coefficients of variation were 0.33–0.38 and 0.34–0.62 %, respectively. The enzyme electrode lost 35 % of its initial activity after its 100 uses, over a period of 2 months, when stored at 4 °C.