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991.
We present a method for finding exact solutions of Max-Cut, the problem of finding a cut of maximum weight in a weighted graph.
We use a Branch-and-Bound setting that applies a dynamic version of the bundle method as bounding procedure. This approach
uses Lagrangian duality to obtain a “nearly optimal” solution of the basic semidefinite Max-Cut relaxation, strengthened by
triangle inequalities. The expensive part of our bounding procedure is solving the basic semidefinite relaxation of the Max-Cut
problem, which has to be done several times during the bounding process. We review other solution approaches and compare the
numerical results with our method. We also extend our experiments to instances of unconstrained quadratic 0–1 optimization
and to instances of the graph equipartition problem. The experiments show that our method nearly always outperforms all other
approaches. In particular, for dense graphs, where linear programming-based methods fail, our method performs very well. Exact
solutions are obtained in a reasonable time for any instance of size up to n = 100, independent of the density. For some problems of special structure we can solve even larger problem classes. We could
prove optimality for several problems of the literature where, to the best of our knowledge, no other method is able to do
so.
Supported in part by the EU project Algorithmic Discrete Optimization (ADONET), MRTN-CT-2003-504438. 相似文献
992.
Marco Bramanti Giovanni Cupini Ermanno Lanconelli Enrico Priola 《Mathematische Zeitschrift》2010,266(4):789-816
We consider a class of degenerate Ornstein–Uhlenbeck operators in ${\mathbb{R}^{N}}We consider a class of degenerate Ornstein–Uhlenbeck operators in
\mathbbRN{\mathbb{R}^{N}} , of the kind
A o ?i, j=1p0aij?xixj2 + ?i, j=1Nbijxi?xj\mathcal{A}\equiv\sum_{i, j=1}^{p_{0}}a_{ij}\partial_{x_{i}x_{j}}^{2} + \sum_{i, j=1}^{N}b_{ij}x_{i}\partial_{x_{j}} 相似文献
993.
Gabriele Stabile Giovanni Luca Torrisi 《Methodology and Computing in Applied Probability》2010,12(3):415-429
We consider risk processes with non-stationary Hawkes claims arrivals, and we study the asymptotic behavior of infinite and
finite horizon ruin probabilities under light-tailed conditions on the claims. Moreover, we provide asymptotically efficient
simulation laws for ruin probabilities and we give numerical illustrations of the theoretical results. 相似文献
994.
Giovanni Colombo Khai T. Nguyen 《Calculus of Variations and Partial Differential Equations》2010,37(1-2):141-166
Quantitative versions (i.e., taking into account a suitable “distance” of a set from being a sphere) of the isoperimetric inequality are obtained, in the spirit of Fuglede (Trans Am Math Soc 314:619–638, 1989) and Fusco et al. (Ann Math 168:941–980, 2008) for a class of not necessarily convex sets called φ-convex sets. Our work is based on geometrical results on φ-convex sets, obtained using methods of both nonsmooth analysis and geometric measure theory. 相似文献
995.
Giacomo Luigi Petretto Sergio Stoccoro Maria Agostina Cinellu Giovanni Minghetti 《Journal of organometallic chemistry》2010,695(2):256-259
Taking advantage of palladium peculiar “rollover” C,N cyclometallation, it is possible to promote C(3) functionalization of 6-alkyl-substituted-2,2′-bipyridines. The carbonylation reaction of rollover species [Pd(Ln)Cl]2, (HL1 = 6-isopropyl-2,2′-bipy, 1; HL2 = 6-neopentyl-2,2′-bipy, 2; HL3 = 6-ethyl-2,2′-bipy, 3; HL4 = 6-methyl-2,2′-bipy, 4) allowed the synthesis of 2-(pyridin-2-yl)-6-alkyl-nicotinic acids or esters. These nicotinic derivatives are extremely rare and, as far as we know, quite unreported in the case of the 6-substituted molecules. 相似文献
996.
Carstensen O Sielk J Schönborn JB Granucci G Hartke B 《The Journal of chemical physics》2010,133(12):124305
In a large-scale simulation study of ultrafast photochemical dynamics for an azobenzene compound with an additional ethylenic bridge we have found unexpected features: while the dynamics starting from the Z isomer follow a barrierless path with steep gradients, the dynamics starting from the E isomer proceed through a different conical intersection surrounded by a rather flat potential energy landscape and then encounter a sizeable barrier in the electronic ground state that markedly influences the reaction behavior. Direct comparisons with experimental static UV spectra, quantum yields, and transient absorption spectra show good agreement and reveal signatures of this unusual behavior. 相似文献
997.
In this paper we set up a method called overlap decoherence correction (ODC) to take into account the quantum decoherence effect in a surface hopping framework. While keeping the standard surface hopping approach based on independent trajectories, our method allows to account for quantum decoherence by evaluating the overlap between frozen Gaussian wavepackets, the time evolution of which is obtained in an approximate way. The ODC scheme mainly depends on the parameter σ, which is the Gaussian width of the wavepackets. The performance of the ODC method is tested versus full quantum calculations on three model systems, and by comparison with full multiple spawning (FMS) results for the S(1)→S(0) decay in the azobenzene molecule. 相似文献
998.
A straightforward procedure for the preparation of nucleoside analogue 1 and its regioisomer 2 containing a dihydro-1,4-dithiin as sugar moiety has been accomplished in four steps by our readily available heterocyclic system 5. Nucleobase insertion was carried out by direct addition of N4-acetylcytosine to sulfoxide derivatives via Pummerer-type glycosidation reaction. 相似文献
999.
Donfack JH Simo CC Ngameni B Tchana AN Kerr PG Finzi PV Vidari G Giardina S Buonocore D Ngadjui BT Moundipa PF Marzatico F 《Natural product communications》2010,5(10):1607-1612
Free radicals, in particular radical oxygen species (ROS), play an important role in the aetiology and pathogenesis of various diseases. Current research in many countries focuses on the use of local medicinal plants as a promising source of liver protective agents. This paper describes the hepatoprotective effects of the methanol extract and four isolated compounds from Ficus chlamydocarpa on CCl4-induced liver damage, as well as the possible antioxidant mechanisms involved in this protection. The DPPH test, along with the beta-Carotene-Linoleic Acid Model System and Ferric-Reducing Antioxidant Power assays, as well as the inhibition of microsomal lipid peroxidation were used to measure radical-scavenging and antioxidant activities. Pretreatment of rats with the methanol extract of F. chlamydocarpa before CCl4 administration, significantly prevented serum increase of hepatic enzyme markers, glutamate oxaloacetate transaminase (GOT) and glutamate pyruvate transaminase (GPT), in a dose-dependent manner. The hepatoprotection was also associated with a significant enhancement in hepatic reduced glutathione (GSH) and a marked decrease of liver malondialdehyde (MDA). Among the four compounds 1-4, isolated from the methanol extract, alpha-amyrin acetate (1) and luteolin (4) showed a significant hepatoprotective activity, as indicated by their ability to prevent liver cell death and lactate dehydrogenase (LDH) leakage during CCl4 intoxication. 相似文献
1000.
Giuseppe Zanoni Alessandro D’Alfonso Lazzaro Feliciani Giovanni Vidari 《Tetrahedron》2010,66(38):7472-8542
Gold(I) mediated Meyer-Schuster rearrangement for the installation of the ‘lower’ side chain of prostaglandins and their analogs has been developed. This Au-mediated rearrangement, featuring a low catalyst loading and mild reaction conditions, has been demonstrated to be an efficient alternative to the standard Horner-Wadsworth-Emmons reaction in prostaglandin chemistry. Moreover, the present results provide a new synthetic process leading to pharmacologically active prostanoids: Latanoprost and Bimatoprost, that continue to hold key positions in the anti-glaucoma drug market. 相似文献
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