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Hans-Christoph Kaiser Hagen Neidhardt Joachim Rehberg 《Monatshefte für Mathematik》2009,45(3):179-185
The negative quantum mechanical particle density in its dependence on the potential in the Hamiltonian is a nonlinear operator.
We give an explicit proof of the monotonicity of this operator for a large class of admissible thermodynamic equilibrium distribution
functions. In particular the zero temperature case is included. 相似文献
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215.
Christian P. Marcel M. Rohde T.H.J.J. Van Der Hagen 《Experimental Thermal and Fluid Science》2009,33(8):1197-1208
During the start-up phase, natural circulation BWRs (NC-BWRs) need to be operated at low pressure conditions. Such conditions favor flashing-induced instabilities due to the large hydrostatic pressure drop induced by the tall chimney. Moreover, in novel NC-BWR designs the steam separation is performed in the steam separators which create large pressure drops at the chimney outlet, which effect on stability has not been investigated yet.In this work, flashing-induced oscillations occurring in a tall, bottom heated channel are numerically investigated by using a simple linear model with three regions and an accurate implementation for estimating the water properties. The model is used to investigate flashing-induced instabilities in a channel for different values of the core inlet friction value. The results are compared with experiments obtained by using the CIRCUS facility at the same conditions, showing a good agreement. In addition, the experiments on flashing-induced instabilities are presented in a novel manner allowing visualizing new details of the phenomenon numerical stability investigations on the effect of the friction distribution are also done. It is found that by increasing the total restriction in the channel the system is destabilized. In addition, the chimney outlet restriction has a stronger destabilizing effect than the core inlet restriction. A stable two-phase region is observed prior to the instabilities in the experiments and the numerical simulations which may help to pressurize the vessel of NC-BWRs and thus reducing the effects of flashing instabilities during start-up. 相似文献
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Helena Montes-Andrés Dr. Pedro Leo Dr. Gisela Orcajo Dr. Antonio Rodríguez-Diéguez Dr. Duane Choquesillo-Lazarte Dr. Carmen Martos Dr. Juan Ángel Botas Dr. Fernando Martínez Dr. Guillermo Calleja 《Chemphyschem》2019,20(10):1334-1339
A novel URJC-3 material based on cobalt and 5,5′-(diazene-1,2-diyl)diisophthalate ligand, containing Lewis acid and basic sites, has been synthesized under solvothermal conditions. Compound URJC-3, with polyhedral morphology, crystallizes in the tetragonal and P43212 space group, exhibiting a three-dimensional structure with small channels along a and b axes. This material was fully characterized, and its hydrogen adsorption properties were estimated for a wide range of temperatures (77–298 K) and pressures (1–170 bar). The hydrogen storage capacity of URJC-3 is quite high in relation to its moderate surface area, which is probably due to the confinement effect of hydrogen molecules inside its reduced pores of 6 Å, which is close the ionic radii of hydrogen molecules. The storage capacity of this material is not only higher than that of active carbon and purified single-walled carbon nanotubes, but also surpasses the gravimetric hydrogen uptake of most MOF materials. 相似文献
218.
Proteins are a diverse class of molecules that can act as catalysts and structural components. Interest in their interactions with ionic solvents is on the increase due to the tuneable possibilities for non-aqueous biocatalysis, improved thermostability of biomaterials, and possible roles in medicine, such as drug delivery and use as cell-growth scaffolds. We summarise here the recent examples of these exciting new aspects of protein-ionic solvent interactions, highlighting future directions. 相似文献
219.
Scott C. Hagen Olaf Horstmann Robert J. Bennett 《International Journal of Computational Fluid Dynamics》2013,27(2):83-91
The successful implementation of a finite element model for computing shallow water flow requires: (1) continuity and momentum equations to describe the physics of the flow, (2) boundary conditions, (3) a discrete surface water region, and (4) an algebraic form of the shallow water equations and boundary conditions. Although steps (1), (2), and (4) may be documented and can be duplicated by multiple scientific investigators, the actual spatial discretization of the domain, i.e. unstructured mesh generation, is not a reproducible process at present. This inability to automatically produce variably-graded meshes that are reliable and efficient hinders fast application of the finite element method to surface water regions. In this paper we present a reproducible approach for generating unstructured, triangular meshes, which combines a hierarchical technique with a localized truncation error analysis as a means to incorporate flow variables and their derivatives. The result is a process that lays the groundwork for the automatic production of finite element meshes that can be used to model shallow water flow accurately and efficiently. The methodology described herein can also be transferred to other modeling applications. 相似文献
220.
Hagen Stosnach 《Spectrochimica Acta Part B: Atomic Spectroscopy》2010,65(9-10):859-863
Selenium is essential for many aspects of human health and, thus, the object of intensive medical research. This demands the use of analytical techniques capable of analysing selenium at low concentrations with high accuracy in widespread matrices and sometimes smallest sample amounts.In connection with the increasing importance of selenium, there is a need for rapid and simple on-site (or near-to-site) selenium analysis in food basics like wheat at processing and production sites, as well as for the analysis of this element in dietary supplements. Common analytical techniques like electrothermal atomic absorption spectroscopy (ETAAS) and inductively-coupled plasma mass spectrometry (ICP-MS) are capable of analysing selenium in medical samples with detection limits in the range from 0.02 to 0.7 μg/l. Since in many cases less complicated and expensive analytical techniques are required, TXRF has been tested regarding its suitability for selenium analysis in different medical, food basics and dietary supplement samples applying most simple sample preparation techniques.The reported results indicate that the accurate analysis of selenium in all sample types is possible. The detection limits of TXRF are in the range from 7 to 12 μg/l for medical samples and 0.1 to 0.2 mg/kg for food basics and dietary supplements. Although this sensitivity is low compared to established techniques, it is sufficient for the physiological concentrations of selenium in the investigated samples. 相似文献