全文获取类型
收费全文 | 13440篇 |
免费 | 377篇 |
国内免费 | 46篇 |
专业分类
化学 | 10728篇 |
晶体学 | 75篇 |
力学 | 210篇 |
数学 | 1667篇 |
物理学 | 1183篇 |
出版年
2023年 | 107篇 |
2022年 | 450篇 |
2021年 | 507篇 |
2020年 | 283篇 |
2019年 | 332篇 |
2018年 | 253篇 |
2017年 | 215篇 |
2016年 | 436篇 |
2015年 | 446篇 |
2014年 | 422篇 |
2013年 | 832篇 |
2012年 | 864篇 |
2011年 | 977篇 |
2010年 | 595篇 |
2009年 | 580篇 |
2008年 | 820篇 |
2007年 | 799篇 |
2006年 | 682篇 |
2005年 | 624篇 |
2004年 | 525篇 |
2003年 | 443篇 |
2002年 | 433篇 |
2001年 | 165篇 |
2000年 | 132篇 |
1999年 | 112篇 |
1998年 | 115篇 |
1997年 | 99篇 |
1996年 | 127篇 |
1995年 | 86篇 |
1994年 | 84篇 |
1993年 | 78篇 |
1992年 | 61篇 |
1991年 | 75篇 |
1990年 | 54篇 |
1989年 | 72篇 |
1988年 | 62篇 |
1987年 | 49篇 |
1986年 | 52篇 |
1985年 | 64篇 |
1984年 | 82篇 |
1983年 | 43篇 |
1982年 | 67篇 |
1981年 | 60篇 |
1980年 | 55篇 |
1979年 | 46篇 |
1978年 | 54篇 |
1977年 | 38篇 |
1976年 | 32篇 |
1975年 | 24篇 |
1963年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
Let {B
1
d
(t)} and {B
d
2(t)} be independent Brownian motions in R
d
starting from 0 and nx respectively, and let w
d
i
(a,b) ={xR
d
: B
d
i
(t)=x for some t(a,b)}, i=1,2. Asymptotic expressions as n for the probability of dist(w
d
1(n
2
t
1, n
2
t
2), w
2
d
(0,n
2
t
3))1 with d4, respectively for the probability of dist(w
1
4(n
2
t
1,n
2
t
2),w
2
4(0,n
2
t
3))1 are obtained. As an application, an improvement of a result due to M. Aizenman concerning the intersections of Wiener sausages in R
4 is presented. 相似文献
992.
A domain
is the domain of holomorphy of the generating function of a Pólya frequency sequence of order r if and only if it satisfies the following conditions: (A) G contains the point z = 0, (B) G is symmetric with respect to the real axis, (C) T = dist(0,G)G. 相似文献
993.
The effect of irradiation on concentrations and relaxation behaviour of brain metabolites was studied by means of high-resolution 1H NMR in vitro. The studies were performed on rat brains irradiated with the doses of 20 Gy applied in fractions of 2 Gy. Standard procedures were used to obtain HClO4 extracts of rat brains. The 1H NMR studies of the extracts solutions in D2O were performed using a Varian Inova-300 NMR spectrometer. The integral intensities of the metabolite signals were found to change during the irradiation cycle and after it. These changes are accompanied by the variations in the T1 relaxation times. N-acetylaspartate, glycerophosphocholine, phosphocholine, choline, creatine and phosphocreatine, myoinositol and taurine were analysed as potential markers of irradiation injury. 相似文献
994.
995.
In this paper, we prove higher integrability results for the gradient of the solutions of some elliptic equations with degenerate
coercivity whose prototype is
where for example, a(x,u)=(1+|u|)−θ with θ ∈ (0,1). We study the same problem for minima of functionals closely related to the previous equation. 相似文献
996.
Low-power laser irradiation improves histomorphometrical parameters and bone matrix organization during tibia wound healing in rats 总被引:7,自引:0,他引:7
Garavello-Freitas I Baranauskas V Joazeiro PP Padovani CR Dal Pai-Silva M da Cruz-Höfling MA 《Journal of photochemistry and photobiology. B, Biology》2003,70(2):81-89
The influence of daily energy doses of 0.03, 0.3 and 0.9 J of He-Ne laser irradiation on the repair of surgically produced tibia damage was investigated in Wistar rats. Laser treatment was initiated 24 h after the trauma and continued daily for 7 or 14 days in two groups of nine rats (n=3 per laser dose and period). Two control groups (n=9 each) with injured tibiae were used. The course of healing was monitored using morphometrical analysis of the trabecular area. The organization of collagen fibers in the bone matrix and the histology of the tissue were evaluated using Picrosirius-polarization method and Masson's trichrome. After 7 days, there was a significant increase in the area of neoformed trabeculae in tibiae irradiated with 0.3 and 0.9 J compared to the controls. At a daily dose of 0.9 J (15 min of irradiation per day) the 7-day group showed a significant increase in trabecular bone growth compared to the 14-day group. However, the laser irradiation at the daily dose of 0.3 J produced no significant decrease in the trabecular area of the 14-day group compared to the 7-day group, but there was significant increase in the trabecular area of the 15-day controls compared to the 8-day controls. Irradiation increased the number of hypertrophic osteoclasts compared to non-irradiated injured tibiae (controls) on days 8 and 15. The Picrosirius-polarization method revealed bands of parallel collagen fibers (parallel-fibered bone) at the repair site of 14-day-irradiated tibiae, regardless of the dose. This organization improved when compared to 7-day-irradiated tibiae and control tibiae. These results show that low-level laser therapy stimulated the growth of the trabecular area and the concomitant invasion of osteoclasts during the first week, and hastened the organization of matrix collagen (parallel alignment of the fibers) in a second phase not seen in control, non-irradiated tibiae at the same period. The active osteoclasts that invaded the regenerating site were probably responsible for the decrease in trabecular area by the fourteenth day of irradiation. 相似文献
997.
A prototype calix[4]arene-based receptor for carbohydrate recognition containing peptide and phosphate binding groups 总被引:2,自引:0,他引:2
Segura M Bricoli B Casnati A Muñoz EM Sansone F Ungaro R Vicent C 《The Journal of organic chemistry》2003,68(16):6296-6303
A novel class of macrobicyclic receptors for carbohydrate recognition based on upper rim, peptide-bridged calix[4]arenes has been designed and synthesized. Receptor 12, in which a charged phosphate group cooperates with peptide hydrogen-bonding donor and acceptor groups in the binding process, is the most efficient and selective in the complexation of simple carbohydrate derivatives. The selectivity observed is toward beta-glucoside 13a, which is better bound (DeltaG degrees = 19.6 kJ mol(-)(1)) compared to the corresponding alpha anomer 13b (DeltaG degrees = 17.0 kJ mol(-)(1)) and to the beta-galactoside 13c (DeltaG degrees = 17.7 kJ mol(-)(1)) in CDCl(3). A substantial drop in the stability constant is observed by esterification of the phosphate group in the host 12 or by alkylation of the OH groups in the 2 and 3 positions in the beta-glucoside and beta-galactoside derivatives. On the basis of a careful analysis of the (1)H NMR data available, a binding mode of the beta-octylglucoside 13a to receptor 12 is proposed. 相似文献
998.
Coelho CJ Galvão RK de Araújo MC Pimentel MF da Silva EC 《Journal of chemical information and computer sciences》2003,43(3):928-933
A novel strategy for the optimization of wavelet transforms with respect to the statistics of the data set in multivariate calibration problems is proposed. The optimization follows a linear semi-infinite programming formulation, which does not display local maxima problems and can be reproducibly solved with modest computational effort. After the optimization, a variable selection algorithm is employed to choose a subset of wavelet coefficients with minimal collinearity. The selection allows the building of a calibration model by direct multiple linear regression on the wavelet coefficients. In an illustrative application involving the simultaneous determination of Mn, Mo, Cr, Ni, and Fe in steel samples by ICP-AES, the proposed strategy yielded more accurate predictions than PCR, PLS, and nonoptimized wavelet regression. 相似文献
999.
Gutsul EI Belkova NV Sverdlov MS Epstein LM Shubina ES Bakhmutov VI Gribanova TN Minyaev RM Bianchini C Peruzzini M Zanobini F 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(10):2219-2228
The reactions of the octahedral dihydrido complexes [MH(2)(PP(3))] [M=Fe, Ru, Os; PP(3)=P(CH(2)CH(2)PPh(2))(3)] with a variety of weak ROH acids have been studied by IR and NMR methods in either CH(2)Cl(2) or THF in the temperature range from 190 to 290 K. This study has allowed the determination of the spectral and thermodynamic properties associated with the formation of dihydrogen bonds (DHB) between the terminal hydrides and the OH group. Both the DHB enthalpy values and the hydride basicity factors (E(j)) have been found to increase in the order Fe < Ru < Os. The proton transfer process, leading to the DHB complexes, and eventually to eta(2)-H(2) products, has been found to depend on the acidic strength of the alcohol as well as the nature of the solvent. Low temperature IR and NMR techniques have been used to trace the complete energy profile of the proton transfer process involving the osmium complex [OsH(2)(PP(3))] with trifluoroethanol. 相似文献
1000.
Bassindale AR MacKinnon IA Maesano MG Taylor PG 《Chemical communications (Cambridge, England)》2003,(12):1382-1383
Hexasilsesquioxane cages (T6) have been prepared from a range of alkyl and aryl trichlorosilanes using a "non aqueous" hydrolysis with dimethyl sulfoxide. 相似文献