全文获取类型
收费全文 | 1113篇 |
免费 | 30篇 |
专业分类
化学 | 778篇 |
晶体学 | 12篇 |
力学 | 30篇 |
数学 | 191篇 |
物理学 | 132篇 |
出版年
2023年 | 8篇 |
2022年 | 26篇 |
2021年 | 35篇 |
2020年 | 17篇 |
2019年 | 15篇 |
2018年 | 17篇 |
2017年 | 15篇 |
2016年 | 37篇 |
2015年 | 21篇 |
2014年 | 30篇 |
2013年 | 41篇 |
2012年 | 57篇 |
2011年 | 65篇 |
2010年 | 36篇 |
2009年 | 51篇 |
2008年 | 66篇 |
2007年 | 62篇 |
2006年 | 69篇 |
2005年 | 66篇 |
2004年 | 53篇 |
2003年 | 47篇 |
2002年 | 31篇 |
2001年 | 17篇 |
2000年 | 11篇 |
1999年 | 15篇 |
1998年 | 14篇 |
1997年 | 11篇 |
1996年 | 20篇 |
1995年 | 18篇 |
1994年 | 14篇 |
1993年 | 13篇 |
1992年 | 13篇 |
1991年 | 9篇 |
1990年 | 6篇 |
1989年 | 11篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 5篇 |
1985年 | 8篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1978年 | 6篇 |
1976年 | 4篇 |
1974年 | 5篇 |
1973年 | 6篇 |
1971年 | 4篇 |
1969年 | 3篇 |
排序方式: 共有1143条查询结果,搜索用时 15 毫秒
31.
The microwave spectrum of N2D4 has been observed and analyzed. Based on five low-J rotational transitions the effective rotational constants are: A = 74712.9 ± 1.9 MHz, B = 18500.42 ± 0.46 MHz, and C = 18439.91 ± 0.46 MHz. The quadrupole coupling constants of the 14N nuclei are Xaa = 4.23 ± 0.04 MHz, Xbb = 1.98 ± 0.05 MHz, and Xcc = ?2.25 ± 0.05 MHz. Using the observed ground state inversion splittings for N2D4 and N2H4 the barrier to inversion of a single amino group is computed to be 5.00 kcal mol?1. 相似文献
32.
Cafeo G Kohnke FH Parisi MF Pistone Nascone R La Torre GL Williams DJ 《Organic letters》2002,4(16):2695-2697
[reaction: see text] The meso-decamethyl-calix[5]pyrrole 2b was synthesized from the furan-based analogue 1b via the homologation of the furan rings to pyrrole, and its solid-state structure was determined by X-ray crystallography: surprisingly, the binding constant of 2b toward chloride is found to be lower than that of the tetrameric analogue 2a. 相似文献
33.
Graziella Tocco Michela Begala Giovanna Delogu Carmen Picciau Gianni Podda 《Tetrahedron letters》2004,45(37):6909-6913
In the presence of catalytic amount of indium(III) chloride (10 mol %), 2,2′-dihydroxybiphenyl and bis(2-hydroxyphenyl)methane react quickly, without using any solvent, with ketones or β-keto esters possessing at least one hydrogen atom in α to the ketone-carbonyl group, to afford some new dibenzo(d,f)(1,3)dioxepines and some 12H-dibenzo(d,g)(1,3)dioxocin derivatives, respectively. 相似文献
34.
Giovanna Cerami 《Rendiconti del Circolo Matematico di Palermo》1983,32(3):336-357
The main purpose of this paper is to use variational methods in the study of problems of following type: $$\left\{ {\begin{array}{*{20}c} {Lu = \lambda f(x,u) in \Omega } \\ {u = 0 on \partial \Omega } \\ \end{array} } \right.$$ Here Ω is supposed to be a bounded domain with smooth boundary ? Ω,L an elliptic operator, λ∈IR andf(x, t) a real function defined on \(\tilde \Omega \times IR\) having one or several simple discontinuities ont. Mainly we are interested in solutions which satisfy (.) a. e., which are most meaningful in physical problems, and we prove various existence theorems for several choices ofL, f and λ. The main difficulty consists in the fact that the functionals related to (.) are not Fréchet differentiable in every point, sincef is discontinuous. 相似文献
35.
Koji Yoshida Nobutaka Yamamoto Shinya Hosokawa Alfred Q.R. Baron Toshio Yamaguchi 《Chemical physics letters》2007,440(4-6):210-214
Inelastic X-ray scattering experiments have been performed on methanol as a function of density from ambient to the supercritical state. Positive dispersion of the sound velocity, as compared to the hydrodynamic values, is 50% in the ambient condition and decreases to zero at 0.50 g cm−3 over the momentum transfer Q = 1–10 nm−1 with lowering density; however, it increases again with a further decrease in density down to 0.20 g cm−3in the supercritical state only in the Q-range above 5 nm−1. These results have been interpreted as the formation of small oligomers in the low-density supercritical methanol. 相似文献
36.
This study describes a comparison of different modes of open-tubular electrochromatography (OTCEC) in bare and etched capillaries. To carry out the investigation, the separation of impurities of two synthetic peptides and the separation of a mixture of five heterocyclic aromatic amines were studied. Three different types of stationary phase were evaluated: (i) fluorosurfactants (anionic and zwitterionic) adsorbed in the inner wall of the capillary (electrochromatography with dynamically modified stationary phases (DMS)CEC); (ii) physically adsorbed polymers (DMA-SO(3-) and DMA-N(+)(CH(3))(3)) and (iii) chemically modified capillaries (C(18), cholesteryl 10-undecanoate and diol). The results confirm that electrochromatography can be a viable alternative to capillary electrophoresis (CE) and liquid chromatography, more established separation techniques. It is possible to differentiate some minor species for the synthetic peptides that cannot be resolved by CE or high-performance liquid chromatography (HPLC). Moreover the separation of the amine mixture depends strongly on the stationary phase used. 相似文献
37.
38.
39.
Stidder B Fragneto G Roser SJ 《Langmuir : the ACS journal of surfaces and colloids》2005,21(20):9187-9193
The effect of the addition of 1, 2, 4, and 6 mol % cholesterol to 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) floating bilayers has been investigated by neutron reflectivity. All samples exhibited fully stable and reversible gel and fluid phases. Around the main lipid phase transition temperature, DPPC double bilayers exhibit large increases in the water layer separating the bilayers and the upper bilayer roughness. The inclusion of low amounts of cholesterol reduced the swelling of the water layer between the bilayers and the upper bilayer roughness and progressively widened the temperature range over which swelling occurs. Results from asymmetric bilayers are also reported. A higher amount of cholesterol in the lower bilayer induces a smaller swelling of the water layer between the bilayers than in the symmetric case. Finally, the effect of the inclusion of a leaflet of 1,2-dipalmitoyl-sn-glycero-3-phosphoethanolamine (DPPE) was investigated. The presence of a leaflet with a higher gel-transition temperature (T(m)) modifies the phase behavior of the lower T(m) leaflet. 相似文献
40.
2-and 4-Ethoxymethoxybenzyl methyl ethers were employied as useful starting materials for the synthesis of 1,2- or 1,4-dicarbo-substituted benzenes. The proposed reaction sequence involves connection between the reductive lithiation of benzyl alkyl ethers and the metal-catalyzed cross-coupling reaction of aromatic triflates. 相似文献