Discovery of a self-trapped-electron center in α-TeO 2

Electron spin resonance (ESR) studies show that electron irradiation of an f -TeO 2 single crystal followed by 330-nm UV illumination at ～10 v K generates a new spin-1/2 paramagnetic center having C 2 symmetry, like the Te lattice sites, that is attributed to a self-trapped charge on a Te. Identification is facilitated by a strong hyperfine interaction with 125 Te at a central Te site and weaker 125 Te superhyperfine interactions with three different equivalent pairs of neighboring Te cations. The irradiations also produce the diamagnetic V_{O}^{\times} center and the paramagnetic V_{O}^{\bullet} and V_{O}^{\prime} centers. From measurements of concentration changes of the paramagnetic centers due to thermal annealing of the new center it is deduced that the self-trapped charge is a self-trapped electron. It is designated as a \hbox{TeO}_{2}^{\prime} center. This assignment is consistent with its low thermal stability since it anneals quickly at temperatures above 40 v K. ESR characteristics of this new center are described.     

Correlated electromigration of H in the switchable mirror YH(3-delta)

Electromigration of hydrogen in YH(3-delta) is studied by exploiting the H concentration dependence of the optical transmission of YH(3-delta). We find the effective valence Z* of H in YH(3-delta) to be negative. Its value is dominated by a huge wind-force-like term, i.e., Z* approximately K/rho, with K approximately -60 mOmega cm. This value is 3 orders of magnitude larger than typical for H in metals. In an Arrhenius plot, the ratio of hydrogen and electron fluxes extrapolates to unity at infinite temperature, suggesting a one-to-one correlation of hydrogen and electron hopping. We discuss our results in the light of strong electron correlation theories which predict each proton to bind two electrons in a sort of Zhang-Rice singlet.     

Interpreting early land management through compound specific stable isotope analyses of archaeological soils

Compound specific stable isotope analyses of managed soils using isotope ratio mass spectrometry have been undertaken as a means of determining early land use practices. delta (15)N amino acid signals demonstrate differences between manured grassland, unmanured grassland and continuous cereal cultivation under long-term experimental land use control conditions, with delta (15)N in hydrophobic amino acids providing the most distinctive signals. Analysis of early modern/medieval and of Bronze age anthropogenic soils from Orkney demonstrates that such signals are retained in archaeological contexts. delta (13)C analyses of n- alkanoic acid components of the fossil, Bronze Age, anthropogenic soils suggest a major terrestrial input to these soils, with uniform composition of formation materials. Surficial soils demonstrate the assimilation of isotopically lighter carbon, providing a means of assessing the mobility of the n- alkanoic acids within soils and sediments. Copyright 1999 John Wiley & Sons, Ltd.     

Vortex lattice transitions in YNi2B2C

We have performed extensive small-angle neutron scattering (SANS) diffraction studies of the vortex lattice in single crystal YNi₂B₂C for B‖c. High-resolution SANS, combined with a field-oscillation vortex lattice preparation technique, allows us to separate Bragg scattered intensities from two orthogonal domains and accurately determine the unit cell angle, β. The data suggest that upon increasing field there is a finite transition width where both low- and high-field distorted hexagonal vortex lattice phases, mutually rotated by 45°, coexist. The smooth variation of diffracted intensity from each phase through the transition corresponds to a redistribution of populations between the two types of domains.     

Centred TVD schemes for hyperbolic conservation laws

New first- and high-order centred methods for conservation lawsare presented. Convenient TVD conditions for constructing centredTVD schemes are then formulated and some useful results areproved. Two families of centred TVD schemes are constructedand extended to nonlinear systems. Some numerical results arealso presented.     

An algebraic approach to discrete mechanics

Using basic ideas from algebraic geometry, we extend the methods of Lagrangian and symplectic mechanics to treat a large class of discrete mechanical systems, that is, systems such as cellular automata in which time proceeds in integer steps and the configuration space is discrete. In particular, we derive an analog of the Euler-Lagrange equation from a variational principle, and prove an analog of Noether's theorem. We also construct a symplectic structure on the analog of the phase space, and prove that it is preserved by time evolution.     

Inverse parabolic problems and discrete orthogonality

Summary This paper considers a discrete sampling scheme for the approximate recovery of initial data for one dimensional parabolic initial boundary value problems on a bounded interval. To obtain a given approximate, data is sampled at a single time and at a finite number of spatial points. The significance of this inversion scheme is the ability to accurately predict the error in approximation subject to choice of sample time and spatial sensor locations. The method is based on a discrete analogy of the continuous orthogonality for Sturm-Liouville systems. This property, which is of independent mathematical interest, is the notion of discrete orthogonal systems, which loosely speaking provides an exact (or approximate) Gauss-type quadrature for the continuous biorthogonality conditions.Supported in part by NSF Grant #DMS8905-344. Texas Advanced Research Program Grant #0219-44-5195 and AFOSR Grant #88-0309Visiting at Texas Tech University, Fall 1989Supported in part by NSF Grant #DMS8905-344, NSA grant #MDA904-85-H009 and NASA Grant #NAQ2-89     

Effects of pre-spark heat release on engine knock limit

It is well known that spark ignited engine efficiency is limited by end gas autoignition, commonly known as knock. This study focuses on a recently discovered phenomena, pre-spark heat release (PSHR) due to low-temperature chemistry, and its impact on knock behavior. Boosted operating conditions are more common as engines are downsizing and downspeeding in efforts to increase fuel economy and prone to PSHR. Experiments were prone at fixed fueling and air fuel ratio for a range of intake temperature that spanned the threshold for PSHR. It was found that when PSHR occurred, the knock-limited combustion phasing was insensitive to intake temperature; higher intake temperatures did not require retarded timings as it is usual. Inspection of the temperature–pressure history overlaid on ignition delay contours allow the results to be explained. The temperature rise from the low-temperature reactions moves the end gas state into the negative temperature coefficient (NTC) region, which terminates the heat release reactions. The end gas then resides in the long ignition delay peninsula, which inhibits knock.     

Some properties of canonical correlations and variates in infinite dimensions

In this paper the notion of functional canonical correlation as a maximum of correlations of linear functionals is explored. It is shown that the population functional canonical correlation is in general well defined, but that it is a supremum rather than a maximum, so that a pair of canonical variates may not exist in the spaces considered. Also the relation with the maximum eigenvalue of an associated pair of operators and the corresponding eigenvectors is not in general valid. When the inverses of the operators involved are regularized, however, all of the above properties are restored. Relations between the actual population quantities and their regularized versions are also established. The sample functional canonical correlations can be regularized in a similar way, and consistency is shown at a fixed level of the regularization parameter.