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61.
62.
Several variants of the modal interpretation of quantum mechanics have been introduced and discussed in recent years. In this paper we present a study of the mathematical foundations of such an interpretation in the framework of the quantum theory of measurement. 相似文献
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64.
The dynamics of a crystalline monolayer of molecular nitrogen physisorbed on the basal plane of graphite, which was assumed to be rigid, has been studied by means of lattice and molecular dynamics. The study focusses mainly on the registered solid in which the centres of mass adopt the √3 × √3 R30° structure, but some results are also reported for denser monlayers, including one where the centre-of-mass lattice is non-triangular. Harmonic dispersion curves are reported for two models of the N2-N2 interaction combined with Steele's representation of the molecule-surface interaction. The one-phonon density of states is given for one of the models. Molecular dynamics results for the same model at two temperatures, 5 and 17 K, are analysed in terms of the dynamical structure factor, and one-phonon approximation to it, and the out-of-plane motions are treated in a manner similar to the one-phonon approximation. In-plane and out-of-plane motions are largely decoupled in all cases studied, and the in-plane motions show evidence of marked anharmonicity. The out-of-plane motions appear to exhibit Fermi-Pasta-Ulam type recurrences, although this is not analysed in detail. 相似文献
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66.
Antonio Maccione Antonio Plumitallo Gianni Podda 《Journal of heterocyclic chemistry》1983,20(5):1397-1398
Treatment of 2-chloro-1,3,2-benzodioxastibole with diacyl chlorides afforded cyclic tetraesters in yields depending on ring size. The exclusive formation of dimeric derivatives was obtained using this method. The products were characterized by analytical and spectroscopic (ir, nmr and ms) data. 相似文献
67.
The discovery of new metal-based antitumour drugs, whether cisplatin derivatives or those based on other metals, has been largely based on cell viability assays (IC50 values) and compounds that bind to DNA. This approach has been applied for more than 30 years during which time very few new drugs have entered clinical use. In this article we discuss what the future holds for metal-based drugs, in particular anti-metastasis drugs, in these enlightened times of the post genomic era. 相似文献
68.
Pagliai M Bellucci L Muniz-Miranda M Cardini G Schettino V 《Physical chemistry chemical physics : PCCP》2006,8(1):171-178
The adsorption of pyridine onto silver colloids has been investigated by Raman spectroscopy experiments and by ab initio DFT and MP2 calculations. The solvation dynamics of the pyridine in water has been studied by a molecular dynamics simulation. The results are compared with the latest available experimental and theoretical data. It is found that the pyridine is essentially hydrogen bonded to one solvent molecule. Calculations based on pyridine-water and pyridine-Ag(+) complexes allow the reproduction of the experimentally observed Raman features and explain the adsorption process of the ligand in silver hydrosols. 相似文献
69.
Gianni Dal Maso Giuliano Lazzaroni 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2010
We present a variational model to study the quasistatic growth of brittle cracks in hyperelastic materials, in the framework of finite elasticity, taking into account the non-interpenetration condition. 相似文献
70.