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排序方式: 共有780条查询结果,搜索用时 343 毫秒
771.
772.
G. Orlandini S. Della Monaca V. D. Efros A. Khugaev W. Leidemann E. L. Tomusiak L. Yuan 《Few-Body Systems》2008,44(1-4):329-331
Results on the transverse response function R T (q,ω) of 3He obtained within the Lorentz integral transform [LIT] [1] method are presented. The response is calculated using the BonnRA nucleon-nucleon potential [2], the Tucson-Melbourne [3] three-body force, and the Coulomb potential for various momentum transfers. The results are compared with available data. 相似文献
773.
G. Morello F. Della SalaL. Carbone L. MannaR. Cingolani M. De Giorgi 《Superlattices and Microstructures》2010
In this contribution we report on an optical nonlinearity featuring colloidal seeded grown CdSe/CdS nanorods (NRs). It consists of a photoluminescence (PL) blueshift of single rod spectra with increasing laser power and a transient, power-dependent redshift of the spectra studied by time resolved PL measurement, strictly related to the multicarrier scattering occurring at high excitation density. We attribute this nonlinearity to a photo-induced screening of an internal field, originating from the piezoelectric polarization induced at the core/shell interface. 相似文献
774.
775.
C. Della Casa A. Fraleoni P. Costa Bizzarri M. Lanzi L. Paganin 《Macromolecular Symposia》2002,180(1):217-222
Polythiophene copolymers containing alkyl side chains of different length and partially functionalized with chromophoric groups have been synthesized by FeCl3 oxidative coupling of 3-alkylthiophenes and functionalized 3-alkylthiophenes. Composition, molecular weigth and configuration of the soluble fraction of the copolymers have been investigated and some structure-property correlations have been evidenced. 相似文献
776.
777.
Dr. Fabio Pirro Dr. Salvatore La Gatta Dr. Federica Arrigoni Dr. Antonino Famulari Dr. Ornella Maglio Prof. Pompea Del Vecchio Prof. Mario Chiesa Prof. Luca De Gioia Prof. Luca Bertini Dr. Marco Chino Prof. Flavia Nastri Prof. Angela Lombardi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(1):e202211552
De novo metalloprotein design is a remarkable approach to shape protein scaffolds toward specific functions. Here, we report the design and characterization of Due Rame 1 (DR1), a de novo designed protein housing a di-copper site and mimicking the Type 3 (T3) copper-containing polyphenol oxidases (PPOs). To achieve this goal, we hierarchically designed the first and the second di-metal coordination spheres to engineer the di-copper site into a simple four-helix bundle scaffold. Spectroscopic, thermodynamic, and functional characterization revealed that DR1 recapitulates the T3 copper site, supporting different copper redox states, and being active in the O2-dependent oxidation of catechols to o-quinones. Careful design of the residues lining the substrate access site endows DR1 with substrate recognition, as revealed by Hammet analysis and computational studies on substituted catechols. This study represents a premier example in the construction of a functional T3 copper site into a designed four-helix bundle protein. 相似文献
778.
Paolo Vacca Maria Grazia Maglione Carla Minarini Giovanna Salzillo Eugenio Amendola Dario Della Sala Alfredo Rubino 《Macromolecular Symposia》2005,228(1):263-272
In order to optimize polymer light emitting diode (PLED) performances, devices with holes injected through an Indium Tin Oxide (ITO) / Polyaniline (PANI) electrode into the polymer are much more efficient than devices fabricated with the anode made only by ITO. We demonstrated that by using doped PANI as hole injection layer in a polymer light emitting diode the manufacturing process can become simpler. Indeed, the pattern of conductive layer can be produced without ITO photolithography by UV exposition. As hole transporter layer, Poly(N-vinylcarbazole) (PVK) was spin coated over the doped PANI layer and a layer of tris (8-hydroxy) quinoline aluminum (Alq3) was then thermally evaporated so as to form the electron transport layer. To complete the device structure, Aluminum contacts were deposited onto the organic layers by vacuum evaporation at low pressure. The layers were characterized by X-ray small-angle diffraction, IR Raman and UV-Vis spectroscopies. Devices without PANI and with PANI as HIL were studied. 相似文献
779.
Maurizio Penco Luciana Sartore Stefania Della Sciucca Alberto D'Amore 《Macromolecular Symposia》2005,228(1):255-262
Mass-variation measurements were carried out on carbon black (CB)-poly(vinyl chloride) (PVC) composite film with 40% by weight of di(2-ethylhexyl)-phthalate (DOP), cast on resonant piezo-layer (RPL) elements of lead zirconat titanate (PZT). Even if anomalous diffusion is predicted by fitting the data with Mt/M∞=ktα, the fractional uptake Mt/M∞ is linear with the square root of the time up to Mt/M∞=0.6, suggesting Fickian behavour. The anomalous values of α are probably due to experimental time lag. A dependence of the diffusion on the morphology of the material and the penetrant shape and flexibility has been found. 相似文献
780.
Michael Wilms Lesly V. Melendez Dr. Rohan J. Hudson Dr. Christopher R. Hall Samantha Prabath Ratnayake Prof. Dr. Trevor Smith Prof. Dr. Enrico Della Gaspera Prof. Dr. Gary Bryant Dr. Timothy U. Connell Prof. Dr. Daniel E. Gómez 《Angewandte Chemie (International ed. in English)》2023,62(24):e202303501
We report a new composite material consisting of silver nanoparticles decorated with three-dimensional molecular organic cages based on light-absorbing porphyrins. The porphyrin cages serve to both stabilize the particles and allow diffusion and trapping of small molecules close to the metallic surface. Combining these two photoactive components results in a Fano-resonant interaction between the porphyrin Soret band and the nanoparticle-localised surface-plasmon resonance. Time-resolved spectroscopy revealed the silver nanoparticles transfer up to 37 % of their excited-state energy to the stabilising layer of porphyrin cages. These unusual photophysics cause a 2-fold current increase in photoelectrochemical water-splitting measurements. The composite structure provides a compelling proof of concept for advanced photosensitiser systems with intrinsic porosity for photocatalytic and sensing applications. 相似文献