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排序方式: 共有375条查询结果,搜索用时 78 毫秒
41.
Askari MS Girard B Murugesu M Ottenwaelder X 《Chemical communications (Cambridge, England)》2011,47(28):8055-8057
The reaction of nitrosobenzene with copper(I) complexes of a tetradentate ligand led to two novel species that are best described as copper(II) complexes of an O-bonded nitrosobenzyl radical anion, in either the singlet or the triplet spin-state. Both states were characterized by crystal structures, magnetic measurements and DFT calculations. 相似文献
42.
F. Girard M.-G. Lee L. A. Agrofoglio A. Fridland 《Journal of heterocyclic chemistry》1998,35(4):911-913
A stereoselective five-step total synthesis of the hitherto unknown carbocyclic alpha-L-dideoxyhomonu-cleosides starting from readily available (1R,5S)-2-oxabicyclo[3.3.0]oct-6-en-3-one is described. 相似文献
43.
M.A. Bouchene V. Blanchet C. Nicole N. Melikechi B. Girard H. Ruppe S. Rutz E. Schreiber L. Wöste 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,2(2):131-141
The interaction of a sequence of two identical ultrashort laser pulses with an atomic system results in quantum interferences
as in Ramsey fringes experiments. These interferences allow achievement of temporal coherent control of the excitation probability.
We present the results of a temporal coherent control experiment on two different atomic systems: one-photon absorption in
K (4s-4p) and two-photon absorption in Cs (6s-7d). In K, the quantum interferences between the two excitation paths associated with the laser pulses are revealed through
rapid oscillations of the excitation probability as a function of the time delay between the two pulses. These oscillations
take place at the transition frequency (period T = 2.56 fs). The interferences are modulated by beats (at about 580 fs) resulting from the doublet structure of the excited
state (4p (2
P
1/2
, 2
P
3/2
)). Three complementary interpretations of this experiment are presented: in terms of beats of quantum interferences, of variation
in the spectrum intensity, and of wave packet interferences. Whenever the two laser pulses are temporally overlapped, optical
interferences are superimposed on to the quantum interferences. The distinction between these two types of interference is
clearly revealed in the two-photon excitation scheme performed on Cs (6s-7d (2
D
3/2
, 2
D
5/2
)) because quantum interferences occur at twice the frequency of the optical interferences.
Received: 30 December 1997 / Revised: 28 February 1998 / Accepted: 4 March 1998 相似文献
44.
Q. Liu B. Poumellec C. Haut D. Dragoe R. Blum G. Girard J.-E. Bourée A. Kudlinski Y. Quiquempois G. Blaise 《Applied Physics A: Materials Science & Processing》2005,81(6):1213-1219
Amorphous N- or Ge-doped H:SiO2 films deposited on silica by the matrix distributed electron cyclotron resonance-PECVD method were irradiated by an electron-beam with different doses in order to pole the material and induce second harmonic generation (SHG). SHG was measured using the Maker-fringe method. When irradiated at an acceleration voltage of 25 kV, an incident current of 5 nA during 480 s, the N-doped H:SiO2 films exhibited a maximum second harmonic signal in the order of 0.003 pm/V, but when irradiated with an acceleration voltage of 30 kV, at 5 nA during 240 s, the films exhibited a maximum second harmonic signal of 0.006 pm/V. With a smaller current of 0.5 nA during 25 s and 25 kV acceleration voltage, the Ge-doped H:SiO2 films (3.8 at. % Ge) showed a maximum second-order nonlinearity of 0.0005 pm/V. But an H:SiO2 films with a smaller Ge content (1.0 at. % Ge), showed a large SHG: d33=0.09 pm/V when irradiated at 25 kV, 0.5 nA during 15 s. PACS 78.66.J; 42.65.K; 68.60.D 相似文献
45.
46.
S. Agarwal J. Galin B. Gatty D. Guerreau M. Lefort X. Tarrago R. Babinet J. Girard 《Zeitschrift für Physik A Hadrons and Nuclei》1980,296(4):287-294
We have tried to investigate the influence of the entrance channel mass asymmetry on the reaction mechanisms associated with heavy ion collisions. Two systems, one very much asymmetric (O+Mo) and the other one almost symmetric (Cr+Fe), were studied in detail by measuring evaporation residues, deep inelastic collision products and fission fragments. An important fraction of the fragments observed in the Cr+Fe system exhibits all the characteristics of fission fragments. The analysis of these data seems to indicate that these fission like products are most likely emitted by a long lived composite system having not reached full statistical equilibrium for all the degrees of freedom. As a consequence, the fusion cross section for this symmetric system is too low as compared to predictions based on a critical distance approach for fusion, whereas the asymmetric system (O+Mo) is well understood in term of the same model. 相似文献
47.
Tolman's paradox arises in Lorentz-invariant theories of superluminal particles. In this paper we first try to clarify the nature of the paradox and what it means to solve it. We then analyze the various attempts made to either solve or eliminate it. We show that general consequences can be drawn which hold in essentially all paradox-free schemes proposed so far. 相似文献
48.
Summary In the framework of the boson transformation method, a general approach to the study of finite-dimensionality superconductors
is applied to the investigation of the electromagnetic properties of a semiinfinite superconductor and of a film of arbitrary
thickness in the presence of a parallel external magnetic field. The magnetic-field and current density distributions near
the surfaces are computed and numerical results are given for some typical cases. As an application, an estimation of the
superheating field for type-II superconductor is obtained and compared with previous results.
Riassunto Nell'àmbito del metodo della trasformazione bosonica, una tecnica generale per lo studio di superconduttori a dimensione finita è applicata allo studio delle proprietà elettromagnetiche di un superconduttore semi-infinito e di un film di spessore arbitrario. Sono calcolate le distribuzioni del campo magnetico e della densità di corrente, e sono riportati risultati numerici per qualche caso tipico. Infine, si ottiene, e si confronta con precedenti risultati, una stima del campo di surriscaldamento per superconduttori del II tipo.
Резюме В рамках метода бозонного преобразования общий подход для исследования конечно-мерных сверхпроводников применяется к изучению электромагнитных свойств полубесконечного сверхпроводника и пленки произвольной толщины в присутствии параллельного внешнего магнитного поля. Вычисляются распределения магнитного поля и плотности тока вблизи поверхностей. Приводятся численные результаты для некоторых типичных случаев. Оценивается поле супернагревания для сверхпроводника второго рода. Оценка сравнивается с имеющимися результатами.相似文献
49.
By inserting nitrocellulose strips into agarose gels alongside the electrophoresed lanes and passing an electric current perpendicularly in the direction of the strips, highly efficient transfer of DNA bands onto the membrane in the form of concentrated dots is achieved. DNA detection limits by this technique are enhanced, at least three times as visualized by ethidium bromide fluorescence and at least twice more by radiolabeling. 相似文献
50.
Joseph G. Atkinson Burton K. Wasson José J. Fuentes Yves Girard C.Stanley Rooney Edward L. Engelhardt 《Tetrahedron letters》1979,20(31):2857-2860
2-Nitroaryl triflates undergo efficient base-catalyzed nucleophilic displacement by dimethyl malonate anion to yield dimethyl nitroarylmalonates, which subsequently are converted in high yields to nitroarylacetic acids and oxindoles. 相似文献