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101.
The B-spline density-functional method has been applied to the conformers of the (1R, 2R)-1,2-dibromo-1,2-dichloro-1,2-difluoroethane molecule. The cross section, asymmetry, and dichroic parameters relative to core and valence orbitals, which do not change their nature along the conformational curve, have been systematically studied. While the cross section and the asymmetry parameter are weakly affected, the dichroic parameter appears to be rather sensitive to the particular conformer of the molecule, suggesting that this dynamical property could be a useful tool for conformational analysis. The computational method has also been applied to methyl rotation in methyloxirane. Unexpected and dramatic sensitivity of the dichroic-parameter profile to the methyl rotation, both in the core and valence states, has been found. Boltzmann averaging over the conformers reproduces quite closely the profiles previously obtained for the minimum-energy conformation, which is in good agreement with the experimental results. 相似文献
102.
Ugo Azzena Giovanna DettoriMaria Vittoria Idini Luisa PisanoGrazia Sechi 《Tetrahedron》2003,59(40):7961-7966
Selective removal of the 4-methoxy group of 3,4,5-trimethoxystilbenes was performed under electron transfer conditions from Na metal in THF. Careful control of reaction conditions and quenching procedure allowed the synthesis of either (E)-3,5-dimethoxystilbenes or 3,5-dimethoxybibenzyls. 相似文献
103.
104.
Giovanna Carnovale 《Acta Appl Math》1998,53(2):187-228
This paper answers a few questions about algebraic aspects of bialgebras, associated with the family of solutions of the quantum Yang–Baxter equation in Acta Appl. Math. 41 (1995), pp. 57–98. We describe the relations of the bialgebras associated with these solutions and the standard deformations of GLn and of the supergroup GL(m|n). We also show how the existence of zero divisors in some of these algebras are related to the combinatorics of their related matrix, providing a necessary and sufficient condition for the bialgebras to be a domain. We consider their Poincaré series, and we provide a Hopf algebra structure to quotients of these bialgebras in an explicit way. We discuss the problems involved with the lift of the Hopf algebra structure, working only by localization. 相似文献
105.
Riassunto Si dimostrano teoremi di esistenza, di unicità e di regolarizzazione per la soluzione del problema di Cauchy-Dirichlet per
una classe di sistemi parabolici a coefficienti misurabili.
Lavoro eseguito nell'ambito del gruppo G.N.A.F.A. del C.N.R. 相似文献
Summary We show that the Cauchy-Dirichlet problem for a class of parabolic systems with measurable coefficients admits a unique solution. We show, also, regularity's properties for the solution.
Lavoro eseguito nell'ambito del gruppo G.N.A.F.A. del C.N.R. 相似文献
106.
We study bilateral problems for a second order parabolic operator with principal part not of divergence form. We prove existence, uniqueness, Holder-continuity and approximation results for both strong and generalized solutions. 相似文献
107.
Giovanna Pizzirani Pierluigi Magagnini Paolo Giusti 《Journal of Polymer Science.Polymer Physics》1971,9(6):1133-1145
The glass transition temperatures of a number of poly(vinyl phenyl ketones), poly-(vinyl benzoates), and poly(phenyl acrylates) have been measured by a refractometric method. The effects exerted on Tg by the nature and position of the ring substituents and by the different groups binding the pendant phenyl rings to the polyvinyl chain are discussed. The importance of knowledge of the side-group motions in the glassy state for the interpretation of glass temperature data is emphasized. 相似文献
108.
109.
Giovanna Carnovale 《Algebras and Representation Theory》2006,9(1):99-120
We show which H
op
-cleft extensions of k for a dual quasi-triangular Hopf algebra (H, r) are H-Azumaya. The result is given in terms of bijectivity of a map defined in terms of the universal r-form r and the 2-cocycle σ, generalizing a well-known result for the commutative and co-commutative case. We illustrate the Theorem with an explicit computation for the Hopf algebras of type E(n).Presented by A. Verschoren 相似文献
110.
Giancarlo Consolo Carmela Currò Giovanna Valenti 《Mathematical Methods in the Applied Sciences》2020,43(18):10474-10489
The formation of Turing vegetation patterns in flat arid environments is investigated in the framework of a generalized version of the hyperbolic Klausmeier model. The extensions here considered involve, on the one hand, the strength of the rate at which rainfall water enters into the soil and, on the other hand, the functional dependence of the inertial times on vegetation biomass and soil water. The study aims at elucidating how the inclusion of these generalized quantities affects the onset of bifurcation of supercritical Turing patterns as well as the transient dynamics observed from an uniformly vegetated state towards a patterned state. To achieve these goals, linear and multiple-scales weakly nonlinear stability analysis are addressed, this latter being inspected in both large and small spatial domains. Analytical results are then corroborated by numerical simulations, which also serve to describe more deeply the spatio-temporal evolution of the emerging patterns as well as to characterize the different timescales involved in vegetation dynamics. 相似文献